We develop a perturbative framework for time-dependent point interactions in quantum systems with purely discrete unperturbed spectrum. In two and three dimensions the point interaction is described through the renormalized resolvent obtained from heat-kernel regularization, while in one dimension the diagonal Green function is finite and no renormalization is required. Time dependence is introduced either through the interaction parameter or through the motion of the support point. In both cases we expand the non-autonomous Hamiltonian in the spectral basis of the corresponding static point-interaction problem and derive the first- and second-order pole shifts, projection corrections, and transition amplitudes. The method is illustrated by explicit examples: point interactions with time-dependent coupling, harmonic oscillators perturbed by moving point interactions, and a particle on a sphere with a moving interaction center. We also discuss the one-dimensional harmonic oscillator with a moving delta potential, showing that in the non-renormalized case the present formulation reduces to the standard time-dependent perturbation theory.
We develop a perturbative framework for time-dependent point interactions in quantum systems with purely discrete unperturbed spectrum. In two and three dimensions the point interaction is described through the renormalized resolvent obtained from heat-kernel regularization, while in one dimension the diagonal Green function is finite and no renormalization is required. Time dependence is introduced either through the interaction parameter or through the motion of the support point. In both cases we expand the non-autonomous Hamiltonian in the spectral basis of the corresponding static point-interaction problem and derive the first- and second-order pole shifts, projection corrections, and transition amplitudes. The method is illustrated by explicit examples: point interactions with time-dependent coupling, harmonic oscillators perturbed by moving point interactions, and a particle on a sphere with a moving interaction center. We also discuss the one-dimensional harmonic oscillator with a moving delta potential, showing that in the non-renormalized case the present formulation reduces to the standard time-dependent perturbation theory.
In this work, we show that the completeness relation for the eigenvectors, which is an essential assumption of quantum mechanics, remains true if the Hamiltonian, having a discrete spectrum, is modified by a delta potential (to be made precise by a renormalization scheme) supported at a point in two- and three-dimensional compact manifolds or Euclidean spaces. The formulation can be easily extended to an N center case and the case where delta interaction is supported on curves in the plane or space. We finally give an interesting application for the sudden perturbation of the support of the delta potential.
The Dirac variation-of-constants method has long provided a basis for perturbative solution of the time-dependent Schr\"odinger equation. In spite of its widespread utilization, certain aspects of the method have been discussed only superficially and remain somewhat obscure. The present review attempts to clarify some of these points, particularly those related to secular and normalization terms. Secular terms arise from an over-all time-dependent phase in the wave function, while normalization terms preserve the norm of the wave function. A proper treatment of the secular terms is essential in the presence of a physically significant level shift that can produce secular divergences in the time-dependent perturbation functions. The normalization terms are always important, although the formulation of a simple method for including them is of greatest utility in applications requiring higher-order perturbation theory (e.g., nonlinear optical phenomena), where difficulties have arisen in previous treatments. Although the Dirac perturbation technique includes the correct secular and normalization terms when properly executed, it is convenient to reinterpret the perturbation problem so that the secular and normalization terms can be factored from the wave function to all orders. It is shown that an appropriate over-all multiplicative, time-dependent normalization and phase factor can be obtained, and that it is simply the amplitude for finding the system in the unperturbed eigenstate at any time t. The regular part of the wave function remaining after this factorization provides a complete description of the physical properties of the system of interest and determines the over-all normalization and phase, as well. Most important, the regular function and its perturbation expansion satisfy equations which are more convenient for computational applications than are the customary Dirac equations, and, in contrast to the latter, they reduce directly to the familiar time-independent perturbation equations in the static limit. To illustrate the general development, the model problem of a linearly perturbed harmonic oscillator and the static, harmonic, and electromagnetic perturbations of arbitrary quantum-mechanical systems are treated explicitly. In the case of an adiabatically applied static perturbation, the familiar adiabatic theorem is recovered with the over-all phase factor giving the perturbed eigenvalue, while in the case of an harmonic perturbation, the overall phase factor obtained includes the system level shift appropriate for a quasiperiodic state. For an electromagnetic perturbation, compact expressions are obtained for various nonlinear optical susceptibilities in forms suitable for computations. Time-dependent Hartree-Fock approximations are treated explicity to demonstrate that difficulties can arise when normalization and secular terms are not extracted prior to application of the perturbation formalism. Connection is also made with other methods which can be employed to eliminate secular and normalization terms from the wave function; these include a projection procedure and multiple-time-scales perturbation theory. The elimination of secular divergences from the perturbation functions is shown to be important for the construction of a valid Fourier transform. Secular and normalization terms also arise in connection with variational principles for the time-dependent Schr\"odinger equation. By employing the Frenkel variational principle and an ansatz for the total wave function that explicitly isolates the secular and normalization terms, a computationally convenient variational functional is obtained. This form of the Frenkel principle provides a bound to the system level shift induced by an oscillatory perturbation and is equivalent to the Ritz variational principle in the static limit. Explicit expressions for the variational functional in the Hartree-Fock approximations are derived in forms suitable for computational applications to the interactions of radiation and matter.
We present a time-dependent extension of logarithmic perturbation theory for nonrelativistic quantum dynamics governed by the Schrödinger equation, in which the logarithm of the wave function is expanded in powers of a coupling constant. The resulting hierarchy of equations defining the perturbative corrections is governed by a gauge-rotated Hamiltonian of the unperturbed system and leads to closed-integral expressions for the time-dependent corrections based on Duhamel's formula. This closed-integral structure of corrections is a hallmark of time-independent logarithmic perturbation theory and is preserved in the present extension. This structure, in particular, provides a computable expression for the instantaneous energy shift. Furthermore, dynamic energy shifts arise naturally within this framework in the form of time-averaged expectation values of pseudopotentials and can be related, for example, to AC Stark shifts and electric polarizabilities. As an illustration, we apply the method to the harmonic oscillator and the hydrogen atom, both driven by a time-dependent laser field. The harmonic oscillator provides a proof of principle for which the exact solution is recovered, while the hydrogen atom illustrates the method applied to atomic systems. Supported by numerical simulations, we demonstrate the applicability to obtain relevant physical observables with high accuracy. The present approach offers a promising alternative for analytical studies of time-dependent multi-photon processes in the perturbative regime.
Abstract This review presents time-independent perturbative methods for solving the one-dimensional Schrödinger equation, highlighting representative cases that reveal key aspects of the theory. The focus is on their relevance to quantum computing applications, particularly in systems with finite-dimensional state spaces. The main link between these methods and quantum processing emerges when we consider systems with only a finite number of well-defined energy levels, e.g., two levels corresponding to the ‘zero’ and ‘one’ states of a quantum bit (qubit), for which the Schrödinger equation describes a quantum algorithm corresponding to the unitary evolution of the qubits. Perturbative techniques can then be applied to this evolution to gain deeper insight into the algorithm or to simplify it in a controlled manner, as described in the last sections of this review. We initially discuss representative applications using benchmark cases that exemplify the essential features of perturbation theory while avoiding unnecessary technical complications. The methods presented involve direct approaches to solutions for quantum systems with small potential perturbations, with consideration of indirect and approximation techniques. Key cases examined include the particle in a potential well, the harmonic oscillator, and systems with polynomial or Dirac delta distribution perturbations, each chosen to highlight unique aspects of perturbative analysis. Starting with an overview of the unperturbed Schrödinger equation, we derive canonical solutions and then use perturbative techniques to approximate energy shifts and wavefunction corrections in both non-degenerate and degenerate settings. By combining theoretical discussion with case studies, this review underscores how perturbative methods are applied across a range of elementary quantum mechanical problems especially for applications in the qubit model, which, in many cases of interest, can be reduced to the explicit calculations shown here.
We develop a systematic method of operator perturbation theory in the Heisenberg picture, which is the formal analog of time-independent stationary-state perturbation theory in the Schr\"odinger picture. However, we use the eigenoperators and operator eigenfrequencies to calculate the time evolution of the dynamical variables of interest. The spectrum of the unperturbed Hamiltonian is assumed to be discrete. The method is especially well-suited for treating systems where the unperturbed Hamiltonian represents noninteracting fermions and/or bosons, and therefore, we illustrate the method using the exactly solvable model of Jaynes and Cummings: a single two-level atom interacting with a single quantized field mode. The time evolution of these operator solutions is shown to be unitary order by order in powers of the interaction strength. We find that the time evolution of exact operator solutions is well approximated for significantly longer times by the time evolution of this method's operator solutions than by the time evolution of the same operator solutions calculated using the Dyson expansion. We also demonstrate that time-dependent operator solutions are very convenient for computing quantities such as correlation functions.
We investigate the quantum dynamics of a particle subjected to a linear potential using the Lewis--Riesenfeld invariant operator method. Starting from the time-dependent Schrödinger equation associated with a constant external force, we construct the most general Hermitian quadratic invariant and derive the corresponding coupled differential equations for its time-dependent coefficients. By means of an appropriate sequence of unitary transformations, the invariant operator is reduced to the form of a harmonic oscillator Hamiltonian. This reduction enables a clear classification of the system according to the sign of the conserved quantity ω2. Particular attention is devoted to the physically relevant case ω2 >0, which yields a discrete eigenspectrum. Explicit analytical expressions for the invariant coefficients, the displacement parameters, and the transformed wave functions are obtained. The resulting formalism provides an exact quantum description of a particle under a constant force and establishes a direct connection between invariant theory and harmonic oscillator quantization.