How we identify heat and work is a fundamental question in modern quantum thermodynamics. Usually, heat and work are attributed to changes in the density matrix and the Hamiltonian, respectively, during time-evolution processes in quantum systems. Recently, it has been recognized that this identification is ambiguous. Furthermore, quantum thermodynamics involving quantum measurement is still under development. Motivated by these on-going works, we consider a quantum many-body system from which we extract energy by local operations and classical communication (LOCC) according to the quantum energy teleportation (QET) protocol. The central idea to define heat and work unambiguously is based on a sharp insight into the optimization condition of LOCC. When LOCC is optimized, the extractable energy by QET becomes a daemonic ergotropy; thus, it can be attributed as work. On the other hand, when LOCC is not optimized, we have not squeezed out all the energy with the unitary operation. It means there is uncontrollable energy left in the system. The uncontrollable energy can be attributed as heat after careful treatment of many-body interactions. The heat term consists of nonlocal correlation due to communication between remote participants, and the correlation cannot be directly observed for the participant in the subsystem. Thus, this feature is consistent with the traditional perspective of heat as an uncontrollable energy. To deeply understand the nature of heat, we derive two types of generalized Clausius inequality in our effective quantum thermodynamics, and discuss the direction of the inequality. To justify our perspective, we examine a one-dimensional Kitaev-like model and discuss the physical meaning of effective temperature in our thermodynamics.
AI Summary
The paper asks how to distinguish heat from work in quantum energy teleportation (QET), where Alice measures one part of a ground-state many-body system and Bob uses the communicated outcome to extract energy through local feedback. It constructs an effective thermodynamic description of Bob’s subsystem, treating the remainder as an environment.
Optimizing Alice’s measurement and Bob’s feedback connects the extracted energy to daemonic ergotropy. For nonoptimal protocols, the paper defines the extraction deficit $q=\Delta E_B-\Delta E_B^*\leq0$. After subtracting changes in the interaction-energy contribution, it proposes heat as $Q=\Delta E_{B,B}-\Delta E_{B,B}^*$, where the star denotes the protocol maximizing total extraction, not necessarily local-energy reduction. Consequently, $Q$ can have either sign. A Gibbs reference state at an effective inverse temperature yields the identity $\beta_{\rm eff}Q+\Delta S_B=\Delta D$, with entropy and relative-entropy changes measured relative to the optimal protocol. Relative-entropy positivity then gives a bound $-Q\leq\Pi$.
An analytically treated four-spin Kitaev-like chain illustrates the definitions, distinguishes optimization of total and local extraction, and verifies saturation of the heat bound. Matching the reference state to Bob’s measurement-averaged state gives $\beta_{\rm eff}=(2h)^{-1}\log[(h-\epsilon_B)/(h+\epsilon_B)]$.
The construction concerns effective heat associated with inaccessible correlations rather than a net energy flow across Bob’s boundary. The paper leaves unresolved the separation of measurement and feedback contributions to heat, the connection to Lindblad descriptions, and a first-law formulation for the subsystem.
Little sign of AI-generated textOverclaimsIncrementalStrong assumptionsPossible error
Central claim may not hold: The paper does not establish that energy still extractable through further unitary control is uncontrollable heat, or that its proposed heat definition is unique.
The paper explicitly leaves first-law accounting and the heat contribution of Alice's measurement unresolved, limiting its claimed thermodynamic identification.
The defined heat Q is a difference of local final-energy expectations and can be determined locally given the reference value, contrary to its claimed local unobservability.
In the correlated four-spin example, the averaged-state temperature prescription contradicts Eq. (msigma), because conditional postmeasurement states have strictly less entropy than their average.
No-signalling makes Bob's averaged postmeasurement state independent of Alice's measurement, so the example's type-II bound is saturated for every protocol rather than selectively at maximum heat.
Written by gpt-6.1-sol from the paper's full text. Automated: it can be wrong.
How we identify heat and work is a fundamental question in modern quantum thermodynamics. Usually, heat and work are attributed to changes in the density matrix and the Hamiltonian, respectively, during time-evolution processes in quantum systems. Recently, it has been recognized that this identification is ambiguous. Furthermore, quantum thermodynamics involving quantum measurement is still under development. Motivated by these on-going works, we consider a quantum many-body system from which we extract energy by local operations and classical communication (LOCC) according to the quantum energy teleportation (QET) protocol. The central idea to define heat and work unambiguously is based on a sharp insight into the optimization condition of LOCC. When LOCC is optimized, the extractable energy by QET becomes a daemonic ergotropy; thus, it can be attributed as work. On the other hand, when LOCC is not optimized, we have not squeezed out all the energy with the unitary operation. It means there is uncontrollable energy left in the system. The uncontrollable energy can be attributed as heat after careful treatment of many-body interactions. The heat term consists of nonlocal correlation due to communication between remote participants, and the correlation cannot be directly observed for the participant in the subsystem. Thus, this feature is consistent with the traditional perspective of heat as an uncontrollable energy. To deeply understand the nature of heat, we derive two types of generalized Clausius inequality in our effective quantum thermodynamics, and discuss the direction of the inequality. To justify our perspective, we examine a one-dimensional Kitaev-like model and discuss the physical meaning of effective temperature in our thermodynamics.
The paper asks how to distinguish heat from work in quantum energy teleportation (QET), where Alice measures one part of a ground-state many-body system and Bob uses the communicated outcome to extract energy through local feedback. It constructs an effective thermodynamic description of Bob’s subsystem, treating the remainder as an environment.
Optimizing Alice’s measurement and Bob’s feedback connects the extracted energy to daemonic ergotropy. For nonoptimal protocols, the paper defines the extraction deficit q=ΔEB−ΔEB∗≤0. After subtracting changes in the interaction-energy contribution, it proposes heat as Q=ΔEB,B−ΔEB,B∗, where the star denotes the protocol maximizing total extraction, not necessarily local-energy reduction. Consequently, Q can have either sign. A Gibbs reference state at an effective inverse temperature yields the identity βeffQ+ΔSB=ΔD, with entropy and relative-entropy changes measured relative to the optimal protocol. Relative-entropy positivity then gives a bound −Q≤Π.
An analytically treated four-spin Kitaev-like chain illustrates the definitions, distinguishes optimization of total and local extraction, and verifies saturation of the heat bound. Matching the reference state to Bob’s measurement-averaged state gives βeff=(2h)−1log[(h−ϵB)/(h+ϵB)].
The construction concerns effective heat associated with inaccessible correlations rather than a net energy flow across Bob’s boundary. The paper leaves unresolved the separation of measurement and feedback contributions to heat, the connection to Lindblad descriptions, and a first-law formulation for the subsystem.
Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to arbitrary quantum states. We formulate an operational thermodynamics suitable for application to an open quantum systems undergoing a general quantum evolution. We derive the first law of ther- modynamics for a process described by a completely-positive and trace-preserving map and show consistency with the Hatano-Sasa statement of the second law. We show that heat, from the first law, is positive when the input state of the map majorises the output state. Moreover, the change in entropy is also positive for the same majorisation condition. This makes a strong connection between the two operational laws of thermodynamics. Introduction.— The laws of thermodynamics were forged in the furnaces of the industrial revolution, as engineers and scientists refined their picture of energy, studying heat and its interconversion to mechanical work with a view to powering the mines and factories of this new era of human endeavor. Followed by the development of statistical mechanics at the change of the centuries (1), far from its pragmatic inception, thermodynamics is now a theory with a remarkable range of applicability, successfully describing the properties of macro- scopic systems ranging from refrigerators to black holes (2). Moving on to the 21st century with both the industrial and electronic revolutions behind us, we are currently pushing technology towards and beyond the microscopic scale. With a view to devices operating at a scale where quantum mech- anical laws become important we may ask whether the solid and some combination of the two (8). Finally, central to the work presented here is a work extraction formalism for non-passivity of quantum states (9). Despite the range of ap- proaches a more general picture for the thermodynamics of general quantum evolutions is far from clear. In this Letter, we take an operational approach to character- izing the energy change of an open quantum process described by a completely-positive trace-preserving (CPTP) map. In analogy to the first law of thermodynamics we discuss work done, extractable work, and heat. The concepts of ergotropy and adiabatic work allow us to state our main result: An op- erational first law for general quantum processes. We show that our operational first law is in agreement with widely used Hatano-Sasa version of the second law for CPTP maps (10, 11) by explicitly stating the Clausius inequality for unital and thermal maps. We then show that both operational heat and the change in von Neumann entropy are positive when the input state of the map majorises the output state. Thermodynamics of quantum systems.— The first law of thermodynamics states that the internal energy change in a thermodynamic process can be split up into two contributions - work and heat: dE = Q + W. For a generic quantum system, the internal energy at time t is E(t) = tr( (t)H(t)), implying that the change in the internal energy dE depends only on the end points. Heat and work on the other hand are path-dependent—thus the different notation for the 'differen- tials'. As an illustration we may consider the heat expended when pushing a piston into a cylinder filled with gas: It not only depends on the initial and final positions of the piston but also on how fast it is pushed. Using the derivative of the internal energy with respect to time the following two expres- sions are motivated (10):
Understanding the thermal behavior of quantum many-body pure states is one of the most fundamental issues in quantum thermodynamics. It is widely known that typical pure states yield vanishing work, just as thermal states do, when one restricts to local operations that cannot access correlations among subsystems. However, it remains unclear whether this equivalence to thermal states persists under LOCC (local operations and classical communication), where classically accessible correlations can be exploited for work extraction. In this work, we establish criteria for determining whether many-body pure states remain equivalent to thermal states even under LOCC, and show that this thermal equivalence is governed by their multipartite quantum correlation structure. We show that states with asymptotically maximal multipartite entanglement, such as Haar-random states, cannot yield extensive work under LOCC, whereas some states with limited multipartite entanglement, such as constant-degree graph states, allow extensive work extraction despite being locally indistinguishable from thermal states. Thus, our work provides a refined operational notion of thermal equivalence beyond the traditional local regime, which is becoming increasingly important due to the recent expansion of experimentally accessible operations.
The question of with what we associate work and heat in a quantum thermodynamic process has been extensively discussed, mostly for systems with time-dependent Hamiltonians. In this paper, we aim to investigate the energy exchanged between two quantum systems through interaction where the Hamiltonian of the system is time-independent. An entropy-based re-definitions of heat and work are presented for these quantum thermodynamic systems therefore an entropy-based formalism of both the first and the second laws of thermodynamics are introduced. We will use the genuine reasoning based on which Clausius originally defined work and heat. The change in the energy which is accompanied by a change in the entropy is identified as heat, while any change in the energy which does not lead to a change in the entropy is known as work. It will be seen that quantum coherence does not allow all the energy exchanged between two quantum systems to be only of the heat form. Several examples will also be discussed. Finally, we will examine irreversibility from our entropy-based formalism of quantum thermodynamics.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.
The minimal-coupling quantum heat engine is a thermal machine consisting of an explicit energy storage system, heat baths, and a working body, which alternatively couples to subsystems through discrete strokes --- energy-conserving two-body quantum operations. Within this paradigm, we present a general framework of quantum thermodynamics, where a work extraction process is fundamentally limited by a flow of non-passive energy (ergotropy), while energy dissipation is expressed through a flow of passive energy. It turns out that small dimensionality of the working body and a restriction only to two-body operations make the engine fundamentally irreversible. Our main result is finding the optimal efficiency and work production per cycle within the whole class of irreversible minimal-coupling engines composed of three strokes and with the two-level working body, where we take into account all possible quantum correlations between the working body and the battery. One of the key new tools is the introduced ``control-marginal state" --- one which acts only on a working body Hilbert space, but encapsulates all features regarding work extraction of the total working body-battery system. In addition, we propose a generalization of the many-stroke engine, and we analyze efficiency vs extracted work trade-offs, as well as work fluctuations after many cycles of the running of the engine.
Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was introduced aiming at extending the thermodynamic formalism to genuine quantum settings, also referred to as autonomous quantum systems: free from external controls, only quantum systems interacting with each other. In this paper, we apply such a thermodynamic framework to common experimental situations of interacting quantum systems. In situations where traditional frameworks detect only heat exchanges, the recent autonomous thermodynamic framework points at work exchanges based on two mechanisms: population inversion and coherence generation / consumption. Such mechanisms are well known in the literature for being related to work expenditure and extraction, in particular in relation with ergotropy, which emphasizes the relevance of the autonomous framework and the limitations of traditional ones. Furthermore, the autonomous framework also identifies a genuine non-unitary mechanism of work exchange related to athermality. %, also pointed out as a resource for work extraction. Finally, in the semi-classical limit, the autonomous framework identifies all energy exchanges as pure work, but distinguishes between local work and interaction energy.
Our results show that the autonomous framework provides a refined analysis of work exchange mechanisms in the quantum realm and serves as a consistent approach to analyze thermodynamic processes in realistic quantum devices.