We develop a first-principles thermodynamic framework for non-Hermitian dynamics based on a post-selected version of the fluctuation theorem. This allows us to identify a quantity that remains positive throughout the non-Hermitian evolution and can be interpreted as the entropy production of the post-selected dynamics. We relate this quantity to previously proposed notions of non-Hermitian entropy and derive an associated second law. Furthermore, we establish a connection with information-theoretic quantities, in particular the Petz-Rényi divergences, and leverage this connection to derive upper and lower bounds. Finally, we decompose the entropy production into incoherent and coherent contributions, identifying distinctive features of the coherent term in the vicinity of exceptional points. We illustrate our results using a paradigmatic model of non-Hermitian evolution based on a two-level system.
We develop a first-principles thermodynamic framework for non-Hermitian dynamics based on a post-selected version of the fluctuation theorem. This allows us to identify a quantity that remains positive throughout the non-Hermitian evolution and can be interpreted as the entropy production of the post-selected dynamics. We relate this quantity to previously proposed notions of non-Hermitian entropy and derive an associated second law. Furthermore, we establish a connection with information-theoretic quantities, in particular the Petz-Rényi divergences, and leverage this connection to derive upper and lower bounds. Finally, we decompose the entropy production into incoherent and coherent contributions, identifying distinctive features of the coherent term in the vicinity of exceptional points. We illustrate our results using a paradigmatic model of non-Hermitian evolution based on a two-level system.
We establish the general framework of quantum fluctuation theorems by finding the symmetry between the forward and backward transitions of any given quantum channel. The Petz recovery map is adopted as the reverse quantum channel, and the notion of entropy production in thermodynamics is extended to the quantum regime. Our result shows that the fluctuation theorems, which are normally considered for thermodynamic processes, can be a powerful tool to study the detailed statistics of quantum systems as well as the effect of coherence transfer in an arbitrary non-equilibrium quantum process. We introduce a complex-valued entropy production to fully understand the relation between the forward and backward processes through the quantum channel. We find the physical meaning of the imaginary part of entropy production to witness the broken symmetry of the quantum channel. We also show that the imaginary part plays a crucial role in deriving the second law from the quantum fluctuation theorem. The dissipation and fluctuation of various quantum resources including quantum free energy, asymmetry and entanglement can be coherently understood in our unified framework. Our fluctuation theorem can be applied to a wide range of physical systems and dynamics to query the reversibility of a quantum state for the given quantum processing channel involving coherence and entanglement.
We analyze the production of entropy along nonequilibrium processes in quantum systems coupled to generic environments.First, we show that the entropy production due to final measurements and the loss of correlations obeys a fluctuation theorem in detailed and integral forms.Second, we discuss the decomposition of the entropy production into two positive contributions, adiabatic and nonadiabatic, based on the existence of invariant states of the local dynamics.Fluctuation theorems for both contributions hold only for evolutions verifying a specific condition of quantum origin.We illustrate our results with three relevant examples of quantum thermodynamic processes far from equilibrium.
Fluctuation theorems and the second law of thermodynamics are powerful relations constraining the behavior of out-of-equilibrium systems. While there exist generalizations of these relations to feedback controlled quantum systems, their applicability is limited, in particular when considering strong and continuous measurements. In this Letter, we overcome this shortcoming by deriving a novel fluctuation theorem, and the associated second law of information thermodynamics, which remain applicable in arbitrary feedback control scenarios. In our second law, the entropy production is bounded by the coarse-grained entropy production that is inferrable from the measurement outcomes, an experimentally accessible quantity that does not diverge even under strong continuous measurements. We illustrate our results by a qubit undergoing discrete and continuous measurement, where our approach provides a useful bound on the entropy production for all measurement strengths.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.
We introduce the coherent-incoherent correspondence as a framework for deriving quantum thermodynamic uncertainty relations under continuous measurement in Lindblad dynamics. The coherent-incoherent correspondence establishes a mapping between the original quantum system that undergoes \textit{ coherent} evolution and its corresponding \textit{incoherent} system without coherent dynamics. The coherent-incoherent correspondence relates quantities across these two systems, including jump statistics, dynamical activity, and entropy production. Since the classical-like properties of the incoherent system allow us to derive thermodynamic uncertainty relations within it, these relations can be transferred to the coherent system via the coherent-incoherent correspondence. This enables us to derive quantum thermodynamic uncertainty relations for the original coherent system. Unlike existing quantum uncertainty relations, which typically require explicit quantum correction terms, our approach avoids these additional terms. This means that we can establish a lower bound for quantum entropy production using only current statistics. This approach opens up new possibilities for inferring entropy production in quantum systems. Through numerical calculations for a model with coherent jump operators, we show that steady-state coherence lowers the bounds on precision (i.e., allows higher precision).