Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2607.14687 · Physics

Electrons Hopping across a Molecular Network: Spectra and Symmetries

Ludwig Schulz, Max Best, Carsten Henkel

quant-phcond-mat.str-elSubmitted Jul 16, 2026• Announced Jul 17, 2026• 0 citations
arXivHTMLPDF

Abstract

We investigate interacting spinless electrons on finite molecular ring networks described by a tight-binding Hubbard Hamiltonian. The interplay between lattice geometry, Coulomb interactions and discrete symmetries is analysed for rings with $L=3,4,5,6$ nodes, filled with one, two or three electrons. Special attention is devoted to the role of the network symmetries in determining the structure of the many-body spectrum and the Mulliken classification of the eigenstates. Using group-theoretical methods, we examine the evolution of the spectra in the presence of an external magnetic flux. The Zeeman effect lifts degeneracies and results in combination with the Coulomb interaction to avoided crossings in symmetry sectors. We identify a qualitatively distinction between systems with an even and odd number of particles. At half-filling, particle-hole symmetry (duality) protects selected symmetry sectors against Zeeman splitting.

Comments
submitted to special issue in Physics: "Quantum Theory 100 Years Later: advances on Foundations and Applications"

Related papers

The Hubbard model with bond-charge interaction on a triangular lattice: a renormalization group study

Bibhas Bhattacharyya, Shreekantha Sil

We have studied the Hubbard model with bond-charge interaction on a triangular lattice for a half-filled band. At the point of particle-hole symmetry the model could be analysed in detail in two opposite regimes of the parameter space. Using a real-space renormalization group (RG) we calculate the ground-state energy and the local moment over the whole parameter space. The RG results obey the exact results in the respective limits. In the intermediate region of the parameter space, the RG results clearly show the effects of the non-bipartite geometry of the lattice as well as the absence of symmetry in the reversal of the sign of the hopping matrix element.

arXiv:cond-mat/9904056•Journal of Physics Condensed Matter•Jan 1, 1999•7 citations

Topological edge states in a Rydberg composite

Matthew T. Eiles, Christopher W. Wächtler, Alexander Eisfeld +1 more

We examine topological phases and symmetry-protected electronic edge states in the context of a Rydberg composite: a Rydberg atom interfaced with a structured arrangement of ground-state atoms. We show that the spectrum of the electronic Hamiltonian of such a composite possesses a mapping to that of a tight-binding Hamiltonian, which can exhibit nontrivial topology depending on the arrangement of the ground-state atoms and the principal quantum number of the Rydberg state. The Rydberg electron moves in a combined potential including the long-ranged Coulomb interaction with the Rydberg core and short-ranged interactions with each neutral atom; the effective hopping amplitudes between sites are determined by this combination. We first confirm the existence of topologically-protected edge states in a Rydberg composite by mapping it to the paradigmatic Su-Schrieffer-Heeger dimer model. Following that, we show that more complicated systems with trimer unit cells can be studied in a Rydberg composite. Published by the American Physical Society 2024

arXiv:2309.03039•Physical review. B./Physical review. B•Feb 20, 2024•7 citations

Spin gaps in two models of strongly correlated electron systems

Arnold E. Sikkema

Two aspects of strongly correlated electron systems are studied in this thesis. Hubbard-type models are thought to be at the basis of high-critical-temperature superconductivity. One interaction which has not had much study is the nearest-neighbour hopping of on-site singlet pairs. We refine earlier renormalization group arguments and, using the density-matrix renormalization group method, numerically confirm their prediction that a spin gap opens at infinitesimal pair-hopping amplitude V > 0 in the one-dimensional tight-binding model. We also find a phase separation transition at a finite V > 0 as well as a spin-gap transition at a finite V < 0. The exotic magnetic behaviour of heavy-fermion materials involves an interplay between the screening of local moments from each other and the formation of a magnetic state of long range order. While the single-impurity Kondo Hamiltonian is thought to model some aspects of this behaviour, the properties of the Kondo lattice model away from half-filling are largely unknown. We determine the presence of a spin-gap region in the phase diagram of the one-dimensional Heisenberg-Kondo lattice model and make predictions about certain concealed dimerization order parameters.

•Jan 1, 2009•0 citations

Quantum wire networks with local Z2 symmetry

K. Kazymyrenko, Sébastien Dusuel, Benoît Douçot

For a large class of networks made of connected loops, in the presence of an external magnetic field of half flux quantum per loop, we show the existence of a large local symmetry group, generated by simultaneous flips of the electronic current in all the loops adjacent to a given node. Using an ultralocalized single particle basis adapted to this local ${\mathbb{Z}}_{2}$ symmetry, we show that it is preserved by a large class of interaction potentials. As a main physical consequence, the only allowed tunneling processes in such networks are induced by electron-electron interactions and involve a simultaneous hop of two electrons. Using a mean-field picture and then a more systematic renormalization-group treatment, we show that these pair-hopping processes do not generate a superconducting instability, but they destroy the Luttinger liquid behavior in the links, giving rise at low energy to a strongly correlated spin-density-wave state.

arXiv:cond-mat/0507376•Physical Review B•Dec 19, 2005•6 citations

Ground states of the Falicov-Kimball model with correlated hopping

Jacek Wojtkiewicz, R. Lemański

Two-dimensional spinless Falicov-Kimball model (FKM) with correlated hopping is studied perturbatively in the limit of large on-site Coulomb interaction U. In the half filled case (i.e., ${\ensuremath{\rho}}_{i}+{\ensuremath{\rho}}_{e}=1,$ where ${\ensuremath{\rho}}_{i},{\ensuremath{\rho}}_{e}$ are densities of ions and electrons, respectively) the effective Hamiltonian in spin variables is derived up to terms proportional to ${U}^{\ensuremath{-}3}.$ Unlike the simplest FKM case, it contains odd parity terms (resulting from the correlated hopping) in addition to even parity ones. The ground-state phase diagram of the effective Hamiltonian is examined in the $(a/t,h)$ plane, where $a/t$ is a parameter characterizing strength of the correlated hopping and h is a difference of chemical potentials of two sorts of particles present in the system. It appears to be asymmetric with respect to the change $\stackrel{\ensuremath{\rightarrow}}{h}\ensuremath{-}h$ and an additional ordered phase is found for a certain interval of $a/t.$

arXiv:cond-mat/0106200•Physical review. B, Condensed matter•Nov 8, 2001•28 citations

Electron correlations in quantum dots

D. L. J. Tipton

Quantum dot structures confine electrons in a small region of space. Some properties of semiconductor quantum dots, such as the discrete energy levels and shell filling effects visible in addition spectra, have analogies to those of atoms and indeed dots are sometimes referred to as 'artificial atoms'. However, atoms and dots show some fundamental differences due to electron correlations. For real atoms, the kinetic energy of electrons dominates over their mutual Coulomb repulsion energy and for this reason the independent electron approximation works well. For quantum dots the confining potential may be shallower than that of real atoms leading to lower electron densities and a dominance of mutual Coulomb repulsion over kinetic energy. In this strongly correlated regime the independent electron picture leads to qualitatively incorrect results. This thesis concentrates on few-electron quantum dots in the strongly correlated regime both for quasi-one-dimensional and two-dimensional dots in a square confining potential. In this so-called 'Wigner' regime the ground-state electronic charge density is localised near positions of classical electrostatic minima and the interacting electronic spectrum consists of well separated spin multiplets. In the strongly correlated regime the structure of low-energy multiplets is explained by mapping onto lattice models with extended-Hubbard and Heisenberg effective Hamiltonians. The parameters for these effective models are calculated within a Hartree approximation and are shown to reproduce well the exact results obtained by numerical diagonalisation of the full interacting Hamiltonian. Comparison is made between square dots and quantum rings with full rotational symmetry. In the very low-density regime, direct diagonalisation becomes impractical due to excessive computer time for convergence. In this regime a numerical renormalisation group method is applied to one-dimensional dots, enabling effective spin-interactions to be pr

•Jan 1, 2001•0 citations
We investigate interacting spinless electrons on finite molecular ring networks described by a tight-binding Hubbard Hamiltonian. The interplay between lattice geometry, Coulomb interactions and discrete symmetries is analysed for rings with L=3,4,5,6L=3,4,5,6L=3,4,5,6 nodes, filled with one, two or three electrons. Special attention is devoted to the role of the network symmetries in determining the structure of the many-body spectrum and the Mulliken classification of the eigenstates. Using group-theoretical methods, we examine the evolution of the spectra in the presence of an external magnetic flux. The Zeeman effect lifts degeneracies and results in combination with the Coulomb interaction to avoided crossings in symmetry sectors. We identify a qualitatively distinction between systems with an even and odd number of particles. At half-filling, particle-hole symmetry (duality) protects selected symmetry sectors against Zeeman splitting.
We have studied the Hubbard model with bond-charge interaction on a triangular lattice for a half-filled band. At the point of particle-hole symmetry the model could be analysed in detail in two opposite regimes of the parameter space. Using a real-space renormalization group (RG) we calculate the ground-state energy and the local moment over the whole parameter space. The RG results obey the exact results in the respective limits. In the intermediate region of the parameter space, the RG results clearly show the effects of the non-bipartite geometry of the lattice as well as the absence of symmetry in the reversal of the sign of the hopping matrix element.
We examine topological phases and symmetry-protected electronic edge states in the context of a Rydberg composite: a Rydberg atom interfaced with a structured arrangement of ground-state atoms. We show that the spectrum of the electronic Hamiltonian of such a composite possesses a mapping to that of a tight-binding Hamiltonian, which can exhibit nontrivial topology depending on the arrangement of the ground-state atoms and the principal quantum number of the Rydberg state. The Rydberg electron moves in a combined potential including the long-ranged Coulomb interaction with the Rydberg core and short-ranged interactions with each neutral atom; the effective hopping amplitudes between sites are determined by this combination. We first confirm the existence of topologically-protected edge states in a Rydberg composite by mapping it to the paradigmatic Su-Schrieffer-Heeger dimer model. Following that, we show that more complicated systems with trimer unit cells can be studied in a Rydberg composite. Published by the American Physical Society 2024
Two aspects of strongly correlated electron systems are studied in this thesis. Hubbard-type models are thought to be at the basis of high-critical-temperature superconductivity. One interaction which has not had much study is the nearest-neighbour hopping of on-site singlet pairs. We refine earlier renormalization group arguments and, using the density-matrix renormalization group method, numerically confirm their prediction that a spin gap opens at infinitesimal pair-hopping amplitude V > 0 in the one-dimensional tight-binding model. We also find a phase separation transition at a finite V > 0 as well as a spin-gap transition at a finite V < 0. The exotic magnetic behaviour of heavy-fermion materials involves an interplay between the screening of local moments from each other and the formation of a magnetic state of long range order. While the single-impurity Kondo Hamiltonian is thought to model some aspects of this behaviour, the properties of the Kondo lattice model away from half-filling are largely unknown. We determine the presence of a spin-gap region in the phase diagram of the one-dimensional Heisenberg-Kondo lattice model and make predictions about certain concealed dimerization order parameters.
For a large class of networks made of connected loops, in the presence of an external magnetic field of half flux quantum per loop, we show the existence of a large local symmetry group, generated by simultaneous flips of the electronic current in all the loops adjacent to a given node. Using an ultralocalized single particle basis adapted to this local Z2{\mathbb{Z}}_{2}Z2​ symmetry, we show that it is preserved by a large class of interaction potentials. As a main physical consequence, the only allowed tunneling processes in such networks are induced by electron-electron interactions and involve a simultaneous hop of two electrons. Using a mean-field picture and then a more systematic renormalization-group treatment, we show that these pair-hopping processes do not generate a superconducting instability, but they destroy the Luttinger liquid behavior in the links, giving rise at low energy to a strongly correlated spin-density-wave state.
Two-dimensional spinless Falicov-Kimball model (FKM) with correlated hopping is studied perturbatively in the limit of large on-site Coulomb interaction U. In the half filled case (i.e., ${\ensuremath{\rho}}_{i}+{\ensuremath{\rho}}_{e}=1,$ where ${\ensuremath{\rho}}_{i},{\ensuremath{\rho}}_{e}$ are densities of ions and electrons, respectively) the effective Hamiltonian in spin variables is derived up to terms proportional to ${U}^{\ensuremath{-}3}.$ Unlike the simplest FKM case, it contains odd parity terms (resulting from the correlated hopping) in addition to even parity ones. The ground-state phase diagram of the effective Hamiltonian is examined in the (a/t,h)(a/t,h)(a/t,h) plane, where a/ta/ta/t is a parameter characterizing strength of the correlated hopping and h is a difference of chemical potentials of two sorts of particles present in the system. It appears to be asymmetric with respect to the change $\stackrel{\ensuremath{\rightarrow}}{h}\ensuremath{-}h$ and an additional ordered phase is found for a certain interval of a/t.a/t.a/t.
Quantum dot structures confine electrons in a small region of space. Some properties of semiconductor quantum dots, such as the discrete energy levels and shell filling effects visible in addition spectra, have analogies to those of atoms and indeed dots are sometimes referred to as 'artificial atoms'. However, atoms and dots show some fundamental differences due to electron correlations. For real atoms, the kinetic energy of electrons dominates over their mutual Coulomb repulsion energy and for this reason the independent electron approximation works well. For quantum dots the confining potential may be shallower than that of real atoms leading to lower electron densities and a dominance of mutual Coulomb repulsion over kinetic energy. In this strongly correlated regime the independent electron picture leads to qualitatively incorrect results. This thesis concentrates on few-electron quantum dots in the strongly correlated regime both for quasi-one-dimensional and two-dimensional dots in a square confining potential. In this so-called 'Wigner' regime the ground-state electronic charge density is localised near positions of classical electrostatic minima and the interacting electronic spectrum consists of well separated spin multiplets. In the strongly correlated regime the structure of low-energy multiplets is explained by mapping onto lattice models with extended-Hubbard and Heisenberg effective Hamiltonians. The parameters for these effective models are calculated within a Hartree approximation and are shown to reproduce well the exact results obtained by numerical diagonalisation of the full interacting Hamiltonian. Comparison is made between square dots and quantum rings with full rotational symmetry. In the very low-density regime, direct diagonalisation becomes impractical due to excessive computer time for convergence. In this regime a numerical renormalisation group method is applied to one-dimensional dots, enabling effective spin-interactions to be pr