Accurately controlling entangling gates remains a major challenge for quantum technology applications with solid-state spin qubits. Here, we study a group-IV color-center with a strongly-coupled nuclear spin and approach the problem from a quantum control perspective. We show that there are three different types of entangling gates where the entanglement is mediated by the parallel hyperfine-coupling component, the orthogonal one or both. We derive the respective quantum speed limits (QSL) and show by means of dynamical decoupling, resonant driving of single- and double-quantum transitions, quantum optimal control and algebraic gate decomposition how these gates can be realized. We finally discuss the experimental applicability.
Accurately controlling entangling gates remains a major challenge for quantum technology applications with solid-state spin qubits. Here, we study a group-IV color-center with a strongly-coupled nuclear spin and approach the problem from a quantum control perspective. We show that there are three different types of entangling gates where the entanglement is mediated by the parallel hyperfine-coupling component, the orthogonal one or both. We derive the respective quantum speed limits (QSL) and show by means of dynamical decoupling, resonant driving of single- and double-quantum transitions, quantum optimal control and algebraic gate decomposition how these gates can be realized. We finally discuss the experimental applicability.
Color centers associated with group-IV dopants in diamond with long-lived nuclear spins have emerged as major candidates for distributed quantum computing nodes and quantum repeaters. Several proof-of-principle experiments have already been demonstrated. A key operation for long-distance entanglement-distribution protocols are fast and robust gates between the electron spin and a nuclear spin. Here, we investigate numerically for an existing experimental platform of a Germanium-vacancy (GeV) center with a strongly-coupled 13C spin, how such gates can be implemented via quantum optimal control. In the presence of realistic noise we investigate different parameter regimes and gate operations and obtain robust two-qubit gates with fidelities exceeding 99.9%. The framework provides a scalable strategy for group-IV quantum nodes and can be adapted to related architectures.
A quantum register coupled to a spin-photon interface is a key component in quantum communication and information processing.Group-IV color centers in diamond (SiV -, GeV -, and SnV -) are promising candidates for this application, comprising an electronic spin with optical transitions coupled to a nuclear spin as the quantum register.However, the creation of a quantum register for these color centers with deterministic and strong coupling to the spin-photon interface remains challenging.Here, we make first-principles predictions of the hyperfine parameters of the group-IV color centers, which we verify experimentally with a comprehensive comparison between the spectra of spin active and spin neutral intrinsic dopant nuclei in single GeV -and SnV -emitters.In line with the theoretical predictions, detailed spectroscopy on large sample sizes reveals that hyperfine coupling causes a splitting of the optical transition of SnV -an order of magnitude larger than the optical line width and provides a magnetic field insensitive transition.This strong coupling provides access to a new regime for quantum registers in diamond color centers, opening avenues for novel spin-photon entanglement and quantum sensing schemes for these well-studied emitters.
Abstract Color centers in solids, such as the nitrogen-vacancy center in diamond, offer well-protected and well-controlled localized electron spins that can be employed in various quantum technologies. Moreover, the long coherence time of the surrounding spinful nuclei can enable a robust quantum register controlled through the color center. We design pulse sequence protocols that drive the electron spin to generate robust entangling gates with these nuclear memory qubits. We find that compared to using Carr-Purcell-Meiboom-Gill (CPMG) alone, Uhrig decoupling sequence and hybrid protocols composed of CPMG and Uhrig sequences improve these entangling gates in terms of fidelity, spin control range, and spin selectivity. We provide analytical expressions for the sequence protocols and also show numerically the efficacy of our method on nitrogen-vacancy centers in diamond. Our results are broadly applicable to color centers weakly coupled to a small number of nuclear spin qubits.
Abstract Diamond has emerged as a highly promising platform for quantum network applications. Color centers in diamond fulfill the fundamental requirements for quantum nodes: they constitute optically accessible quantum systems with long‐lived spin qubits. Furthermore, they provide access to a quantum register of electronic and nuclear spin qubits and they mediate entanglement between spins and photons. All these operations require coherent control of the color center's spin state. This review provides a comprehensive overview of the state‐of‐the‐art, challenges, and prospects of such schemes, including high‐fidelity initialization, coherent manipulation, and readout of spin states. Established microwave and optical control techniques are reviewed, and moreover, emerging methods such as cavity‐mediated spin–photon interactions and mechanical control based on spin–phonon interactions are summarized. For different types of color centers, namely, nitrogen–vacancy and group‐IV color centers, distinct challenges persist that are subject of ongoing research. Beyond fundamental coherent spin qubit control techniques, advanced demonstrations in quantum network applications are outlined, for example, the integration of individual color centers for accessing (nuclear) multiqubit registers. Finally, the role of diamond spin qubits in the realization of future quantum information applications is described.
Solid-state quantum registers consisting of optically active electron spins with nearby nuclear spins are promising building blocks for future quantum technologies. For electron spin-1 registers, dynamical decoupling (DD) quantum gates have been developed that enable the precise control of multiple nuclear spin qubits. However, for the important class of electron spin- 1 / 2 systems, this control method suffers from intrinsic selectivity limitations, resulting in reduced nuclear spin gate fidelities. Here, we demonstrate improved control of single nuclear spins by an electron spin- 1 / 2 using dynamically decoupled radio-frequency (DDRF) gates. We make use of the electron spin- 1 / 2 of a diamond tin-vacancy center, showing high-fidelity single-qubit gates, single-shot readout, and spin coherence beyond a millisecond. The DD control is used as a benchmark to observe and control a single 3 1 C nuclear spin. Using the DDRF control method, we demonstrate improved control on that spin. In addition, we find and control an additional nuclear spin that is insensitive to the DD control method. Using these DDRF gates, we show entanglement between the electron and the nuclear spin with 72(3)% state fidelity. Our extensive simulations indicate that DDRF gate fidelities well in excess are feasible. Finally, we employ time-resolved photon detection during readout to quantify the hyperfine coupling for the electron’s optically excited state. Our work provides key insights into the challenges and opportunities for nuclear spin control in electron spin- 1 / 2 systems, opening the door to multiqubit experiments on these promising qubit platforms.
Long distance quantum networking requires combining efficient spin-photon interfaces with long-lived local memories. Group-IV color centers in diamond (SiV, GeV, and SnV) are promising candidates for this application, containing an electronic spin-photon interface and dopant nuclear spin memory. Recent work has demonstrated state-of-the-art performance in spin-photon coupling and spin-spin entanglement. However, coupling between the electron and nuclear spins introduces a phase kickback during optical excitation that limits the utility of the nuclear memory. Here, we propose using the large hyperfine coupling of SnV-117 to operate the device at zero magnetic field in a regime where the memory is insensitive to optical excitation. We further demonstrate ground state spin control of a SnV-117 color center integrated in a photonic integrated circuit, showing 97.8% gate fidelity and 2.5 ms coherence time for the memory spin level. This shows the viability of the zero-field protocol for high fidelity operation, and lays the groundwork for building quantum network nodes with SnV-117 devices.