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arXiv:2607.01620

Identical-Particle Symmetry-Enabled Complete Coherent Control of Ultracold Atomic and Molecular Collisions

Jing-Chen Zhang, Adrien Devolder, Timur V. Tscherbul, Paul Brumer, Yu Liu

physics.atom-phcond-mat.quant-gasquant-phSubmitted Jul 2, 2026• Announced Jul 3, 2026• 0 citations
v1 · Jul 2, 2026v2 · Sep 16, 2026
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Abstract

We show that exchange symmetry in collisions of identical particles enables symmetry-protected coherent control of the total scattering cross section. For identical fermions, antisymmetrization enforces complete phase synchronization of the contributing scattering channels, yielding maximal control visibility. For identical bosons, synchronization persists but with reduced visibility due to additional exchange (satellite) contributions. Collisions of distinguishable particles lack this symmetry-imposed phase locking, leading to lower controllability and visibility. We elucidate these principles through coupled-channel quantum-scattering calculations for lithium-lithium collisions, comparing the $^{6}\mathrm{Li}$-$^{6}\mathrm{Li}$ (identical fermions), $^{7}\mathrm{Li}$-$^{7}\mathrm{Li}$ (identical bosons), and $^{6}\mathrm{Li}$-$^{7}\mathrm{Li}$ (distinguishable) systems. Furthermore, in the identical particle cases, symmetry-enforced synchronization enables full control over the parity of the final state at any collisional energy. This mechanism is broadly applicable to identical-particle collisions, including homonuclear molecules for which established approaches -- DC electric fields, or microwave shielding -- are ineffective or unavailable.

Comments
16 pages, 10 figures

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We show that exchange symmetry in collisions of identical particles enables symmetry-protected coherent control of the total scattering cross section. For identical fermions, antisymmetrization enforces complete phase synchronization of the contributing scattering channels, yielding maximal control visibility. For identical bosons, synchronization persists but with reduced visibility due to additional exchange (satellite) contributions. Collisions of distinguishable particles lack this symmetry-imposed phase locking, leading to lower controllability and visibility. We elucidate these principles through coupled-channel quantum-scattering calculations for lithium-lithium collisions, comparing the 6Li^{6}\mathrm{Li}6Li-6Li^{6}\mathrm{Li}6Li (identical fermions), 7Li^{7}\mathrm{Li}7Li-7Li^{7}\mathrm{Li}7Li (identical bosons), and 6Li^{6}\mathrm{Li}6Li-7Li^{7}\mathrm{Li}7Li (distinguishable) systems. Furthermore, in the identical particle cases, symmetry-enforced synchronization enables full control over the parity of the final state at any collisional energy. This mechanism is broadly applicable to identical-particle collisions, including homonuclear molecules for which established approaches -- DC electric fields, or microwave shielding -- are ineffective or unavailable.
Quantum coherent control of bimolecular collisions beyond the ultracold regime can face a major challenge due to the incoherent addition of different partial wave contributions to the total scattering cross section. These contributions become increasingly numerous as the collision energy increases, leading to a loss of overall control. Here, we overcome this limitation by leveraging the recently discovered Partial Wave Phase Locking (PWPL) effect, which synchronizes the oscillations of all partial wave contributions. By using rigorous quantum scattering calculations, we demonstrate that PWPL enables coherent control of spin exchange in ion-atom collisions, far outside the ultracold regime, even with as many as 5000 partial wave contributions. The predicted extent of control is sufficient to be measurable in cold atom-ion hybrid experiments.
Coherent control of atomic and molecular scattering relies on the preparation of colliding particles in superpositions of internal states, establishing interfering pathways that can be used to tune the outcome of a scattering process. However, the incoherent addition of different partial wave contributions to the integral cross-sections, commonly encountered in systems with complex collisional dynamics, poses a significant challenge, often limiting the control. This work demonstrates that time-reversal symmetry can be used to overcome these limitations by constraining the relation between the S-matrix elements. For example, the preparation of a superposition of two states related by the time-reversal superposition can provide extensive control for transitions to a time-reversal invariant final state, such as the J = 0, M = 0. Using the example of ultracold O 2 –O 2 scattering, we show that for such states coherent control is robust against short-range dynamical complexity. Furthermore, the time-reversal symmetry also protects the control against a distribution of collisional energies. Beyond the ultracold regime, we observe significant differences in the controllability of crossed-molecular beam vs trap experiments with complete control achievable in the former case at any temperature, emphasizing the cooperative role of time-reversal and permutation symmetries in maintaining control at any temperature. These results open new avenues for the coherent control of complex inelastic collisions and chemical reactions both in and outside of the ultracold regime.
We show that quantum interference-based coherent control is a highly efficient tool for tuning ultracold molecular collision dynamics that is free from the limitations of commonly used methods that rely on external electromagnetic fields. By varying the relative populations and phases of initial coherent superpositions of degenerate molecular states, we demonstrate complete coherent control over integral scattering cross sections in the ultracold s-wave regime of both the initial and final collision channels. The proposed control methodology is applied to ultracold O_{2}+O_{2} collisions, showing extensive control over s-wave spin-exchange cross sections and product branching ratios over many orders of magnitude.
This chapter addresses the quantum mechanics of identical particles, emphasizing the role of wavefunction symmetry in determining statistical behavior. Symmetric and antisymmetric wavefunctions are defined, and the implications of particle indistinguishability are examined, particularly regarding how it influences measurable outcomes and the concept of energy exchange degeneracy. The distinguishability of identical particles is discussed and shown to affect specific calculations. For systems where particle interactions can be neglected in the zero-order approximation, the total energy eigenfunction is expressed as a product of single-particle eigenfunctions. The Pauli exclusion principle is derived as a consequence of antisymmetrization. The relationship between symmetry type (bosonic or fermionic) and quantum statistics is elaborated. As an illustration, the ground state and the first excited sss-state of the helium atom are analyzed under a simplified approximation. Metadata/Keywords: identical particles, symmetric wavefunction, antisymmetric wavefunction, Pauli exclusion principle, quantum statistics, energy exchange degeneracy, indistinguishability, helium atom, symmetry and statistics
The fundamental challenge of controlling binary collisions is addressed. Advanced scattering theory is employed to demonstrate that partial-wave phase locking (PWPL) effectively overcomes the challenges posed by random partial-wave contributions in ion-atom collisions (Sr+{}^{+}+-Rb), enabling robust coherent quantum control even beyond the ultracold regime.