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arXiv:2606.27392 · Stats

Statistics of Non-Conserved Observables in Lindblad Master Equations

Giovanni Modanese

Published Jun 25, 2026• 0 citations
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Abstract

We study the dynamics of observables that are conserved under the Hamiltonian evolution of a closed quantum system, but cease to be conserved when the system is coupled to a Markovian environment and described by a Lindblad master equation. Starting from the adjoint Lindblad equation, we derive elementary expressions for the time derivatives of the expectation value and second moment of an observable O, with particular emphasis on the case [H,O]=0 but L†(O)≠0. These formulae provide a direct assessment of how collapse operators break Hamiltonian conservation laws and generate fluctuations of formerly conserved quantities. The discussion is illustrated by analytic examples: one-qubit amplitude damping, a two-qubit excitation-number model, a momentum-diffusion model in which the mean is conserved while the variance grows, and the Jaynes–Cummings model. The latter also shows the complementary case of a reservoir coupled through a conserved quantity, where dephasing can occur without changing the statistics of that quantity. We finally comment on the relation between Lindblad source terms and idealized wave-function reduction models in which local conservation may hold only statistically.

DOI
10.3390/stats9040069

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We derive a fundamental conservation law of operator current for master equations describing reduced quantum systems. If this law is broken, the temporal integral of the current operator of an arbitrary system observable does not yield in general the change of that observable in the evolution. We study Lindblad-type master equations as examples and prove that the application of the secular approximation during their derivation results in a violation of the conservation law. We show that generally any violation of the law leads to artificial corrections to the complete quantum dynamics, thus questioning the accuracy of the particular master equation.
We study the role of correlations with the environment as the source of non-Markovian quantum evolutions. We first focus on the impact that correlations with the environment can have on the dynamical map that evolve the system. We expand the set of initial states of a system and its environment that are known to guarantee completely positive reduced dynamics for the system when the combined state evolves unitarily. We characterize the correlations in the initial state in terms of its quantum discord. The induced maps can be not completely positive when quantum correlations including, but not limited to, entanglement are present. We discuss the implications and limitations of the Markov approximation necessary to derive the Kossakowski-Lindblad master equation. A generalized non-Markovian master equation is derived from the dynamical map of systems correlated with their environment. The physical meaning of not completely positive maps is studied to obtain a consistent theory of non-Markovian quantum dynamics. These are associated to inverse maps necessary to establish correlations and they give rise to a canonical embedding map that is local in time. This master equation goes beyond the Kossakowski-Lindblad master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory. Through out this discussion, the general dynamics of two interacting qubits is used as an example for illustrations.
By exploiting the peculiarities of a recently introduced formalism for describing open quantum systems (the parametric representation with environmental coherent states) we derive an equation of motion for the reduced density operator of an open quantum system that has the same structure of the celebrated Gorini–Kossakowski–Sudarshan–Lindblad equation, but holds regardless of Markovianity being assumed. The operators in our result have explicit expressions in terms of the Hamiltonian describing the interactions with the environment, and can be computed once a specific model is considered. We find that, instead of a single set of Lindblad operators, in the general (non-Markovian) case there one set of Lindblad-like operators for each and every point of a symplectic manifold associated to the environment. This intricacy disappears under some assumptions (which are related to Markovianity and the classical limit of the environment), under which it is possible to recover the usual master-equation formalism. Finally, we find such Lindblad-like operators for two different models of a qubit in a bosonic environment, and show that in the classical limit of the environment their renown master equations are recovered.