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arXiv:1110.5427 · Physical Review A

Conservation law of operator current in open quantum systems

Juha Salmilehto, Paolo Solinas, Mikko Möttönen

Published Mar 7, 2012• 27 citations
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Abstract

We derive a fundamental conservation law of operator current for master equations describing reduced quantum systems. If this law is broken, the temporal integral of the current operator of an arbitrary system observable does not yield in general the change of that observable in the evolution. We study Lindblad-type master equations as examples and prove that the application of the secular approximation during their derivation results in a violation of the conservation law. We show that generally any violation of the law leads to artificial corrections to the complete quantum dynamics, thus questioning the accuracy of the particular master equation.

DOI
10.1103/physreva.85.032110

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We derive a fundamental conservation law of operator current for master equations describing reduced quantum systems. If this law is broken, the temporal integral of the current operator of an arbitrary system observable does not yield in general the change of that observable in the evolution. We study Lindblad-type master equations as examples and prove that the application of the secular approximation during their derivation results in a violation of the conservation law. We show that generally any violation of the law leads to artificial corrections to the complete quantum dynamics, thus questioning the accuracy of the particular master equation.
The Lindblad theory of open quantum systems has been successfully applied in various fields ranging from quantum optics, condensed matter physics, and quantum thermodynamics to quantum chemistry. Nevertheless, there are situations where we can compare its predictions to those of exact methods or numerically exact results and find discrepancies between them. One example is the case where a single harmonic oscillator is coupled to a thermal bath of independent harmonic oscillators. In this case, for certain parameters, the exact master equation describes equilibration of the system to a thermal state with a temperature different from the one predicted by the Lindblad master equation. The Lindblad theory, based on a weak coupling between the system and environment as well as the Born-Markov approximation, predicts that the system will evolve to a thermal state whose temperature is equal to the initial temperature of the bath. This result is a consequence of the Born approximation, which supposes that throughout the evolution, the bath only fluctuates around its initial equilibrium state. In this master thesis we study the validity of the Born approximation as well as its consistency with other approximations. By starting from a Hamiltonian for the total system we show that, if the the Born approximation is not invoked, the dynamics of the system is determined by a hierarchy of equations for matrices which can be used to reconstruct the reduced density matrix of the system. This hierarchy approach is fundamentally different from the standard approach, which describes the system dynamics with a weak-coupling master equation, because the hierarchy does not restrict the amount of entanglement possible between the system and the environment. Furthermore, we show how invoking the Born approximation reduces to the usual result and how a generalised ansatz, which we refer to as a generalised Born approximation, reduces the hierarchy to a master equation where the bath temperature is an additional degree of freedom. Finally, we analyse the conservation of the energy of the total system and its relationship to the Markov and secular approximations, and discuss whether imposing it as a condition can fix the time-dependent temperature.
We study the dynamics of observables that are conserved under the Hamiltonian evolution of a closed quantum system, but cease to be conserved when the system is coupled to a Markovian environment and described by a Lindblad master equation. Starting from the adjoint Lindblad equation, we derive elementary expressions for the time derivatives of the expectation value and second moment of an observable O, with particular emphasis on the case [H,O]=0 but L†(O)≠0. These formulae provide a direct assessment of how collapse operators break Hamiltonian conservation laws and generate fluctuations of formerly conserved quantities. The discussion is illustrated by analytic examples: one-qubit amplitude damping, a two-qubit excitation-number model, a momentum-diffusion model in which the mean is conserved while the variance grows, and the Jaynes–Cummings model. The latter also shows the complementary case of a reservoir coupled through a conserved quantity, where dephasing can occur without changing the statistics of that quantity. We finally comment on the relation between Lindblad source terms and idealized wave-function reduction models in which local conservation may hold only statistically.
We derive a nonperturbative bound on the distance between evolutions of open quantum systems described by time-dependent generators. We show how this result can be employed to provide an explicit upper bound on the error of the rotating-wave approximation in the presence of dissipation and decoherence. We apply the derived bound to the strong-coupling limit in open quantum systems and to the secular approximation used to obtain a master equation of the Gorini-Kossakowski-Lindblad-Sudarshan form from the Redfield master equation.
Abstract Quantum master equations are widely used to describe the dynamics of open quantum systems. All these different master equations rely on specific approximations that may or may not be justified. Starting from a microscopic model, applying the standard Born and Markov approximations results in the Redfield equation that does not guarantee to preserve positivity. The latter is typically achieved by additionally applying the secular approximation resulting in a quantum master equation in Lindblad form. There are other ways to obtain an equation in Lindblad form, one of which is the recently proposed universal Lindblad equation (ULE). It has been shown that it is in the same equivalence class of approximations as the Redfield master equation although avoiding the heuristic secular approximation (Nathan and Rudner 2020 Phys. Rev. B 102 115109). In this work, we prove that the solutions of the master equation obtained by applying the secular approximation are also obtained by an approximation of the same order as the one performed to obtain the Redfield equation. We hereby provide a mathematical justification for the secular approximation. We show that the result of applying the secular approximation is obtained naturally by applying a self-consistency argument. This shows that the resulting master equation is also in the same equivalence class of approximations as the Redfield master equation and the ULE. We furthermore give numerical considerations about the accuracy of the secular master equation compared to the ULE.
Master equations of Lindblad type have attained prominent status in the fields of quantum optics and quantum information since they are guaranteed to satisfy fundamental notions of quantum dynamics such as complete positivity. When Lindblad operators are used to describe thermal reservoirs in contact with an open quantum system, the fundamental laws of thermodynamics and the fluctuation‐dissipation theorem provide additional mandatory criteria. We show several examples of innocent‐looking Lindblad operators which have questionable properties in this regard. Compatibility criteria between Hamiltonian and Lindblad terms as well as consequences of their violation are discussed. An alternative stochastic approach to dissipative quantum dynamics is outlined and illustrated through a harmonic‐chain model for which the approach of local Lindblad operators fails.
Open quantum system dynamics is efficiently described by the quantum master equation formalism. Therein, quantum master equations in Lindblad form constitute an important subclass describing Markovian dynamics. When an open quantum system is in an out-of-equilibrium state, an exchange of particles between the open system and reservoirs takes place yielding to a non-zero average net current and associated current fluctuations, which can be characterised with the quantum jump formalism for quantum master equations expressed in Lindblad form. However, a large class of quantum master equations cannot be described by Lindblad dynamics. Here we assess the validity and the effectiveness of the quantum jump formalism when the dissipators in the quantum master equation describe a non-additive, open quantum system dynamics. We find that an additive unravelling of the non-additive quantum master equation does not generate a completely-positive dynamics in the scenario of perfect jump detection. Nevertheless, allowing for an imperfect jump detection scenario, we find that an additive unravelling is possible that reproduces the current and the fluctuations obtained via the Landauer-Büttiker formalism.