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arXiv:2606.01524

Magneto-optical characterization of GeSn and GeSn/SiGeSn heterostructures

Mehdi Ashrafganjoie, Kelvin Dsouza, Prithu Bhatnagar, Khalid Hossain, Mangal Dhoubhadel, Preston Webster, Simone Assali, Patrick Daoust, Oussama Moutanabbir, Shui-Qing Yu, Daryoosh Vashaee, Demitry Farfurnik

quant-phcond-mat.otherSubmitted Jun 1, 2026• Announced Jun 2, 2026
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Abstract

Hole spin qubits in germanium (Ge)-based heterostructures have demonstrated their potential for scalable quantum information processing using all-electrical gate operations. Furthermore, the emerging material platform of germanium-tin (GeSn) can feature a direct bandgap, which makes it promising for establishing spin-photon interfaces for quantum networking. Here, we perform magneto-photoluminescence measurements of a Ge0.88Sn0.12/Si0.02Ge0.89Sn0.09 double quantum well using the double modulation Fourier transform infrared-based photoluminescence spectroscopy. Our measurements reveal theoretically expected diamagnetic shift at low magnetic fields as well as the linear trend of zeroth-level Landau quantization at higher fields and Zeeman-induced polarization-dependent energy shifts at +/- 12 T. We extract an effective g-factor of ~ 2 and an excitonic reduced mass of ~ 0.04 me consistent with previous estimations for heavy-hole Γ-valley excitons. The observation of sizable Zeeman splitting is consistent with strong spin-orbit interaction in Ge-based hole systems, which can enable electrically driven spin control. Our analysis can be adopted for studying and evaluating group-IV semiconductor heterostructures as hosts for hole spin qubits toward scalable quantum information processing.

Related papers

Comparative assessment of germanium-based spin-qubit modalities: donor, acceptor, gate-defined hole, and gate-defined electron platforms

D. -M. Mei, K. -M. Dong, S. A. Panamaldeniya +4 more

High-purity germanium (Ge) has re-emerged as a versatile semiconductor platform for spin-based quantum information processing because it combines mature materials processing, access to spin-free isotopes, high mobilities, small effective masses, and strong but engineerable spin--orbit coupling. However, ``Ge qubits'' are not a single technology. Donor spin qubits, acceptor spin qubits, gate-defined hole spin qubits, and gate-defined electron spin qubits exploit different parts of the Ge band structure and therefore make distinct trade-offs among coherence, controllability, fabrication complexity, and scalability. Here we compare these four Ge-based spin-qubit modalities on a common physical and architectural footing. We review the shared Ge materials physics, including isotopic purification, the multivalley \(L\)-point conduction band, the spin-\(3/2\) valence band, heavy-hole/light-hole mixing, strain, interfaces, disorder, and phonons. We also introduce a common framework for estimating phononic-crystal-modified \(T_1\) using a calibrated reference relaxation rate, a geometry-dependent strain-density-of-states suppression factor, and parasitic relaxation channels. The comparison shows that gate-defined Ge hole-spin qubits currently offer the strongest combination of all-electrical control, demonstrated multiqubit operation, and scalability. Donor, acceptor, and gate-defined electron qubits remain important complementary directions for memory, hybrid, and exploratory architectures. Overall, Ge supports a diverse qubit ecosystem, with gate-defined hole-spin qubits presently providing the clearest path toward scalable Ge-based quantum processors.

quant-pharXiv:2605.13680•May 14, 2026

Circuit Quantum Electrodynamics and Spin Qubits with Multi-Hole Quantum Dots in planar Germanium

Franco De Palma

Spin qubits in semiconductor quantum dots constitute one of the leading platforms for quantum information processing, combining long coherence times, high-fidelity gate operations, and compatibility with semiconductor industry technologies. In particular, holes confined in planar Ge/SiGe heterostructures have recently emerged as promising qubit candidates owing to their low effective mass, high mobility, low percolation density, absence of valley states, and strong spin-orbit interaction, which enables fast all-electrical spin control. At the same time, spin-orbit interaction also gives rise to a highly anisotropic and electrically tunable gyromagnetic response. Understanding and controlling this response is therefore essential for high-fidelity single- and multi-qubit operations. The realization of scalable quantum processors also requires efficient qubit readout and long-range connectivity. Circuit quantum electrodynamics (cQED), based on the coupling between artificial atoms and microwave photons confined in superconducting resonators, provides a natural framework to address these challenges. However, the implementation of hybrid semiconductor-superconductor devices in planar Ge has so far been hindered by large microwave losses originating from the heterostructure. In this thesis, we demonstrate, for the first time in planar Ge, strong coupling between a hole charge qubit in a double quantum dot and a high-impedance microwave resonator, reaching a cooperativity of C â 100. In addition, we leverage the frequency tunability of the resonator to perform detailed spectroscopy of a multi-level energy spectrum of low-lying states arising from strong Coulomb-correlation effects. To further improve the quality of the hole-photon interface, we investigate the source of microwave losses in different Ge/SiGe heterostructures, identifying defects at the lattice-mismatched Si/Ge interface as the dominant source of resonator losses in reverse-graded heterostructures. To mitigate this limitation, a deep tapered-etching approach is introduced, enabling the fabrication of superconducting resonators directly on etched heterostructures. This method yields internal quality factors exceeding Qint > 10 000 for high-impedance Josephson junction array resonators and Qint > 100 000 for 50 â Nb resonators. Finally, this thesis explores the spin properties of multi-hole quantum dots beyond the conventional single-orbital picture. By reconstructing and electrically tuning the g tensors of holes confined in different orbital states, we show that confinement can substantially modify both their magnitude and orientation. These results open new opportunities for engineering qubit properties through orbital occupation. Furthermore, highly coherent singlet-triplet oscillations are demonstrated in the seven-hole regime, yielding a quality factor of approximately 330 at in-plane magnetic fields as low as 2.5 mT. Together, these results establish a foundation for high-fidelity hole-spin-qubit operation based on g-tensor engineering and for the integration of planar Ge quantum dots with superconducting quantum circuits.

•Jan 1, 2026•0 citations

Switchable heavy-hole/light-hole spin qubit

Zoltán György, Dmitry Miserev, Jelena Klinovaja +1 more

Compressively strained Ge quantum wells in planar SiGe/Ge heterostructures are the state-of-the-art platform for hole spin qubits. While they exhibit robust coherence times, they possess weak intrinsic spin-orbit interaction (SOI) due to the heavy-hole (HH) character of the wavefunction. Recently, light-hole (LH) qubits were proposed in GeSn/Ge heterostructures, offering strong, intrinsic, linear-in-momentum SOI. In this work, we propose a switchable HH-LH spin qubit in a bilayer Ge heterostructure with SiGeSn barriers, combining the advantages of HH and LH devices. The character of the qubit can be changed by shuttling from an LH well to an HH well, which also enables fast, hopping-based single-qubit rotations. Additionally, we observe an HH-LH resonance introduced by the in-plane confinement, resulting in $g$-factor peaks and first-order charge noise sweet spots. Our calculations reveal a sweet spot with Rabi frequencies on the order of 100 MHz, comparable to the LH regime, but with a more than tenfold increase in coherence time, on the order of 100 $μ$s.

cond-mat.mes-hallCross-listedarXiv:2608.25914•Aug 27, 2026

Superfast hole spin qubits enabled by uniaxial strain-boosted spin-orbit coupling

Yi-Xu Wang, Yang Liu, Shan Guan +2 more

Two-dimensional (2D) electron/hole gases confined in semiconductor heterostructures suffer from weak Rashba spin-orbit coupling (SOC) for manipulating spin degreee of freedom via an electric rather than a magnetic field. Here, we show that complementary metal-oxide-semiconductor technology-accessible strain could substantially enhance the linear Rashba SOC of the top hole subband in Ge/SiGe quantum wells (QWs) to a level comparable to that of 2D Rashba materials through enhancing the mixture of the light-hole and heavy-hole bands. We further show that strongly enhanced Rashba SOC boosts the Rabi frequency of hole spin qubits confined in Ge/SiGe QWs by two orders of magnitude to an unprecedented 40 GHz, more than one order of magnitude faster than other qubit platforms. We also demonstrate that the hole spin rotation with Rabi frequency > 25 GHz enters a new regime being immune to gate control-induced electric noise, opening a new avenue to simultaneously improve the gate speed and gate fidelity. Our findings provide a new routine to substantially enhance the Rashba SOC in 2D semiconductor hole gases to a level that is great for spintronic applications.

cond-mat.mes-hallCross-listedarXiv:2608.18483•Aug 20, 2026

Light-hole gate-defined spin-orbit qubit

Patrick Del Vecchio, Oussama Moutanabbir

The selective confinement of light holes (LHs) is demonstrated by introducing a low-dimensional system consisting of a highly tensile-strained Ge quantum well enabling the design of an ultrafast gate-defined spin qubit under the electric dipole spin resonance. The qubit size-dependent $g$ factor and dipole moment are mapped, and the parameters inducing their modulation are discussed. It is found that the LH qubit dipole moment is two to three orders of magnitude higher than that of the canonical heavy-hole qubit. This behavior originates from the significant spin splitting resulting from the combined action of large cubic and linear Rashba spin-orbit interactions that are peculiar to LHs. The qubit relaxation rate is also affected by the strong spin-orbit interaction and follows typically a ${B}^{7}$ behavior. The proposed all-group IV, direct band-gap LH qubit provides an effective platform for a scalable qubit-optical photon interface sought after for long-range entanglement distribution and quantum networks.

arXiv:2211.10514•Physical review. B./Physical review. B•Apr 10, 2023•13 citations

Light-Hole Spin Qubits in Strained SiGe Lattice-Matched to Ge

Edmondo Valvo, Davide Costa, Patrick Del Vecchio +3 more

Strained germanium ($\varepsilon$-Ge) quantum wells on metamorphic SiGe buffers have enabled advanced hole-based spin qubit devices. Alternatively, unstrained Ge with lattice-matched strained silicon-germanium ($\varepsilon$-SiGe) barriers eliminates the need for metamorphic buffers altogether. The ground state character of both these platforms is predominantly heavy-hole (HH) with a largely anisotropic spin response. We propose and study an alternative heterostructure, lattice-matched to Ge, in which both the SiGe quantum well and barriers are tensile strained, with their composition contrast providing the band offset for confinement and the tensile strain stabilizing a light-hole (LH) ground state. We show large spin-orbit coupling (SOC), both linear and cubic, along with a significantly more isotropic spin response compared to strained HH qubits. We also study the decoherence properties of the proposed device, showing an appreciable gain in the quality factor compared to their HH counterparts. Finally, we propose a bilayer heterostructure that allows for electrical switching between HH and LH ground state character.

cond-mat.mes-hallCross-listedarXiv:2608.25852•Aug 27, 2026
Hole spin qubits in germanium (Ge)-based heterostructures have demonstrated their potential for scalable quantum information processing using all-electrical gate operations. Furthermore, the emerging material platform of germanium-tin (GeSn) can feature a direct bandgap, which makes it promising for establishing spin-photon interfaces for quantum networking. Here, we perform magneto-photoluminescence measurements of a Ge0.88Sn0.12/Si0.02Ge0.89Sn0.09 double quantum well using the double modulation Fourier transform infrared-based photoluminescence spectroscopy. Our measurements reveal theoretically expected diamagnetic shift at low magnetic fields as well as the linear trend of zeroth-level Landau quantization at higher fields and Zeeman-induced polarization-dependent energy shifts at +/- 12 T. We extract an effective g-factor of ~ 2 and an excitonic reduced mass of ~ 0.04 me consistent with previous estimations for heavy-hole Γ-valley excitons. The observation of sizable Zeeman splitting is consistent with strong spin-orbit interaction in Ge-based hole systems, which can enable electrically driven spin control. Our analysis can be adopted for studying and evaluating group-IV semiconductor heterostructures as hosts for hole spin qubits toward scalable quantum information processing.
High-purity germanium (Ge) has re-emerged as a versatile semiconductor platform for spin-based quantum information processing because it combines mature materials processing, access to spin-free isotopes, high mobilities, small effective masses, and strong but engineerable spin--orbit coupling. However, ``Ge qubits'' are not a single technology. Donor spin qubits, acceptor spin qubits, gate-defined hole spin qubits, and gate-defined electron spin qubits exploit different parts of the Ge band structure and therefore make distinct trade-offs among coherence, controllability, fabrication complexity, and scalability. Here we compare these four Ge-based spin-qubit modalities on a common physical and architectural footing. We review the shared Ge materials physics, including isotopic purification, the multivalley LLL-point conduction band, the spin-3/23/23/2 valence band, heavy-hole/light-hole mixing, strain, interfaces, disorder, and phonons. We also introduce a common framework for estimating phononic-crystal-modified T1T_1T1​ using a calibrated reference relaxation rate, a geometry-dependent strain-density-of-states suppression factor, and parasitic relaxation channels. The comparison shows that gate-defined Ge hole-spin qubits currently offer the strongest combination of all-electrical control, demonstrated multiqubit operation, and scalability. Donor, acceptor, and gate-defined electron qubits remain important complementary directions for memory, hybrid, and exploratory architectures. Overall, Ge supports a diverse qubit ecosystem, with gate-defined hole-spin qubits presently providing the clearest path toward scalable Ge-based quantum processors.
Spin qubits in semiconductor quantum dots constitute one of the leading platforms for quantum information processing, combining long coherence times, high-fidelity gate operations, and compatibility with semiconductor industry technologies. In particular, holes confined in planar Ge/SiGe heterostructures have recently emerged as promising qubit candidates owing to their low effective mass, high mobility, low percolation density, absence of valley states, and strong spin-orbit interaction, which enables fast all-electrical spin control. At the same time, spin-orbit interaction also gives rise to a highly anisotropic and electrically tunable gyromagnetic response. Understanding and controlling this response is therefore essential for high-fidelity single- and multi-qubit operations. The realization of scalable quantum processors also requires efficient qubit readout and long-range connectivity. Circuit quantum electrodynamics (cQED), based on the coupling between artificial atoms and microwave photons confined in superconducting resonators, provides a natural framework to address these challenges. However, the implementation of hybrid semiconductor-superconductor devices in planar Ge has so far been hindered by large microwave losses originating from the heterostructure. In this thesis, we demonstrate, for the first time in planar Ge, strong coupling between a hole charge qubit in a double quantum dot and a high-impedance microwave resonator, reaching a cooperativity of C â 100. In addition, we leverage the frequency tunability of the resonator to perform detailed spectroscopy of a multi-level energy spectrum of low-lying states arising from strong Coulomb-correlation effects. To further improve the quality of the hole-photon interface, we investigate the source of microwave losses in different Ge/SiGe heterostructures, identifying defects at the lattice-mismatched Si/Ge interface as the dominant source of resonator losses in reverse-graded heterostructures. To mitigate this limitation, a deep tapered-etching approach is introduced, enabling the fabrication of superconducting resonators directly on etched heterostructures. This method yields internal quality factors exceeding Qint > 10 000 for high-impedance Josephson junction array resonators and Qint > 100 000 for 50 â Nb resonators. Finally, this thesis explores the spin properties of multi-hole quantum dots beyond the conventional single-orbital picture. By reconstructing and electrically tuning the g tensors of holes confined in different orbital states, we show that confinement can substantially modify both their magnitude and orientation. These results open new opportunities for engineering qubit properties through orbital occupation. Furthermore, highly coherent singlet-triplet oscillations are demonstrated in the seven-hole regime, yielding a quality factor of approximately 330 at in-plane magnetic fields as low as 2.5 mT. Together, these results establish a foundation for high-fidelity hole-spin-qubit operation based on g-tensor engineering and for the integration of planar Ge quantum dots with superconducting quantum circuits.
Compressively strained Ge quantum wells in planar SiGe/Ge heterostructures are the state-of-the-art platform for hole spin qubits. While they exhibit robust coherence times, they possess weak intrinsic spin-orbit interaction (SOI) due to the heavy-hole (HH) character of the wavefunction. Recently, light-hole (LH) qubits were proposed in GeSn/Ge heterostructures, offering strong, intrinsic, linear-in-momentum SOI. In this work, we propose a switchable HH-LH spin qubit in a bilayer Ge heterostructure with SiGeSn barriers, combining the advantages of HH and LH devices. The character of the qubit can be changed by shuttling from an LH well to an HH well, which also enables fast, hopping-based single-qubit rotations. Additionally, we observe an HH-LH resonance introduced by the in-plane confinement, resulting in ggg-factor peaks and first-order charge noise sweet spots. Our calculations reveal a sweet spot with Rabi frequencies on the order of 100 MHz, comparable to the LH regime, but with a more than tenfold increase in coherence time, on the order of 100 μμμs.
Two-dimensional (2D) electron/hole gases confined in semiconductor heterostructures suffer from weak Rashba spin-orbit coupling (SOC) for manipulating spin degreee of freedom via an electric rather than a magnetic field. Here, we show that complementary metal-oxide-semiconductor technology-accessible strain could substantially enhance the linear Rashba SOC of the top hole subband in Ge/SiGe quantum wells (QWs) to a level comparable to that of 2D Rashba materials through enhancing the mixture of the light-hole and heavy-hole bands. We further show that strongly enhanced Rashba SOC boosts the Rabi frequency of hole spin qubits confined in Ge/SiGe QWs by two orders of magnitude to an unprecedented 40 GHz, more than one order of magnitude faster than other qubit platforms. We also demonstrate that the hole spin rotation with Rabi frequency > 25 GHz enters a new regime being immune to gate control-induced electric noise, opening a new avenue to simultaneously improve the gate speed and gate fidelity. Our findings provide a new routine to substantially enhance the Rashba SOC in 2D semiconductor hole gases to a level that is great for spintronic applications.
The selective confinement of light holes (LHs) is demonstrated by introducing a low-dimensional system consisting of a highly tensile-strained Ge quantum well enabling the design of an ultrafast gate-defined spin qubit under the electric dipole spin resonance. The qubit size-dependent ggg factor and dipole moment are mapped, and the parameters inducing their modulation are discussed. It is found that the LH qubit dipole moment is two to three orders of magnitude higher than that of the canonical heavy-hole qubit. This behavior originates from the significant spin splitting resulting from the combined action of large cubic and linear Rashba spin-orbit interactions that are peculiar to LHs. The qubit relaxation rate is also affected by the strong spin-orbit interaction and follows typically a B7{B}^{7}B7 behavior. The proposed all-group IV, direct band-gap LH qubit provides an effective platform for a scalable qubit-optical photon interface sought after for long-range entanglement distribution and quantum networks.
Strained germanium (ε\varepsilonε-Ge) quantum wells on metamorphic SiGe buffers have enabled advanced hole-based spin qubit devices. Alternatively, unstrained Ge with lattice-matched strained silicon-germanium (ε\varepsilonε-SiGe) barriers eliminates the need for metamorphic buffers altogether. The ground state character of both these platforms is predominantly heavy-hole (HH) with a largely anisotropic spin response. We propose and study an alternative heterostructure, lattice-matched to Ge, in which both the SiGe quantum well and barriers are tensile strained, with their composition contrast providing the band offset for confinement and the tensile strain stabilizing a light-hole (LH) ground state. We show large spin-orbit coupling (SOC), both linear and cubic, along with a significantly more isotropic spin response compared to strained HH qubits. We also study the decoherence properties of the proposed device, showing an appreciable gain in the quality factor compared to their HH counterparts. Finally, we propose a bilayer heterostructure that allows for electrical switching between HH and LH ground state character.