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arXiv:2605.26818

Nonclassical energy-change distribution as a witness of non-Markovian quantum dynamics

Marco Pezzutto, Anton Corr, Gabriele De Chiara, Salvatore Lorenzo, Stefano Gherardini

quant-phcond-mat.stat-mechSubmitted May 26, 2026• Announced May 27, 2026• 0 citations
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Abstract

We address the problem of identifying non-Markovian quantum time evolutions of an open quantum system by only performing measurements of the system's energy. We demonstrate that violations of CP-divisibility are always witnessed by non-positive values of the energy-change Kirkwood-Dirac quasiprobability distribution associated with the system's Hamiltonian, evaluated at consecutive times. The link between non CP-divisibility and non-positivity of the system's energy-change distribution is stronger when the system-environment interactions are energy-preserving. The witness works whenever anomalous energy fluxes, due to non-Markovianity, are realized. Anomalous fluxes are also detected by the non-Markovianity measure built over the quantum mutual information between the states of the open system and of a quantum correlated reference.

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We address the problem of identifying non-Markovian quantum time evolutions of an open quantum system by only performing measurements of the system's energy. We demonstrate that violations of CP-divisibility are always witnessed by non-positive values of the energy-change Kirkwood-Dirac quasiprobability distribution associated with the system's Hamiltonian, evaluated at consecutive times. The link between non CP-divisibility and non-positivity of the system's energy-change distribution is stronger when the system-environment interactions are energy-preserving. The witness works whenever anomalous energy fluxes, due to non-Markovianity, are realized. Anomalous fluxes are also detected by the non-Markovianity measure built over the quantum mutual information between the states of the open system and of a quantum correlated reference.
Quantum non-Markovianity of a quantum noisy channel is typically identified with information backflow or, more generally, with departure of the intermediate map from complete positivity. But here, we also indicate certain non-Markovian channels that cannot be witnessed by the CP-divisibility criterion. In complex systems, non-Markovianity becomes more involved on account of subsystem dynamics. Here we study various facets of non-Markovian evolution, in the context of coined quantum walks, with particular stress on disambiguating the internal vs. environmental contributions to non-Markovian backflow. For the above problem of disambiguation, we present a general power-spectral technique based on a distinguishability measure such as trace-distance or correlation measure such as mutual information. We also study various facets of quantum correlations in the transition from quantum to classical random walks, under the considered non-Markovian noise models. The potential for the application of this analysis to the quantum statistical dynamics of complex systems is indicated.
We investigate the ability of correlation measures to witness non-Markovian open-quantum-system dynamics. It is shown that the mutual information and any entanglement measure between the system and an ancilla do not witness all non-Markovian dynamics. A correlation measure is introduced, and it is proven that, in an enlarged setting with two ancillary systems, this measure detects almost all non-Markovian dynamics, except possibly a zero-measure set of dynamics that is nonbijective in finite time intervals. Our proof is constructive and provides different initial states detecting the non-Markovian evolutions. These states are all separable and some are arbitrarily close to a product state. A further advantage of the introduced correlation measure is that it can be efficiently computed through semidefinite programming.
Abstract We determine the Kirkwood–Dirac quasiprobability (KDQ) distribution associated to the stochastic instances of internal energy variations for the quantum system and environment particles in coherent Markovian collision models. In the case the interactions between the quantum system and the particles do not conserve energy, the KDQ of the non-energy-preserving stochastic work is also derived. These KDQ distributions can account for non-commutativity, and return the unperturbed average values and variances for a generic interaction-time, and generic local initial states of the quantum system and environment particles. Using this nonequilibrium-physics approach, we certify the conditions under which the collision process of the model exhibits quantum traits, and we quantify the rate of energy exchanged by the quantum system by looking at the variance of the KDQ energy distributions. Finally, we propose an experimental test of our results on a superconducting quantum circuit implementing a qubit system, with microwave photons representing the environment particles.
Non-Markovian effects in an open-system dynamics are usually associated to information backflows from the environment to the system. However, the way these backflows manifest and how to detect them is unclear. A natural approach is to study the backflow in terms of the correlations the evolving system displays with another unperturbed system during the dynamics. In this work, we study the power of this approach to witness non-Markovian dynamics using different correlation measures. We identify simple dynamics where the failure of completely positive divisibility is in one-to-one correspondence with a correlation backflow. We then focus on specific correlation measures, such as those based on entanglement and the mutual information, and identify their strengths and limitations. We conclude with a study of a recently introduced correlation measures based on state distinguishability and see how, for these measures, adding an extra auxiliary system enlarges the set of detectable non-Markovian dynamics.
The Kolmogorov consistency condition (KCC) defines the statistical boundary between classical and quantum dynamics. Its violation signifies the breakdown of a classical Markov description of temporal correlations. In this work, we establish a direct analytical connection between KCC violation and non-Markovianity in open quantum dynamics, revealing how memory effects manifest as departures from classical probabilistic consistency. Within a generic two-level open quantum system framework, we establish quantitative connections between the magnitude of KCC violation and key information-theoretic and thermodynamic quantities, such as mutual information, the Fano factor, heat exchange, and entropy production rate, thereby enabling a thermodynamic interpretation of temporal quantum correlations. Furthermore, we uncover formal correspondences between KCC violation, the Leggett-Garg inequality, and the negativity of the Kirkwood-Dirac quasi-distribution, identifying them as complementary witnesses of temporal quantum non-classicality. Our results thus provide a unified framework linking information-theoretic, thermodynamic, and temporal indicators of quantumness in open quantum systems.
We show the connection between a witness that detects dynamical maps with initial system-environment correlations and a witness that detects non-Markovian open quantum systems. Our analysis is based on studying the role that state preparation plays in witnessing violations of contractivity of open-quantum-system dynamics. Contractivity is a property of some quantum processes where the trace distance of density matrices decrease with time. From this, we show how a witness of initial correlations is an upper bound to a witness of non-Markovianity. We discuss how this relationship shows further connections between initial system-environment correlations and non-Markovianity, at an instance of time, in open quantum systems.