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arXiv:2503.07759 · Quantum Science and Technology

Non-positive energy quasidistributions in coherent collision models

Marco Pezzutto, Gabriele De Chiara, Stefano Gherardini

Published Jul 10, 2025• 4 citations
arXivHTMLPDF

Abstract

Abstract We determine the Kirkwood–Dirac quasiprobability (KDQ) distribution associated to the stochastic instances of internal energy variations for the quantum system and environment particles in coherent Markovian collision models. In the case the interactions between the quantum system and the particles do not conserve energy, the KDQ of the non-energy-preserving stochastic work is also derived. These KDQ distributions can account for non-commutativity, and return the unperturbed average values and variances for a generic interaction-time, and generic local initial states of the quantum system and environment particles. Using this nonequilibrium-physics approach, we certify the conditions under which the collision process of the model exhibits quantum traits, and we quantify the rate of energy exchanged by the quantum system by looking at the variance of the KDQ energy distributions. Finally, we propose an experimental test of our results on a superconducting quantum circuit implementing a qubit system, with microwave photons representing the environment particles.

DOI
10.1088/2058-9565/aded2e

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Abstract We determine the Kirkwood–Dirac quasiprobability (KDQ) distribution associated to the stochastic instances of internal energy variations for the quantum system and environment particles in coherent Markovian collision models. In the case the interactions between the quantum system and the particles do not conserve energy, the KDQ of the non-energy-preserving stochastic work is also derived. These KDQ distributions can account for non-commutativity, and return the unperturbed average values and variances for a generic interaction-time, and generic local initial states of the quantum system and environment particles. Using this nonequilibrium-physics approach, we certify the conditions under which the collision process of the model exhibits quantum traits, and we quantify the rate of energy exchanged by the quantum system by looking at the variance of the KDQ energy distributions. Finally, we propose an experimental test of our results on a superconducting quantum circuit implementing a qubit system, with microwave photons representing the environment particles.
We consider a collision model representation of nonequilibrium dynamics for an externally driven open quantum system. Specifically we investigate the nondemolition quasiprobability distributions (QPDFs) of work and heat in both Markovian and non-Markovian regimes. In this model, work and heat correspond to different evolution processes, and their contributions can be distinguished. For the system state with initial coherence, in both Markovian and non-Markovian regimes, negative quasiprobabilities at half of the energy gap of the system for work and the variation of internal energy appear, which is considered to be a witness of the quantumness of the system. We also find that when the external driving speed slows down, the quantumness of the system is weakened, and when the driving speed is slow enough, the negative quasiprobability will disappear and the results of the QPDF coincide with those of the two-measurement protocol. Most importantly, we find that non-Markovianity can enhance the quantumness of the system.
We address the problem of identifying non-Markovian quantum time evolutions of an open quantum system by only performing measurements of the system's energy. We demonstrate that violations of CP-divisibility are always witnessed by non-positive values of the energy-change Kirkwood-Dirac quasiprobability distribution associated with the system's Hamiltonian, evaluated at consecutive times. The link between non CP-divisibility and non-positivity of the system's energy-change distribution is stronger when the system-environment interactions are energy-preserving. The witness works whenever anomalous energy fluxes, due to non-Markovianity, are realized. Anomalous fluxes are also detected by the non-Markovianity measure built over the quantum mutual information between the states of the open system and of a quantum correlated reference.
In a multi-level quantum system Fano coherences stand for the formation of quantum coherences due to the interaction with the continuum of modes characterizing an incoherent process. In this paper we propose a V-type three-level quantum system on which we certify the presence of genuinely quantum traits underlying the generation of Fano coherences. We do this by determining work conditions that allows for the loss of positivity of the Kirkwood-Dirac quasiprobability distribution of the stochastic energy changes within the discrete system. We also show the existence of nonequilibrium regimes where the generation of Fano coherences leads to a non-negligible excess energy given by the amount of energy that is left over with respect to the energy of the system at the beginning of the transformation. Excess energy is attained provided the initial state of the discrete system is in a superposition of the energy eigenbasis. We conclude the paper by studying the thermodynamic efficiency of the whole process.
Recent work has revealed the central role played by the Kirkwood-Dirac quasiprobability (KDQ) as a tool to properly account for non-classical features in the context of condensed matter physics (scrambling, dynamical phase transitions) metrology (standard and post-selected), thermodynamics (power output and fluctuation theorems), foundations (contextuality, anomalous weak values) and more. Given the growing relevance of the KDQ across the quantum sciences, our aim is two-fold: First, we highlight the role played by quasiprobabilities in characterizing the statistics of quantum observables and processes in the presence of measurement incompatibility. In this way, we show how the KDQ naturally underpins and unifies quantum correlators, quantum currents, Loschmidt echoes, and weak values. Second, we provide novel theoretical and experimental perspectives by discussing a wide variety of schemes to access the KDQ and its non-classicality features.
We investigate the non-equilibrium work statistics originating from a sudden quench in a bosonic Josephson junction. In particular, by employing the Holstein-Primakoff approximation, the work statistics are analytically characterized in the weak-interaction regime, where the dynamics map onto a time-dependent quantum harmonic oscillator. For a junction initialized in the ground state of the pre-quench Hamiltonian, we demonstrate that the work statistics are governed by a negative binomial distribution, as occurs in fully-connected models driven across a critical point. Furthermore, we also consider initial superposition states containing quantum coherences in the energy basis. To characterize the corresponding work distributions, we employ Kirkwood-Dirac quasiprobabilities (KDQ). Even in the simplest case, when the junction is initialized in a superposition of the ground and second excited states, the KDQ distribution of work exhibits negative or complex values, reflecting non-classical features. Moreover, the coherence content of the initial state can be optimized to enhance the extractable work extracted from the quench, beyond classical bounds. Finally, we propose an experimental interferometric protocol to directly measure the characteristic function of the work distribution in experimentally accessible settings.
We investigate the irreversible entropy production of a qubit in contact with an environment modelled by a microscopic collision model in both Markovian and non-Markovian regimes. Our main goal is to contribute to the discussions on the relationship between non-Markovian dynamics and negative entropy production rates. We employ two different types of collision models that do or do not keep the correlations established between the system and the incoming environmental particle, while both of them pertain to their non-Markovian nature through information backflow from the environment to the system. We observe that as the former model, where the correlations between the system and environment are preserved, gives rise to negative entropy production rates in the transient dynamics, the latter one always maintains positive rates, even though the convergence to the steady-state value is slower as compared to the corresponding Markovian dynamics. Our results suggest that the mechanism underpinning the negative entropy production rates is not solely non-Markovianity through information backflow, but rather the contribution to it through established system-environment correlations.