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arXiv:2605.23197

Anomalous Decay of Quantum Resources: The Entanglement Sudden Death Mpemba Effect

Zhilong Liu, Zehua Tian, Jieci Wang

quant-phgr-qcSubmitted May 22, 2026• Announced May 25, 2026• 0 citations• Revised Jun 9, 2026 (v2)
v1 · May 22, 2026v2 · Jun 9, 2026v3 · Jun 15, 2026v4 · Oct 29, 2026
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Abstract

In classical thermodynamics, the Mpemba effect refers to the counterintuitive observation that hot water can freeze faster than cold water, manifesting as an anomalous crossing of dynamical trajectories. While analogues of this phenomenon have been explored in open quantum systems and spin-chain entanglement asymmetry, its connection to the finite-time decoupling of quantum correlations remains elusive. In this Letter, we uncover a distinct quantum Mpemba effect associated with entanglement sudden death (ESD). By analyzing two qubits interacting with local amplitude damping reservoirs, we demonstrate that a more strongly entangled initial state can experience a faster collapse into a separable state than a more weakly entangled one. This anomalous decay stems from the competition between initial coherence and excited-state population, where the latter acts as a catalyst for entanglement sudden death. We provide exact analytical derivations for the trajectory crossover and ESD time, and map the phase diagram to precisely identify the parameter regime where the effect occurs. Our results offer a new strategy for controlling the lifetime of quantum resources in dissipative environments.

Comments
7 pages, 5 figures

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In classical thermodynamics, the Mpemba effect refers to the counterintuitive observation that hot water can freeze faster than cold water, manifesting as an anomalous crossing of dynamical trajectories. While analogues of this phenomenon have been explored in open quantum systems and spin-chain entanglement asymmetry, its connection to the finite-time decoupling of quantum correlations remains elusive. In this Letter, we uncover a distinct quantum Mpemba effect associated with entanglement sudden death (ESD). By analyzing two qubits interacting with local amplitude damping reservoirs, we demonstrate that a more strongly entangled initial state can experience a faster collapse into a separable state than a more weakly entangled one. This anomalous decay stems from the competition between initial coherence and excited-state population, where the latter acts as a catalyst for entanglement sudden death. We provide exact analytical derivations for the trajectory crossover and ESD time, and map the phase diagram to precisely identify the parameter regime where the effect occurs. Our results offer a new strategy for controlling the lifetime of quantum resources in dissipative environments.
The Mpemba effect (ME)—where hot systems cool faster than colder ones—has intrigued both classical and quantum thermodynamics. Compared to classical systems, quantum systems add complexity due to quantum correlations. Recent works have explored anomalous relaxation and Mpemba-like effects in several quantum systems, considering isolated systems at zero temperature or open systems in contact with reservoirs under Markovian or non-Markovian dynamics. However, these models typically assume an initial unentangled system–bath state, overlooking the role of initial system–environment correlations. Here we propose a type of quantum ME, distinct from the strong ME, originating solely from initial system–bath entanglement. It is shown that the degree of initial entanglement significantly influences the early relaxation dynamics, with certain conditions causing backflow and retarded thermalization. As an example, we investigate the spontaneous emission of a two-level atom in a photonic waveguide at zero temperature, where an initial atom-photon entangled state results in delayed relaxation and a pronounced ME. These findings highlight the crucial role of quantum correlations in thermalization processes and open new avenues for identifying and engineering quantum Mpemba phenomena. Controlling relaxation dynamics through system–environment entanglement may have potential applications in quantum thermal machines, state initialization protocols, and quantum information processing, where precise control over thermalization is essential.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
The highly complicated nature of far from equilibrium systems can lead to a complete breakdown of the physical intuition developed in equilibrium. A famous example of this is the Mpemba effect, which states that nonequilibrium states may relax faster when they are further from equilibrium or, put another way, hot water can freeze faster than warm water. Despite possessing a storied history, the precise criteria and mechanisms underpinning this phenomenon are still not known. Here, we study a quantum version of the Mpemba effect that takes place in closed many-body systems with a U(1) conserved charge: in certain cases a more asymmetric initial configuration relaxes and restores the symmetry faster than a more symmetric one. In contrast to the classical case, we establish the criteria for this to occur in arbitrary integrable quantum systems using the recently introduced entanglement asymmetry. We describe the quantum Mpemba effect in such systems and relate the properties of the initial state, specifically its charge fluctuations, to the criteria for its occurrence. These criteria are expounded using exact analytic and numerical techniques in several examples, a free fermion model, the Rule 54 cellular automaton, and the Lieb-Liniger model.
The quantum Mpemba effect is the counterintuitive phenomenon whereby a quantum state initially farther from equilibrium relaxes faster than one initially closer to it. We demonstrate this effect in random Clifford circuits with a conserved U(1)\mathrm{U}(1)U(1) charge, using the entanglement asymmetry to characterize relaxation through dynamical symmetry restoration. Exact numerical simulations show that an initially more asymmetric state can become locally more symmetric than an initially less asymmetric one. We explain this behavior by mapping the dynamics onto a charge-conserving quantum automaton, in which the decay of the entanglement asymmetry is controlled by the statistics of encounters between two particle species evolving according to a symmetric simple exclusion process. This mapping yields an analytic expression for the entanglement asymmetry and provides a simple microscopic mechanism for the quantum Mpemba effect: stronger initial symmetry breaking corresponds to a denser particle configuration, which enhances the frequency of particle encounters and thereby accelerates symmetry restoration.
The Mpemba effect has initially been noticed in macroscopic systems-namely that hot water can freeze faster than cold water-but recently its extension to open quantum systems has attracted significant attention. This phenomenon can be explained in the context of nonequilibrium thermodynamics of Markovian systems, relying on the amplitudes of different decay modes of the system dynamics. Here, we study the Mpemba effect in a single-level quantum dot coupled to a thermal bath, highlighting the role of the sign and magnitude of the electron-electron interaction in the occurrence of the Mpemba effect. We gain physical insights into the decay modes from a dissipative symmetry of this system called fermionic duality. Based on this analysis of the relaxation to equilibrium of the dot, we derive criteria for the occurrence of the Mpemba effect using two thermodynamically relevant measures of the distance to equilibrium, the nonequilibrium free energy and the dot energy. We furthermore compare this effect to a possible exponential speedup of the relaxation. Finally, we propose experimentally relevant schemes for the state preparation and explore different ways of observing the Mpemba effect in quantum dots in experiments.
An ancient and counterintuitive phenomenon known as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for speeding up relaxation is an important but challenging task in purely quantum system till now. Here, we experimentally study the strong Mpemba effect in a single trapped ion system in which an exponentially accelerated relaxation in time is observed by preparing an optimal quantum initial state with no excitation of the slowest decaying mode. Also, we demonstrate that the condition of realizing such effect coincides with the Liouvillian exceptional point, featuring the coalescence of both the eigenvalues and the eigenmodes of the systems. Our work provides an efficient strategy to engineer the dynamics of open quantum system, and suggests a link unexplored yet between the Mpemba effect and the non-Hermitian physics. The Mpemba effect is an archetype for various anomalous relaxation phenomena. Here, the authors experimentally study a quantum version of the Mpemba effect in a single trapped ion system, where relaxation is exponentially accelerated by removing the excitation of the slowest decaying mode. This phenomenon, seen in Markovian open quantum systems containing Liouvillian exceptional points, indicates a link between the Mpemba effect and non-Hermitian physics.