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arXiv:2605.13685

Berry-Phase-Induced Chirality in Thermodynamics

Zhaoyu Fei, Yu-Han Ma

quant-phcond-mat.stat-mechmath-phSubmitted May 13, 2026• Announced May 14, 2026• 0 citations
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Abstract

Geometric phases are foundational to isolated quantum systems, yet their thermodynamic role in open systems remains unrevealed Developing a dissipative adiabatic perturbation expansion, we discover a Berry-phase-induced chiral work difference that survives decoherence. This chirality evolves from an interferometric thermodynamic Aharonov-Bohm effect in the unitary regime to a fringe-free signal in the dissipative regime. We illustrate this framework in a two-level system and assess its experimental feasibility. Our findings clarify the role of quantum geometry in the geometric formulation of thermodynamics.

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Geometric phases are foundational to isolated quantum systems, yet their thermodynamic role in open systems remains unrevealed Developing a dissipative adiabatic perturbation expansion, we discover a Berry-phase-induced chiral work difference that survives decoherence. This chirality evolves from an interferometric thermodynamic Aharonov-Bohm effect in the unitary regime to a fringe-free signal in the dissipative regime. We illustrate this framework in a two-level system and assess its experimental feasibility. Our findings clarify the role of quantum geometry in the geometric formulation of thermodynamics.
The geometric (Berry) phase of a two-level system in a dissipative environment is analyzed by using the second-quantized formulation, which provides a unified and gauge-invariant treatment of adiabatic and nonadiabatic phases and is thus applicable to a quantitative analysis of transitional regions away from ideal adiabaticity. In view of the recent experimental observation of the Berry phase in a superconducting qubit, we illustrate our formulation for a concrete adiabatic case in the Ohmic dissipation. The correction to the total phase together with the geometry-dependent dephasing time is given in a transparent way. The behavior of the geometric phase away from ideal adiabaticity is also analyzed in some detail.
Within a generalized Langevin framework for open quantum systems, the cyclic evolution of a two-level system is analyzed in terms of the geometric phase extended to dissipative systems for Ohmic friction. This proposal is applied to the dynamics of chiral molecules where the tunneling and parity violating effects are competing. The effect of different system-bath coupling functions in the dissipated energy is shown to be crucial to understand the behavior of the geometric phase as well as the decoherence displayed by the corresponding interference patterns.
The geometric (Berry) phase of a two-level system in a dissipative environment is analyzed by using the second-quantized formulation, which provides a unified and gauge-invariant treatment of adiabatic and nonadiabatic phases and is thus applicable to a quantitative analysis of transitional regions away from ideal adiabaticity. In view of the recent experimental observation of the Berry phase in a superconducting qubit, we illustrate our formulation for a concrete adiabatic case in the Ohmic dissipation. The correction to the total phase together with the geometry-dependent dephasing time is given in a transparent way. The behavior of the geometric phase away from ideal adiabaticity is also analyzed in some detail.
This special issue celebrates the discovery of two of the most important aspects of quantum mechanics: the Aharonov–Bohm effect and the Berry phase. The issue includes work presented at two conferences, 50 Years of the Aharonov–Bohm Effect, 11–14 October 2009, Tel Aviv University, Israel, and the Aharonov–Bohm Effect and Berry Phase 50/25 Anniversary, 14–15 December 2009, Bristol University, UK. The Aharonov–Bohm (AB) effect and the Berry phase have many things in common, apart from the happy coincidence that they were discovered 25 years apart, making possible such a joint anniversary. First, they were both discovered in the same place, the H H Wills Physics Laboratory, University of Bristol, UK. Second, they both were there for everybody to see from day one, from the very beginning of quantum mechanics. They were, so to say, right on the surface; there was no need for sophisticated mathematics or involved constructions. Yet it took so long for somebody to see them. The explanation, we dare to speculate, is that they are so unusual, they challenge so much our everyday experience and ingrained intuitions about physics that it was difficult to recognise them. Third, both the AB effect and the Berry phase are quintessentially quantum; they both manifest themselves as topological/geometric quantum phases. The AB effect revolutionized our understanding of the role of potentials in physics. For the first time, it was shown that a particle moving in a field-free region could be affected by a field in a disjoint region. In doing so, it shattered one of the strongest held principles of physics. In the case of the Berry phase, the importance lies in its absolute generality—the topological/geometric phase named after Berry is acquired by all physical systems when the external parameters they depend upon undergo an adiabatic cyclic change. Remarkably this phase depends only on the geometry of the cyclic path in the abstract parameter space, a fact which deepens our appreciation of the underlying geometry of quantum mechanics. The AB effect and the Berry phase are ubiquitous in modern physics and have implications ranging from the most fundamental to the very applied. First and foremost, they give a deeper understanding of the nature of quantum mechanics itself. Furthermore, we find them in fields as varied as cosmology, particle physics, non-abelian gauge theories, condensed matter, chemical and molecular physics, and laser dynamics. Generalizations of the AB effect to non-abelian gauge theories, such as the Wilson and `t Hooft loops, are important tools for studying confinement and spontaneous symmetry breaking. They explain charge quantization, the quantum Hall effect and the Josephson junction and also play a crucial role in electron microscope holography. Without them an understanding of many effects in the new field of mesoscopic physics, where tiny electronic circuits exhibit quantum behaviour, would be impossible. Like good wine, the AB effect and the Berry phase become finer and more appreciated with time. Even though they appear in textbooks and encyclopaedias, the number of researchers thinking and publishing papers on these two effects is increasing annually. The AB effect and the Berry phase keep being observed in new systems and with every day that passes novel applications are routinely found. This special issue is just a small snapshot of the state of the art 50 and 25 years, respectively, from their discoveries.
The Berry phase is a geometric phase acquired during adiabatic evolution over a closed loop in parameter space. It plays an essential role in geometric quantum gates and other phase-based protocols. In non-Hermitian systems, the Berry phase is complex, introducing fundamentally new geometric effects, including state amplification. In this work, we report experimental measurement of both the real and imaginary components of a Berry phase in a fully quantum system using a superconducting transmon circuit with engineered dissipation. We also demonstrate the path-dependent effects of the imaginary part on the dissipation and its utility in the implementation of non-unitary quantum control. These findings establish a clear geometric distinction between the real and imaginary components of the Berry phase and experimentally confirm the unique adiabatic behavior of non-Hermitian quantum systems.
This thesis consists of several studies performed over different few-dof quantum systems exposed to the effect of an uncontrolled environment. The primary focus of the work is to explore the relation between decoherence and environmentally-induced dissipative effects, and the concept known as geometric phases. The first mention of such an object in the context of quantum mechanics goes back to the seminal work by Berry. He demonstrated that the phase acquired by an eigenstate of a time-dependent Hamiltonian in an adiabatic cycle consists of two distinct contributions: one termed 'geometric' and the other known as the dynamical phase. Since Berry's work, the notion of geometric phase has been extended far beyond the original context, encompassing definitions applicable to arbitrary unitary evolutions. These geometric phases naturally arise in the geometric description of Hilbert space, where they manifest as holonomies and possess significance in the fundamental understanding of quantum mechanics and its mathematical framework, and in explaining various physical phenomena, including the Fractional Hall Effect. Moreover, from a modern perspective, geometric phases hold promise for practical applications, such as constructing geometric gates for quantum information processing and storage. However, in practice, a pure state of a quantum system is an idealized concept, and every experimental or real-world implementation must account for the presence of an environment that interacts with the observed system. This interaction necessitates a description in terms of mixed states and non-unitary evolutions. The definition of a geometric phase applicable in such scenarios remains an open problem, giving rise to multiple proposed solutions. Consequently, characterizing these geometric phases encompase motivations from fundamental aspects of quantum mechanics to technological applications.