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arXiv:2605.06436

Criticality around the Spinodal Point of First-Order Quantum Phase Transitions

Fan Zhang, Chiao Wang, H. T. Quan

cond-mat.stat-mechquant-phSubmitted May 7, 2026• Announced May 8, 2026• 0 citations• Revised May 26, 2026 (v2)
v1 · May 7, 2026v2 · May 26, 2026v3 · May 28, 2026
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Abstract

Universality and scaling are hallmarks of second-order phase transitions but are generally unexpected in first-order quantum phase transitions (FOQPTs). We present a microscopic theory showing that quantum criticality can emerge around the quantum spinodal point of FOQPTs where metastability disappears. We demonstrate that, at this instability, resonant local excitations dynamically decouple a Hilbert subspace characterized by an emergent discrete translational symmetry. Projecting the original Hamiltonian onto this subspace yields an effective Hamiltonian that exhibits a genuine second-order quantum phase transition (SOQPT) and the Kibble-Zurek scaling. We validate this framework in the tilted Ising chain which breaks Z_2 symmetry, and predict the absence of criticality in the staggered-field PXP model. This work indicates that the FOQPT dynamics is usually governed by an emergent critical point around the quantum spinodal point. Our study establishes a bridge between the dynamics of the FOQPT and SOQPT, and thus sheds new light on the long-standing conundrum of the dynamics of the FOQPT.

Comments
7 pages, 3 figures; Supplemental Material included

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Universality and scaling are hallmarks of second-order phase transitions but are generally unexpected in first-order quantum phase transitions (FOQPTs). We present a microscopic theory showing that quantum criticality can emerge around the quantum spinodal point of FOQPTs where metastability disappears. We demonstrate that, at this instability, resonant local excitations dynamically decouple a Hilbert subspace characterized by an emergent discrete translational symmetry. Projecting the original Hamiltonian onto this subspace yields an effective Hamiltonian that exhibits a genuine second-order quantum phase transition (SOQPT) and the Kibble-Zurek scaling. We validate this framework in the tilted Ising chain which breaks Z_2 symmetry, and predict the absence of criticality in the staggered-field PXP model. This work indicates that the FOQPT dynamics is usually governed by an emergent critical point around the quantum spinodal point. Our study establishes a bridge between the dynamics of the FOQPT and SOQPT, and thus sheds new light on the long-standing conundrum of the dynamics of the FOQPT.
Abstract Symmetry-breaking quantum phase transitions lead to the production of topological defects or domain walls in a wide range of physical systems. In second-order transitions, these exhibit universal scaling laws described by the Kibble–Zurek mechanism, but for first-order transitions a similarly universal approach is still lacking. Here, we propose a spinor Bose–Einstein condensate as a testbed system where critical scaling behaviour in a first-order quantum phase transition can be understood from generic properties. We demonstrate the applicability of the Kibble–Zurek mechanism for this transition to determine the critical exponents for: (1) the onset of the decay of the metastable state on short times scales, and (2) the number of resulting phase-separated ferromagnetic domains at longer times, as a one-dimensional spin-1 condensate is ramped across a first-order quantum phase transition. The predictions are in excellent agreement with mean-field numerical simulations and provide a paradigm for studying the decay of metastable states in experimentally accessible systems.
The Kibble-Zurek mechanism captures universality when a system is driven through a continuous phase transition. Here we study the dynamical aspect of quantum phase transitions in the Ising Field Theory where the quantum critical point can be crossed in different directions in the two-dimensional coupling space leading to different scaling laws. Using the Truncated Conformal Space Approach, we investigate the microscopic details of the Kibble-Zurek mechanism in terms of instantaneous eigenstates in a genuinely interacting field theory. For different protocols, we demonstrate dynamical scaling in the non-adiabatic time window and provide analytic and numerical evidence for specific scaling properties of various quantities. In particular, we argue that the higher cumulants of the excess heat exhibit universal scaling in generic interacting models for a slow enough ramp.
Recent work has suggested that the Kibble-Zurek mechanism can be re-interpreted as a theory of critical scaling out of equilibrium. While this has been shown for some classical and integrable models, in this work we demonstrate one crucial aspect of critical scaling theory: universality. We solve for the time-dependent finite-size scaling functions of the 1D transversefield Ising chain during a linear-in-time ramp of the field through the quantum critical point. We then simulate Mott-insulating bosons in a tilted potential, an experimentally-studied system in the same equilibrium universality class, and demonstrate that universality holds for the dynamics as well. We find qualitatively athermal features of the scaling functions, such as negative spin correlations, and show that they should be robustly observable within present cold atom experiments. In addition, we discuss recent results in which the Ising model is extended by imbuing the magnetic field with dynamics. We predict using Kibble-Zurek scaling and numerically confirm that the magnetic field ramp is dynamically arrested at the quantum critical point. Extensions of this theory indicate that dynamic localization near critical points should be omnipresent in nature, and may have implications in particle physics as a possible mechanism for giving the Higgs boson a light mass.
Uncovering and understanding universal dynamics in matter far from equilibrium remains a key challenge. In this work, we identify a so far unrecognized form of universal behavior that emerges after a sudden symmetry-breaking quench at continuous phase transitions. Our key observation is that the order-parameter fluctuations in Ising models exhibit a compelling temporal collapse across a wide range of system sizes and quench strengths, indicative of an emergent single-variable scaling form. This phenomenon can be explained by introducing a so far unknown dynamical critical exponent for the underlying continuous phase transition. We find evidence for a lower critical effective dimension of this universal regime: it is observed in the 2D quantum and 3D and 4D classical Ising models, but not in the 1D quantum or 2D classical cases. Our results suggest that our observed universal far-from-equilibrium scaling may extend beyond the Ising models studied here and could more broadly characterize systems with non-conserved order parameters, opening new avenues for exploring universal dynamics both theoretically and in current experimental platforms.
Quantum phase transition arises in general as second order phase transition at zero temperature, tuned by a non-thermal parameter such as pressure, doping or a magnetic field. The point in the phase diagram of the material in which different phases meet is called a quantum critical point (QCP). Physics around QCPs are of extensive current interest because the critical quantum fluctuations influence the physical properties in a wide temperature range (quantum criticality), and are believed to be responsible for many emergent physical properties such as non-Fermi liquids and unconventional superconductivity. In this research we explore dynamics and thermodynamics near QCPs via investigating three classes of models, which all have real material correspondence. Specifically first, we study local dynamics in a perturbed quantum critical Ising chain with E8 symmetry, where we show the local dynamical spin susceptibility has a singular dependence on frequency, but differs from the diffusion form. The nuclear magnetic resonance (NMR) relaxation rate at low temperatures depends exponentially on the inverse temperature, whose prefactor we also determine. We propose NMR experiments as a means to further test the applicability of the E8 description for CoNb2O6. Second, we investigate the thermodynamic properties of itinerant ferromagnets near quantum critical points, described by the quantum Landau-Ginzburg theory. We provide a regularized perturbative renormalization group procedure to calculate the free energy. We further carry out numerical calculations on thermodynamic quantities, capturing not only the leading critical behaviors, but also the subleading and nonsingular contributions. We demonstrate various thermodynamic signatures of quantum criticality, including the entropy accumulation effect and the divergence of the specific heat coefficient. A detailed comparison to the recent experimental results on an itinerant ferromagnet Sr3Ru2O7 is also presented. Third, we explore Ising-nematic and magnetic phases and their transitions in iso-electronically doped iron pnictides by carrying out a large-N study of an effective low-energy Ginzburg-Landau model for these systems. We demonstrate that the magnetic and Ising orders transitions are concurrent at zero temperature, and both transitions are weakly first-order, which is consistent with RG-based prediction and experimental observations.
Understanding how noise influences nonequilibrium quantum critical dynamics is essential for both fundamental physics and the development of practical quantum technologies. While the quantum Kibble-Zurek (QKZ) mechanism predicts universal scaling during quenches across a critical point, real quantum systems exhibit complex decoherence that can substantially modify these behaviors, ranging from altering critical scaling to completely suppressing it. By considering a specific case of nondemolishing noise, we first show how decoherence can reshape universal scaling and verify these theoretical predictions using numerical simulations of spin chains across a wide range of noise strengths. Then, we study linear quenches in the transverse-field Ising model on IBM superconducting processors where the noise model is unknown. Using large system sizes of 80-120 qubits, we measure equal-time connected correlations, defect densities, and excess energies across various quench times. Surprisingly, unlike earlier observations where noise-induced defect production masked universal behavior at long times, we observe clear scaling relations, pointing towards persistent universal structure shaped by decoherence. The extracted scaling exponents differ from both ideal QKZ predictions and analytic results for simplified noise models, suggesting the emergence of a distinct noise-influenced universality regime. Our results, therefore, point toward the possibility of using universal dynamical scaling as a high-level descriptor of quantum hardware, complementary to conventional gate-level performance metrics.