Out-of-Time-Order Correlators (OTOCs) quantify quantum information scrambling, but their connection to localized phase-space structures, such as chemical transition states, requires formal development. We derive a leading-order semiclassical expansion for the local microcanonical OTOC in systems with an index-1 saddle point, expressing the scrambling rate as a coherent sum over unstable periodic orbits on the Normally Hyperbolic Invariant Manifold (NHIM). Valid in the semiclassical limit and the intermediate-time regime before the Ehrenfest time, our derivation utilizes the Normal Form theory of the transition state, which transforms the Hamiltonian near the saddle into an integrable (though generally non-separable) form dependent on conserved actions. We outline the derivation of the microcanonical trace, the semiclassical propagator for integrable systems, the factorization of the stability matrix, and the Schur complement reduction of the stationary phase approximation. Our result extends periodic-orbit trace methods to scrambling observables, yielding a local instability exponent Λ(J) governing the leading semiclassical growth window. As a special case, when the observation time coincides with the intrinsic periods of the contributing orbits, the trace sum reduces to an effective 1.5Λ scaling, resulting from the competition between local hyperbolic growth and wavepacket dilution. This simplified form is conditional; the full expansion retains a coherent sum over orbit periods. Finally, we discuss how the dependence of the instability on transverse actions establishes a theoretical mechanism for mode-selective control of scrambling, and outline a numerical evaluation strategy to test these predictions.
Out-of-Time-Order Correlators (OTOCs) quantify quantum information scrambling, but their connection to localized phase-space structures, such as chemical transition states, requires formal development. We derive a leading-order semiclassical expansion for the local microcanonical OTOC in systems with an index-1 saddle point, expressing the scrambling rate as a coherent sum over unstable periodic orbits on the Normally Hyperbolic Invariant Manifold (NHIM). Valid in the semiclassical limit and the intermediate-time regime before the Ehrenfest time, our derivation utilizes the Normal Form theory of the transition state, which transforms the Hamiltonian near the saddle into an integrable (though generally non-separable) form dependent on conserved actions. We outline the derivation of the microcanonical trace, the semiclassical propagator for integrable systems, the factorization of the stability matrix, and the Schur complement reduction of the stationary phase approximation. Our result extends periodic-orbit trace methods to scrambling observables, yielding a local instability exponent Λ(J) governing the leading semiclassical growth window. As a special case, when the observation time coincides with the intrinsic periods of the contributing orbits, the trace sum reduces to an effective 1.5Λ scaling, resulting from the competition between local hyperbolic growth and wavepacket dilution. This simplified form is conditional; the full expansion retains a coherent sum over orbit periods. Finally, we discuss how the dependence of the instability on transverse actions establishes a theoretical mechanism for mode-selective control of scrambling, and outline a numerical evaluation strategy to test these predictions.
Abstract Out-of-time-order correlators (OTOCs) quantify quantum information scrambling, but their connection to localized phase-space structures—such as chemical transition states—has remained largely unexplored. We derive a formal leading-order semiclassical expansion for the microcanonical OTOC in systems with an index-1 saddle point, expressing its oscillatory, geometry-resolving contribution as a coherent sum over resonant invariant tori of the normally hyperbolic invariant manifold (NHIM), each a family of periodic orbits, transversely unstable in the full phase space. Although formally subleading in ℏ to the smooth Weyl contribution, this orbit sum carries the localized exponent 2 Λ γ , compared with the smooth exponent Λ max , and it is the only contribution that resolves the periodic-orbit geometry of the transition state: within the local normal-form description, the NHIM is the one structure on the energy shell whose trajectories never escape the saddle neighborhood. Valid in the semiclassical limit and the intermediate-time regime before the Ehrenfest time, our derivation utilizes the normal form theory of the transition state, which transforms the Hamiltonian near the saddle into an integrable (though generally non-separable) form dependent on conserved actions. We outline the derivation of the microcanonical trace, the semiclassical propagator for integrable systems, the factorization of the stability matrix, and the explicit Schur complement reduction of the stationary phase approximation. Our result extends periodic-orbit trace methods to scrambling observables, recovering a local instability exponent Λ ( J ) governing the leading semiclassical growth window. Finally, we discuss how the dependence of the instability on transverse actions suggests a mechanism for mode-selective control of scrambling, and outline a numerical evaluation strategy to test these predictions.
Fast scrambling of quantum correlations, reflected by the exponential growth of out-of-time-order correlators (OTOCs) on short pre-Ehrenfest time scales, is commonly considered as a major quantum signature of unstable dynamics in quantum systems with a classical limit. In two recent works [Phys. Rev. Lett. 123, 160401 (2019)0031-900710.1103/PhysRevLett.123.160401] and [Phys. Rev. Lett. 124, 140602 (2020)10.1103/PhysRevLett.124.140602], a significant difference in the scrambling rate of integrable (many-body) systems was observed, depending on the initial state being semiclassically localized around unstable fixed points or fully delocalized (infinite temperature). Specifically, the quantum Lyapunov exponent λ_{q} quantifying the OTOC growth is given, respectively, by λ_{q}=2λ_{s} or λ_{q}=λ_{s} in terms of the stability exponent λ_{s} of the hyperbolic fixed point. Here we show that a wave packet, initially localized around this fixed point, features a distinct dynamical transition between these two regions. We present an analytical semiclassical approach providing a physical picture of this phenomenon, and support our findings by extensive numerical simulations in the whole parameter range of locally unstable dynamics of a Bose-Hubbard dimer. Our results suggest that the existence of this crossover is a hallmark of unstable separatrix dynamics in integrable systems, thus opening the possibility to distinguish the latter, on the basis of this particular observable, from genuine chaotic dynamics generally featuring uniform exponential growth of the OTOC.
Abstract Out-of-time-ordered correlators (OTOCs), defined via the squared commutator of a time-evolving and a stationary operator, represent observables that provide useful indicators for chaos and the scrambling of information in complex quantum systems. Here we present a quasiclassical formalism of OTOCs, which is obtained from the semiclassical van Vleck–Gutzwiller propagator through the application of the diagonal approximation. For short evolution times, this quasiclassical approach yields the same result as the Wigner–Moyal formalism, i.e. OTOCs are classically described via the square of the Poisson bracket between the two involved observables, thus giving rise to an exponential growth in a chaotic regime. For long times, for which the semiclassical framework is, in principle, still valid, the diagonal approximation yields an asymptotic saturation value for the quasiclassical OTOC under the assumption of fully developed classical chaos. However, numerical simulations, carried out within chaotic few-site Bose–Hubbard systems in the absence and presence of periodic driving, demonstrate that this saturation value strongly underestimates the actual threshold value of the quantum OTOC, which is normally attained after the Ehrenfest time. This indicates that nondiagonal and hence genuinely quantum contributions, thus exceeding the framework of the quasiclassical description, are primarily responsible for describing OTOCs beyond the short-time regime.
Fast scrambling, quantified by the exponential initial growth of out-of-time-ordered correlators (OTOCs), is the ability to efficiently spread quantum correlations among the degrees of freedom of interacting systems and constitutes a characteristic signature of local unstable dynamics. As such, it may equally manifest both in systems displaying chaos or in integrable systems around criticality. Here we go beyond these extreme regimes with an exhaustive study of the interplay between local criticality and chaos right at the intricate phase-space region where the integrability-chaos transition first appears. We address systems with a well-defined classical (mean-field) limit, as coupled large spins and Bose-Hubbard chains, thus allowing for semiclassical analysis. Our aim is to investigate the dependence of the exponential growth of the OTOCs, defining the quantum Lyapunov exponent λ_{q} on quantities derived from the classical system with mixed phase space, specifically the local stability exponent of a fixed point λ_{loc} as well as the maximal Lyapunov exponent λ_{L} of the chaotic region around it. By extensive numerical simulations covering a wide range of parameters we give support to a conjectured linear dependence 2λ_{q}=aλ_{L}+bλ_{loc}, providing a simple route to characterize scrambling at the border between chaos and integrability.
Quantum scrambling often gives rise to short-time exponential growth in out-of-time-ordered correlators (OTOCs). The scrambling rate over an isolated saddle point at finite temperature is shown here to be reduced by a hierarchy of quenching processes. Two of these appear in the classical limit, where escape from the neighbourhood of the saddle reduces the rate by a factor of two, and thermal fluctuations around the saddle reduce it further; a third process can be explained semiclassically as arising from quantum thermal fluctuations around the saddle, which are also responsible for imposing the Maldacena-Shenker-Stanford bound.
This PhD thesis investigates scrambling in near-integrable and chaotic systems. First, we present a quasiclassical formalism of out-of-time-ordered correlators (OTOCs), the main chaos probe that we use, using the semiclassical van Vleck-Gutzwiller propagator and the application of the diagonal approximation. For short evolution times, this quasiclassical approach yields the same result as the Wigner-Moyal formalism, i.e. an exponential growth in a chaotic regime. For long times, for which the semiclassical framework is, in principle, still valid, the diagonal approximation yields an asymptotic saturation value for the quasiclassical OTOC under the assumption of fully developed classical chaos. Numerical simulations in Bose-Hubbard systems show that this estimation strongly underestimates the actual threshold value of the quantum OTOCs. This indicates that genuinely quantum contributions are primarily responsible for describing OTOCs beyond the short-time regime. The thesis then shifts its focus to near-integrable systems, where chaos is present only in the form of a thin chaotic layer. In a fully integrable system, around a fixed point, the dynamics is dictated by a stability exponent, and in a fully chaotic system by a maximal Lyapunov exponent. The question remains open as to how the two compete in near-integrable regimes. We describe this integrability-chaos transition by establishing a description of the dynamics inside the chaotic layer in a universal system: the periodically driven pendulum. We support our claim for the universality of this mechanism by studying two paradigmatic examples of the integrability-to-chaos transition, namely the kicked rotor and the kicked Bose-Hubbard dimer. Finally, we study quantum scars in single- and many-particle systems. For the former, we find that the short-time behaviour of indicators such as the OTOC, computed in the kicked rotor, is not sensitive to the presence of a scar, i.e. to the fulfilment of Heller's criterion. Nonetheless, we show that the OTOC can serve as a probe of unstable periodic orbits. For the latter, we look at the persistent oscillations that manifest in the presence of scars in different observables computed for staggered dimer states in Bose-Hubbard models. As the interaction strength increases, one expects scarring to be a less prevalent phenomenon. This is corroborated by the oscillations that progressively vanish.