Quantum scrambling often gives rise to short-time exponential growth in out-of-time-ordered correlators (OTOCs). The scrambling rate over an isolated saddle point at finite temperature is shown here to be reduced by a hierarchy of quenching processes. Two of these appear in the classical limit, where escape from the neighbourhood of the saddle reduces the rate by a factor of two, and thermal fluctuations around the saddle reduce it further; a third process can be explained semiclassically as arising from quantum thermal fluctuations around the saddle, which are also responsible for imposing the Maldacena-Shenker-Stanford bound.
Quantum scrambling often gives rise to short-time exponential growth in out-of-time-ordered correlators (OTOCs). The scrambling rate over an isolated saddle point at finite temperature is shown here to be reduced by a hierarchy of quenching processes. Two of these appear in the classical limit, where escape from the neighbourhood of the saddle reduces the rate by a factor of two, and thermal fluctuations around the saddle reduce it further; a third process can be explained semiclassically as arising from quantum thermal fluctuations around the saddle, which are also responsible for imposing the Maldacena-Shenker-Stanford bound.
Quantum scrambling often gives rise to short-time exponential growth in out-of-time-ordered correlators. The scrambling rate over an isolated saddle point at finite temperature is shown here to be reduced by a hierarchy of quenching processes. Two of these appear in the classical limit, where escape from the neighborhood of the saddle reduces the rate by a factor of two, and thermal fluctuations around the saddle reduce it further; a third process can be explained semiclassically as arising from quantum thermal fluctuations around the saddle, which are also responsible for imposing the Maldacena-Shenker-Stanford bound.
The ultimate regularity of quantum mechanics creates a tension with the assumption of classical chaos used in many of our pictures of chemical reaction dynamics. Out-of-time-order correlators (OTOCs) provide a quantum analog to the Lyapunov exponents that characterize classical chaotic motion. Maldacena, Shenker, and Stanford have suggested a fundamental quantum bound for the rate of information scrambling, which resembles a limit suggested by Herzfeld for chemical reaction rates. Here, we use OTOCs to study model reactions based on a double-well reaction coordinate coupled to anharmonic oscillators or to a continuum oscillator bath. Upon cooling, as one enters the tunneling regime where the reaction rate does not strongly depend on temperature, the quantum Lyapunov exponent can approach the scrambling bound and the effective reaction rate obtained from a population correlation function can approach the Herzfeld limit on reaction rates: Tunneling increases scrambling by expanding the state space available to the system. The coupling of a dissipative continuum bath to the reaction coordinate reduces the scrambling rate obtained from the early-time OTOC, thus making the scrambling bound harder to reach, in the same way that friction is known to lower the temperature at which thermally activated barrier crossing goes over to the low-temperature activationless tunneling regime. Thus, chemical reactions entering the tunneling regime can be information scramblers as powerful as the black holes to which the quantum Lyapunov exponent bound has usually been applied.
Out-of-time-order correlators (OTOCs) have proven to be a useful tool for studying thermalization in quantum systems. In particular, the exponential growth of OTOCS, or scrambling, is sometimes taken as an indicator of chaos in quantum systems, despite the fact that saddle points in integrable systems can also drive rapid growth in OTOCs. By analyzing the Dicke model and a driven Bose-Hubbard dimer, we demonstrate that the OTOC growth driven by chaos can, nonetheless, be distinguished from that driven by saddle points through the long-term behavior. Besides quantitative differences in the long-term average, the saddle point gives rise to large oscillations not observed in the chaotic case. The differences are also highlighted by entanglement entropy, which in the chaotic-driven dimer matches a Page curve prediction. These results illustrate additional markers that can be used to distinguish chaotic behavior in quantum systems, beyond the initial exponential growth in OTOCs.
Out-of-Time-Ordered Commutators (OTOCs), representing a key diagnostic for scrambling as a facet of short-time quantum chaos, have attracted wide-ranging interest, from many-body physics to quantum gravity. By means of a suitable form of the Wigner-Moyal expansion, and invoking ensemble equivalence in statistical physics, we provide a consistent approach to the growth rate of the OTOC for many-body systems with chaotic classical limit where both the classical Lyapunov exponent and the quantum nature of the density of states enter. Applying this construction to quantized high-dimensional hyperbolic motion, i.e., a quantum chaotic system that exhibits gravity-like correlation functions in the late-time regime, we compute the OTOC growth rate Λ as a function of the number of degrees of freedom, f, and inverse temperature, β.
We show that the scaled growth rate, Λ/f, can be described by a universal function of fβ and displays a cross-over from classical to quantum behavior as we increase f and/or lower the temperature. In the deep quantum regime of infinite f, we find maximally fast scrambling in the sense of the Maldacena-Shenker-Stanford bound on chaos. This elucidates the non-perturbative mechanism underlying the saturation of the bound via quantum contributions to the mean density of states, and it provides further support for this dynamical system as a dual to two-dimensional quantum gravity. In this way, we present first evidence of maximally fast scrambling in a quantum chaotic system with a well-defined classical Hamiltonian limit, without invoking any external mechanism such as (disorder) averaging.
A bstract In semi-classical systems, the exponential growth of the out-of-time-order correlator (OTOC) is believed to be the hallmark of quantum chaos. However, on several occasions, it has been argued that, even in integrable systems, OTOC can grow exponentially due to the presence of unstable saddle points in the phase space. In this work, we probe such an integrable system exhibiting saddle-dominated scrambling through Krylov complexity and the associated Lanczos coefficients. In the realm of the universal operator growth hypothesis, we demonstrate that the Lanczos coefficients follow the linear growth, which ensures the exponential behavior of Krylov complexity at early times. The linear growth arises entirely due to the saddle, which dominates other phase-space points even away from itself. Our results reveal that the exponential growth of Krylov complexity can be observed in integrable systems with saddle-dominated scrambling and thus need not be associated with the presence of chaos.
This paper examines the mathematical relationship between the Maldacena–Shenker–Stanford (MSS) bound on the growth of chaos and the thin–thick chaos framework developed in recent work on coherent disorder and nonlinear stability. The MSS bound constrains the rate at which a regularized out-of-time-order correlator can deviate from its factorized value, yielding a universal speed limit on information scrambling in thermal quantum systems: the Lyapunov exponent satisfies λL≤2π/βλL≤2π/β, and the scrambling time is t∗=(β/2π)log(1/ε)t∗=(β/2π)log(1/ε), where ε∼1/N2ε∼1/N2 is the microscopic initial amplitude. We introduce a thinness index Θ(t)Θ(t) constructed directly from the correlator deviation and show that, under the analyticity and boundedness hypotheses of the MSS argument, Θ(t)Θ(t) remains parametrically small until times of order the scrambling time. The same analytic strip that yields the Lyapunov bound therefore also controls the rate at which this particular thinness index can collapse. When the additional structural hypotheses of the Trojan Universality Class—spectral gap, two-mode normal form, and near-integrable remainder—are imposed, the prefactor of the exponential growth of Θ(t)Θ(t) is suppressed by a factor η(Δ)≤1η(Δ)≤1, delaying the onset of thickness by a logarithmic shift without altering the scrambling rate itself. The analysis reveals a conceptual distinction between scrambling, the microscopic spread of quantum information, and the transition to thick chaos, the operational crossing of a failure threshold in a chosen projection. For the correlator projection these coincide in time, but structural gaps can decouple them, allowing maximal-rate scrambling to coexist with prolonged operational thinness. Limitations include projection dependence, the restrictive nature of the Trojan criteria, and the absence of a general comparison theorem relating distinct thinness indices. The results are elementary consequences of the existing MSS hypotheses and do not modify the original bound.