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arXiv:2604.11392 · Physical review. B./Physical review. B

Absence of thermalization after a local quench and strong violation of the eigenstate thermalization hypothesis

Peter Reimann, Christian Eidecker-Dunkel

cond-mat.stat-mechquant-phSubmitted Apr 13, 2026• Announced Apr 14, 2026• 0 citations
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Abstract

Absence of thermalization after a global quantum quench is a well-established numerical observation in integrable many-body systems, and can be empirically related to a violation of the eigenstate thermalization hypothesis (ETH) in such models. Still, in many of those examples a weaker version of the conventional ETH (wETH) has been numerically reported or even rigorously proven. In this paper we show analytically and illustrate numerically that the absence of thermalization is already possible after a local quench. A closely related finding is a strong violation of the ETH, meaning that not even the wETH is fulfilled anymore. In our analytical explorations we focus on XX-spin-chain models with open boundary conditions, where the local quench is generated by initiating the system in thermal equilibrium and then suddenly switching on (or slightly changing) a single-spin impurity either at the end or in the center of the chain. Numerically we observe qualitatively similar phenomena also for more general XXZ-models in the case of an end-impurity, but not in the case of a central impurity.

Journal reference
Phys. Rev. B 113, 144304 (2026)
DOI
10.1103/zp5y-6d5w
Comments
20 pages, 12 figures, plus appendices 10 pages

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Absence of thermalization after a global quantum quench is a well-established numerical observation in integrable many-body systems, and can be empirically related to a violation of the eigenstate thermalization hypothesis (ETH) in such models. Still, in many of those examples a weaker version of the conventional ETH (wETH) has been numerically reported or even rigorously proven. In this paper we show analytically and illustrate numerically that the absence of thermalization is already possible after a local quench. A closely related finding is a strong violation of the ETH, meaning that not even the wETH is fulfilled anymore. In our analytical explorations we focus on XX-spin-chain models with open boundary conditions, where the local quench is generated by initiating the system in thermal equilibrium and then suddenly switching on (or slightly changing) a single-spin impurity either at the end or in the center of the chain. Numerically we observe qualitatively similar phenomena also for more general XXZ-models in the case of an end-impurity, but not in the case of a central impurity.
Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate thermalization hypothesis (ETH) is presumed to be a key mechanism, but has defied rigorous verification for generic systems thus far. A weaker variant (weak ETH), by contrast, is provably true for a large variety of systems, including even many integrable models, but its implications with respect to the problem of thermalization are still largely unexplored. Here we analytically demonstrate that systems satisfying the weak ETH exhibit thermalization for two very natural classes of far-from-equilibrium initial conditions: the overwhelming majority of all pure states with a preset nonequilibrium expectation value of some given local observable, and the Gibbs states of a Hamiltonian which subsequently is subject to a quantum quench in the form of a sudden change of some local system properties.
Abstract The observable long-time behavior of an isolated many-body system after a quantum quench is considered, i.e. an eigenstate (or an equilibrium ensemble) of some pre-quench Hamiltonian H serves as initial condition which then evolves in time according to some post-quench Hamiltonian H p . Absence of thermalization is analytically demonstrated for a large class of quite common pre- and post-quench spin Hamiltonians. The main requirement is that the pre-quench Hamiltonian must exhibit a Z 2 (spin-flip) symmetry, which would be spontaneously broken in the thermodynamic limit, though we actually focus on finite (but large) systems. On the other hand, the post-quench Hamiltonian must violate the Z 2 symmetry, but for the rest may be non-integrable and may obey the eigenstate thermalization hypothesis for (sums of) few-body observables.
An isolated quantum many-body system in an initial pure state will come to thermal equilibrium if it satisfies the eigenstate thermalization hypothesis (ETH). We consider alternatives to ETH that have been proposed. We first show that von Neumann's quantum ergodic theorem relies on an assumption that is essentially equivalent to ETH. We also investigate whether, following a sudden quench, special classes of pure states can lead to thermal behavior in systems that do not obey ETH, namely, integrable systems. We find examples of this, but only for initial states that obeyed ETH before the quench.
There is a dichotomy in the nonequilibrium dynamics of quantum many-body systems. In the presence of integrability, expectation values of local operators equilibrate to values described by a generalized Gibbs ensemble, which retains extensive memory about the initial state of the system. On the other hand, in generic systems such expectation values relax to stationary values described by the thermal ensemble, fixed solely by the energy of the state. At the heart of understanding, this dichotomy is the eigenstate thermalization hypothesis (ETH): individual eigenstates in nonintegrable systems are thermal, in the sense that expectation values agree with the thermal prediction at a temperature set by the energy of the eigenstate. In systems where ETH is violated, thermalization can be avoided. Thus, establishing the range of validity of ETH is crucial in understanding whether a given quantum system thermalizes. Here, we study a simple model with confinement, the quantum Ising chain with a longitudinal field, in which ETH is violated. Despite an absence of integrability, there exist rare (nonthermal) states that persist far into the spectrum. These arise as a direct consequence of confinement: pairs of particles are confined, forming new ``meson'' excitations whose energy can be extensive in the system size. We show that such states are nonthermal in both the continuum and in the low-energy spectrum of the corresponding lattice model. We highlight that the presence of such states within the spectrum has important consequences, with certain quenches leading to an absence of thermalization and local observables evolving anomalously.
The eigenstate thermalization hypothesis (ETH) is a successful theory that establishes the criteria for ergodicity and thermalization in isolated quantum many-body systems. In this work, we investigate the thermalization properties of spin-$ 1/2 $ XXZ chain with linearly-inhomogeneous interactions. We demonstrate that introduction of the inhomogeneous interactions leads to an onset of quantum chaos and thermalization, which, however, becomes inhibited for sufficiently strong inhomogeneity. To exhibit ETH, and to display its breakdown upon varying the strength of interactions, we probe statistics of energy levels and properties of matrix elements of local observables in eigenstates of the inhomogeneous XXZ spin chain. Moreover, we investigate the dynamics of the entanglement entropy and the survival probability which further evidence the thermalization and its breakdown in the considered model. We outline a way to experimentally realize the XXZ chain with linearly-inhomogeneous interactions in systems of ultracold atoms. Our results highlight a mechanism of emergence of ETH due to insertion of inhomogeneities in an otherwise integrable system and illustrate the arrest of quantum dynamics in presence of strong interactions.
We propose and numerically validate an efficient single-eigenstate diagnostic for the eigenstate thermalization hypothesis (ETH) based on a perturbed eigenstate quench protocol. By introducing a weak random perturbation to an energy eigenstate to break its stationarity, we characterize the time-averaged subsystem evolution speed as a function of the subsystem-to-total system size ratio. The diagnostic relies on a robust qualitative distinction: eigenstates satisfying ETH exhibit an S-shaped curve with a clear inflection point near half the system size, while ETH-violating eigenstates display a convex J-shaped profile. We benchmark the criterion across paradigmatic one-dimensional spin chains covering chaotic, integrable, many-body localized, and quantum many-body scar regimes, obtaining full agreement with established thermalization phenomenology. Our method circumvents the need for explicit thermal ensemble construction, providing a robust, experimentally feasible probe of eigenstate thermalization at the single-eigenstate level.