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arXiv:2111.01599 · Journal of Statistical Mechanics Theory and Experiment

Symmetry-prohibited thermalization after a quantum quench

Peter Reimann

Published Oct 1, 2021• 3 citations
arXivHTMLPDF

Abstract

Abstract The observable long-time behavior of an isolated many-body system after a quantum quench is considered, i.e. an eigenstate (or an equilibrium ensemble) of some pre-quench Hamiltonian H serves as initial condition which then evolves in time according to some post-quench Hamiltonian H p . Absence of thermalization is analytically demonstrated for a large class of quite common pre- and post-quench spin Hamiltonians. The main requirement is that the pre-quench Hamiltonian must exhibit a Z 2 (spin-flip) symmetry, which would be spontaneously broken in the thermodynamic limit, though we actually focus on finite (but large) systems. On the other hand, the post-quench Hamiltonian must violate the Z 2 symmetry, but for the rest may be non-integrable and may obey the eigenstate thermalization hypothesis for (sums of) few-body observables.

DOI
10.1088/1742-5468/ac2a9c

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Abstract The observable long-time behavior of an isolated many-body system after a quantum quench is considered, i.e. an eigenstate (or an equilibrium ensemble) of some pre-quench Hamiltonian H serves as initial condition which then evolves in time according to some post-quench Hamiltonian H p . Absence of thermalization is analytically demonstrated for a large class of quite common pre- and post-quench spin Hamiltonians. The main requirement is that the pre-quench Hamiltonian must exhibit a Z 2 (spin-flip) symmetry, which would be spontaneously broken in the thermodynamic limit, though we actually focus on finite (but large) systems. On the other hand, the post-quench Hamiltonian must violate the Z 2 symmetry, but for the rest may be non-integrable and may obey the eigenstate thermalization hypothesis for (sums of) few-body observables.
Absence of thermalization after a global quantum quench is a well-established numerical observation in integrable many-body systems, and can be empirically related to a violation of the eigenstate thermalization hypothesis (ETH) in such models. Still, in many of those examples a weaker version of the conventional ETH (wETH) has been numerically reported or even rigorously proven. In this paper we show analytically and illustrate numerically that the absence of thermalization is already possible after a local quench. A closely related finding is a strong violation of the ETH, meaning that not even the wETH is fulfilled anymore. In our analytical explorations we focus on XX-spin-chain models with open boundary conditions, where the local quench is generated by initiating the system in thermal equilibrium and then suddenly switching on (or slightly changing) a single-spin impurity either at the end or in the center of the chain. Numerically we observe qualitatively similar phenomena also for more general XXZ-models in the case of an end-impurity, but not in the case of a central impurity.
Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate thermalization hypothesis (ETH) is presumed to be a key mechanism, but has defied rigorous verification for generic systems thus far. A weaker variant (weak ETH), by contrast, is provably true for a large variety of systems, including even many integrable models, but its implications with respect to the problem of thermalization are still largely unexplored. Here we analytically demonstrate that systems satisfying the weak ETH exhibit thermalization for two very natural classes of far-from-equilibrium initial conditions: the overwhelming majority of all pure states with a preset nonequilibrium expectation value of some given local observable, and the Gibbs states of a Hamiltonian which subsequently is subject to a quantum quench in the form of a sudden change of some local system properties.
We explore the role of the initial state on the onset of thermalization in isolated quantum many-body systems after a quench. The initial state is an eigenstate of an initial Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ and it evolves according to a different final Hamiltonian ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$. If the initial state has a chaotic structure with respect to ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, i.e., if it fills the energy shell ergodically, thermalization is certain to occur. This happens when ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{I}$ is a full random matrix, because its states projected onto ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$ are fully delocalized. The results for the observables then agree with those obtained with thermal states at infinite temperature. However, finite real systems with few-body interactions, as the ones considered here, are deprived of fully extended eigenstates, even when described by a nonintegrable Hamiltonian. We examine how the initial state delocalizes as it gets closer to the middle of the spectrum of ${\stackrel{\ifmmode \hat{}\else \^{}\fi{}}{H}}_{F}$, causing the observables to approach thermal averages, be the models integrable or chaotic. Our numerical studies are based on initial states with energies that cover the entire lower half of the spectrum of one-dimensional Heisenberg spin-1/2 systems.
We consider the question of thermalization for isolated quantum systems after a sudden parameter change, a so-called quantum quench. In particular we investigate the pre-requisites for thermalization focusing on the statistical properties of the time-averaged density matrix and of the expectation values of observables in the final eigenstates. We find that eigenstates, which are rare compared to the typical ones sampled by the micro-canonical distribution, are responsible for the absence of thermalization of some infinite integrable models and play an important role for some finite size non-integrable systems, such as the Bose-Hubbard model. We stress the importance of finite size effects for the thermalization of isolated quantum systems and propose a condition, relying on the Kullback-Leibler entropy, to obtain thermalization.
We consider quenches of a quantum system that is prepared in a canonical equilibrium state of one Hamiltonian and then evolves unitarily in time under a different Hamiltonian. Technically, our main result is a systematic expansion of the pre- and postquench canonical ensembles in the quench strength. We first demonstrate how this can be used to predict the system's temperature after the quench from equilibrium properties at the prequench temperature. For a thermalizing postquench system, it furthermore allows us to calculate equilibrium observable expectation values. Finally, in the presence of additional conserved quantities besides the Hamiltonian, we obtain a hierarchy of necessary conditions for thermalization towards the (postquench) canonical ensemble. At first order, these thermalization conditions have a nice geometric interpretation in operator space with the canonical covariance as a semi-inner product: The quench operator (difference between post- and prequench Hamiltonians) and the conserved quantity must be orthogonal in the orthogonal complement of the postquench Hamiltonian. We illustrate the results numerically for a variety of setups involving integrable and nonintegrable models.
An isolated quantum many-body system in an initial pure state will come to thermal equilibrium if it satisfies the eigenstate thermalization hypothesis (ETH). We consider alternatives to ETH that have been proposed. We first show that von Neumann's quantum ergodic theorem relies on an assumption that is essentially equivalent to ETH. We also investigate whether, following a sudden quench, special classes of pure states can lead to thermal behavior in systems that do not obey ETH, namely, integrable systems. We find examples of this, but only for initial states that obeyed ETH before the quench.