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arXiv:2604.09410 · Physical Review Letters

Symmetry-driven thermalization via finite de Finetti theorems

Uttam Singh, Nicolas J. Cerf

quant-phmath-phSubmitted Apr 10, 2026• Announced Apr 13, 2026• 0 citations• Revised Jul 30, 2026 (v2)
v1 · Apr 10, 2026v2 · Jul 30, 2026
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Abstract

Thermal behavior in subsystems of closed quantum systems is commonly attributed to dynamical chaos, quantum ergodicity, canonical typicality, or the eigenstate thermalization hypothesis, suggesting a fundamentally statistical origin of thermalization. Here, we propose a potential alternative mechanism in which thermal structures emerge deterministically from symmetry considerations alone, without recourse to statistical arguments. We prove a finite de Finetti-type theorem for quantum states invariant under energy-preserving unitaries, establishing that the reduced marginals of any such invariant $N$-qudit state are close (both in trace distance and relative entropy) to convex mixtures of thermal product states, with explicit error bounds vanishing as $N \to \infty$. We further present an example of energy-conserving Lindblad dynamics whose long-time limit is invariant under energy-preserving unitaries, providing a dynamical realization of the desired symmetry class. These results imply that invariance under energy-preserving unitaries suffices as a sole fundamental, deterministic principle to enforce thermal structures.

Journal reference
Phys. Rev. Lett. 137, 100402 (2026)
DOI
10.1103/df89-tdks
Comments
6+19 pages, 2 figures, updated appendices and references, corrected minor errors and typos, and revised one figure

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Thermal behavior in subsystems of closed quantum systems is commonly attributed to dynamical chaos, quantum ergodicity, canonical typicality, or the eigenstate thermalization hypothesis, suggesting a fundamentally statistical origin of thermalization. Here, we propose a potential alternative mechanism in which thermal structures emerge deterministically from symmetry considerations alone, without recourse to statistical arguments. We prove a finite de Finetti-type theorem for quantum states invariant under energy-preserving unitaries, establishing that the reduced marginals of any such invariant NNN-qudit state are close (both in trace distance and relative entropy) to convex mixtures of thermal product states, with explicit error bounds vanishing as N→∞N \to \inftyN→∞. We further present an example of energy-conserving Lindblad dynamics whose long-time limit is invariant under energy-preserving unitaries, providing a dynamical realization of the desired symmetry class. These results imply that invariance under energy-preserving unitaries suffices as a sole fundamental, deterministic principle to enforce thermal structures.
The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.
The eigenstate thermalization hypothesis (ETH) provides a powerful framework for understanding thermalization in isolated quantum many-body systems, yet a complete and conceptually transparent derivation has remained elusive. In this work, we derive the structure of ETH from a minimal dynamical principle, which we term the eigenstate typicality principle (ETP), together with general kinematic ingredients arising from entropy maximization, Hilbert-space geometry, and locality. ETP asserts that in quantum-chaotic systems, energy eigenstates are statistically indistinguishable, with respect to local measurements, from states drawn from the Haar measure on a narrow microcanonical shell. Within this framework, diagonal ETH arises from concentration of measure, provided that eigenstate typicality holds. The structure of off-diagonal matrix elements is then fixed by entropic scaling and the finite-time dynamical correlations of local observables, with ETP serving as the dynamical bridge to energy eigenstates, without invoking random-matrix assumptions. Our results establish ETH as a consequence of entropy, Hilbert-space geometry, and chaos-induced eigenstate typicality, and clarify its regime of validity across generic quantum-chaotic many-body systems, thereby deepening our understanding of quantum thermalization and the emergence of statistical mechanics from unitary many-body dynamics.
The eigenstate thermalization hypothesis conjectures that for a thermodynamically large system in one of its energy eigenstates, the reduced density matrix describing any finite subsystem is determined solely by a set of relevant conserved quantities. In a chaotic quantum system, only the energy is expected to play that role and hence eigenstates appear locally thermal. Integrable systems, on the other hand, possess an extensive number of such conserved quantities and therefore the reduced density matrix requires specification of all the corresponding parameters (generalized Gibbs ensemble). However, here we show by unbiased statistical sampling of the individual eigenstates with a given finite energy density that the local description of an overwhelming majority of these states of even such an integrable system is actually Gibbs-like, i.e., requires only the energy density of the eigenstate. Rare eigenstates that cannot be represented by the Gibbs ensemble can also be sampled efficiently by our method and their local properties are then shown to be described by appropriately truncated generalized Gibbs ensembles. We further show that the presence of these rare eigenstates differentiates the model from the chaotic case and leads to the system being described by a generalized Gibbs ensemble at long time under a unitary dynamics following a sudden quench, even when the initial state is a typical (Gibbs-like) eigenstate of the prequench Hamiltonian.
The quantum versions of de Finetti's theorem derived so far express the convergence of nnn-partite symmetric states, i.e., states that are invariant under permutations of their nnn parties, toward probabilistic mixtures of independent and identically distributed (IID) states of the form ${\ensuremath{\sigma}}^{\ensuremath{\bigotimes}n}$. Unfortunately, these theorems only hold in finite-dimensional Hilbert spaces, and their direct generalization to infinite-dimensional Hilbert spaces is known to fail. Here, we address this problem by considering invariance under orthogonal transformations in phase space instead of permutations in state space, which leads to a quantum de Finetti theorem particularly relevant to continuous-variable systems. Specifically, an nnn-mode bosonic state that is invariant with respect to this continuous symmetry in phase space is proven to converge toward a probabilistic mixture of IID Gaussian states (actually, nnn identical thermal states).
If we prepare an isolated, interacting quantum system in an eigenstate and perturb a local observable at an initial time, its expectation value will relax towards a thermal expectation value, even though the time evolution of the system is deterministic. The eigenstate thermalization hypothesis (ETH) of Deutsch and Srednicki suggests that this is possible because each eigenstate of the full quantum system acts as a thermal bath to its subsystems, such that the reduced density matrices of the subsystems resemble thermal density matrices. Here, we use the observation that the eigenvalue distribution of interacting quantum systems is a Gaussian under very general circumstances, and Dyson Brownian motion random matrix theory, to derive the ETH and thereby elevate it from hypothesis to theory. Our analysis provides a derivation of statistical mechanics which neither requires the concepts of ergodicity or typicality, nor that of entropy. Thermodynamic equilibrium follows solely from the applicability of quantum mechanics to large systems and the absence of integrability.
Understanding how isolated quantum systems thermalize has recently gathered renewed interest almost 100 years after the first work by von Neumann, thanks to the experimental realizations of such systems. Experimental and numerical pieces of evidence imply that nonintegrability of the system plays an important role in thermalization. Nonintegrable systems that conserve energy alone are expected to be effectively described by the (micro)canonical ensemble due to the so-called eigenstate thermalization hypothesis (ETH) in the thermodynamic limit. In contrast, it is expected that stationary states in integrable systems are described not by the canonical ensemble but by the generalized Gibbs ensemble (GGE) due to the existence of many nontrivial conserved quantities. In this thesis, we study thermalization and its mechanism in nonintegrable systems from two perspectives. We first study how well the ETH and its finite-size corrections can be predicted by random matrix theory (RMT). Next, we present our study on the emergence of the GGE in a nonintegrable system with an extensive number of local symmetries.