Quantum systems are inherently fragile to environmental fluctuations or decoherence, limiting their advantages in applications of quantum information and quantum computation. State purification offers a route to recover the purity of system under noisy conditions. Here, we demonstrate a rapid purification of initially mixed states by harnessing collective reservoir engineering in driven non-Hermitian qubit systems, together with multipartite entanglement generation in larger systems. We show that the onset of efficient purification-assisted entanglement generation is dictated by the degeneracy of collective subradiant modes, rather than by exceptional points. Moreover, the system dynamics manifests an informational Mpemba effect, i.e., a more mixed initial state reaches its steady state with unit purity at a faster rate, resembling the conventional Mpemba effect where a hotter system cools more rapidly. These results reveal a unique advantage of driven non-Hermitian quantum systems with engineered collective dissipation, enabling enhanced purification efficiency and offering new opportunities for relaxation control of non-Hermitian systems and quantum state preparations.
Quantum systems are inherently fragile to environmental fluctuations or decoherence, limiting their advantages in applications of quantum information and quantum computation. State purification offers a route to recover the purity of system under noisy conditions. Here, we demonstrate a rapid purification of initially mixed states by harnessing collective reservoir engineering in driven non-Hermitian qubit systems, together with multipartite entanglement generation in larger systems. We show that the onset of efficient purification-assisted entanglement generation is dictated by the degeneracy of collective subradiant modes, rather than by exceptional points. Moreover, the system dynamics manifests an informational Mpemba effect, i.e., a more mixed initial state reaches its steady state with unit purity at a faster rate, resembling the conventional Mpemba effect where a hotter system cools more rapidly. These results reveal a unique advantage of driven non-Hermitian quantum systems with engineered collective dissipation, enabling enhanced purification efficiency and offering new opportunities for relaxation control of non-Hermitian systems and quantum state preparations.
Generating entanglement rapidly and reliably is essential for quantum information processing, communication, and metrology. Dissipative preparation is attractive because engineered reservoirs robustly drive a system toward an entangled target, yet relaxation can carry a substantial time cost. Here we formulate the entanglement Mpemba effect, whereby an initially less entangled state overtakes a more entangled state under the same open-system dynamics. This effect turns initial-state engineering into a route for faster preparation without altering the dissipative protocol. We derive a general criterion for the reversal from the relaxation spectrum, applicable even when entanglement evolves nonmonotonically. A reversal of deterministic local operations and classical communication (LOCC)-reachability preorder provides a measure-independent certificate of reversed entanglement order. Exactly solvable models show that initial-state selection can substantially shorten the time required to reach high entanglement. We further propose an experimentally relevant trapped-ion protocol that can realize the entanglement Mpemba effect.
An ancient and counterintuitive phenomenon known as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for speeding up relaxation is an important but challenging task in purely quantum system till now. Here, we experimentally study the strong Mpemba effect in a single trapped ion system in which an exponentially accelerated relaxation in time is observed by preparing an optimal quantum initial state with no excitation of the slowest decaying mode. Also, we demonstrate that the condition of realizing such effect coincides with the Liouvillian exceptional point, featuring the coalescence of both the eigenvalues and the eigenmodes of the systems. Our work provides an efficient strategy to engineer the dynamics of open quantum system, and suggests a link unexplored yet between the Mpemba effect and the non-Hermitian physics. The Mpemba effect is an archetype for various anomalous relaxation phenomena. Here, the authors experimentally study a quantum version of the Mpemba effect in a single trapped ion system, where relaxation is exponentially accelerated by removing the excitation of the slowest decaying mode. This phenomenon, seen in Markovian open quantum systems containing Liouvillian exceptional points, indicates a link between the Mpemba effect and non-Hermitian physics.
The Mpemba effect (ME)—where hot systems cool faster than colder ones—has intrigued both classical and quantum thermodynamics. Compared to classical systems, quantum systems add complexity due to quantum correlations. Recent works have explored anomalous relaxation and Mpemba-like effects in several quantum systems, considering isolated systems at zero temperature or open systems in contact with reservoirs under Markovian or non-Markovian dynamics. However, these models typically assume an initial unentangled system–bath state, overlooking the role of initial system–environment correlations. Here we propose a type of quantum ME, distinct from the strong ME, originating solely from initial system–bath entanglement. It is shown that the degree of initial entanglement significantly influences the early relaxation dynamics, with certain conditions causing backflow and retarded thermalization. As an example, we investigate the spontaneous emission of a two-level atom in a photonic waveguide at zero temperature, where an initial atom-photon entangled state results in delayed relaxation and a pronounced ME. These findings highlight the crucial role of quantum correlations in thermalization processes and open new avenues for identifying and engineering quantum Mpemba phenomena. Controlling relaxation dynamics through system–environment entanglement may have potential applications in quantum thermal machines, state initialization protocols, and quantum information processing, where precise control over thermalization is essential.
The Mpemba effect, where a hotter system cools faster than a colder one under otherwise identical conditions, has been extensively studied in classical systems. In this work, we present the quantum analogue of the Mpemba effect using a dissipative qubit, which is referred to as the canonical quantum Mpemba effect. We demonstrate that, under the identical conditions, the relaxation dynamics of a qubit initialized in a thermal state with a higher temperature can be exponentially faster than those of a colder thermal state. Strikingly, this acceleration is determined solely by the initial temperature of the system, independent of other parameters. The relaxation is confirmed to be a genuine cooling process via the effective steady state temperature, mirroring its classical counterpart. Last, we propose a practical classical quantum hybrid algorithmic quantum circuit to realize this effect using superconducting qubits experimentally.
Since its rediscovery in the twentieth century, the Mpemba effect, where a far-from-equilibrium state may relax faster than a state closer to equilibrium, has been extensively studied in classical systems and has recently received attention in quantum systems. Many theories explaining this counter-intuitive behavior in classical systems rely on memory effects. However, in quantum systems, the relation between the Mpemba effect and memory has remained unexplored. In this Letter, we consider general non-Markovian open quantum systems and reveal new classes of quantum Mpemba effects, with no analog in Markovian quantum dynamics. Generically, open quantum dynamics possess a finite memory time and a unique steady state. Because of non-Markovian dynamics, even if the system is initialized in the steady state it can take a long time to relax back. We find other initial states that reach the steady state much faster. Most notably, we demonstrate that there can be an initial state in which the system reaches the steady state within the finite memory time itself, giving the fastest possible relaxation to stationarity. We verify the effect for quantum dot systems coupled to electronic reservoirs in equilibrium and nonequilibrium setups at weak, intermediate and strong coupling. Our Letter provides new insights into the rich physics underlying accelerated relaxation in quantum systems.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.