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arXiv:2603.26980

Thermoforesis from generalized Caldeira-Leggett models

Daniel Valente, Maurício Matos, Thiago Werlang

quant-phcond-mat.stat-mechSubmitted Mar 27, 2026• Announced Mar 31, 2026
arXivHTMLPDF

Abstract

The standard Caldeira-Leggett model addresses the problem of Brownian motion in a thermal equilibrium environment. Here, we look for generalizations of the Caldeira-Leggett model to account for thermal gradients in the environment. We devise two types of models, and discuss the advantages and limitations of each one. From both models, we find signatures of thermophoresis, i.e., particle transport due to a thermal gradient. In principle, our models can be employed to describe thermophoresis in quantum Brownian particles, an open problem so far.

Journal reference
Braz. J. Phys. 56, 213 (2026)
DOI
10.1007/s13538-026-02131-6
Comments
10 pages, no figures, submitted to Special Issue "Frontiers in Quantum Mechanics and the 45 Years of the Caldeira-Leggett Model", Braz. J. Phys

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The standard Caldeira-Leggett model addresses the problem of Brownian motion in a thermal equilibrium environment. Here, we look for generalizations of the Caldeira-Leggett model to account for thermal gradients in the environment. We devise two types of models, and discuss the advantages and limitations of each one. From both models, we find signatures of thermophoresis, i.e., particle transport due to a thermal gradient. In principle, our models can be employed to describe thermophoresis in quantum Brownian particles, an open problem so far.
When a classical Brownian particle is subjected to a temperature gradient it can undergo thermophoresis, i.e., the particle gets transported towards the colder regions of the environment, which bears relevant consequences to nonequilibrium self-organization. Here, we investigate how the quantum Brownian motion is affected by a temperature gradient. We employ a recently proposed generalized system-plus-reservoir model, where one assumes a continuum field of thermal baths. As our main result, we obtain the quantum influence functional, within the Feynmann-Vernon path integral approach. To test convergence, we derive an effective Langevin equation for the center of mass of the quantum wavepacket, and show that it coincides with the classical Langevin equation at high temperatures. Both the fully quantum (low temperatures) and the semiclassical (high temperature) limits show signatures of quantum thermophoresis in the quantum Brownian motion, a so far unexplored effect.
Quantum Brownian motion, described by the Caldeira-Leggett model, brings insights to the understanding of phenomena and essence of quantum thermodynamics, especially the quantum work and heat associated with their classical counterparts. By employing the phase-space formulation approach, we study the heat distribution of a relaxation process in the quantum Brownian motion model. The analytical result of the characteristic function of heat is obtained at any relaxation time with an arbitrary friction coefficient. By taking the classical limit, such a result approaches the heat distribution of the classical Brownian motion described by the Langevin equation, indicating the quantum-classical correspondence principle for heat distribution. We also demonstrate that the fluctuating heat at any relaxation time satisfies the exchange fluctuation theorem of heat and its long-time limit reflects the complete thermalization of the system. Our research study justifies the definition of the quantum fluctuating heat via two-point measurements.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
Caldeira and Leggett (CL), in a seminal paper, derived a master equation describing Markovian quantum Brownian motion. Such an equation suffered from not being completely positive, and many efforts have been made to solve this issue. We show that when a careful mathematical analysis is performed, the model considered by CL leads to a nondissipative master equation. We argue that the correct way to understand the master equation derived in the CL regime is to consider it non-Markovian. Moreover, we show that if one wants to provide a microscopic description of quantum Brownian motion with the CL model, one always needs to consider a non-Markovian dynamics. We conclude that dissipation is a genuinely non-Markovian feature.