Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2603.26793

Chiral moments make chiral measures

Emilio Pisanty, Nicola Mayer, Andrés Ordóñez, Alexander Löhr, Margarita Khokhlova

physics.data-anphysics.opticsquant-phSubmitted Mar 25, 2026• Announced Mar 27, 2026
arXivHTMLPDF

Abstract

We develop a family of chiral measures to quantify the chirality of a distribution and assign it a handedness. Our measures are built using the tensorial moments of the distribution, which naturally encode its spatial character, not only via its angular shape consistently with existing multipolar-moment approaches, but also its radial dependence. We combine these tensorial moments into a rotationally-invariant pseudoscalar using a newly-defined cross product and triple product for arbitrary symmetric tensors. We analyze these measures for a variety of toy-model distributions, providing intuition for the geometry and guiding the choice of chiral measure optimal for a given distribution. We also apply our measures to a physically-motivated example coming from photoionization in polychromatic chiral light. Our work provides a robust, flexible, intuitive, highly geometrical, and physically-driven framework for understanding and quantifying the chirality of a wide variety of distributions, together with an open-source software package that makes this toolbox readily applicable for the analysis of numerical or experimental data.

Comments
8 pages main text, 24 pages with appendices and references

Related papers

Chiral Temporal Structures in Molecular Rotational Dynamics

Alexander Gabriel Löhr, O. Smirnova, M. Mirahmadi

We introduce chiral rotational wavepackets: coherent superpositions of a few low-lying rotational states of a molecule for which the expectation value of a molecular axis traces a three-dimensional chiral trajectory in the laboratory frame. The handedness is a dynamical property of the quantum state rather than of the equilibrium structure, and we show that it can be imprinted on linear rotors as well as on spherical and symmetric tops. We derive the action of space inversion, time reversal, and their product on such wavepackets in the Wigner $D^J_{MK}$ basis, and define the rotational enantiomers of a given wavepacket. To quantify their handedness we introduce two derivative-based pseudoscalar measures: a geometrical measure built from the curvature and torsion of the trajectory, which is even under time reversal, and a dynamical measure, which is odd under time reversal. The latter is shown to be proportional to the geodesic curvature of the trajectory projected onto the unit sphere, which links it, via the Gauss--Bonnet theorem, to the solid angle enclosed by the projected trajectory and to the parallel-transport holonomy of a molecule-fixed vector. Finally we show that a nonzero geometrical measure is a sufficient condition for the wavepacket to exhibit true chirality through its orientation trajectory in the sense of Barron.

arXiv:2609.37896•Sep 29, 2026•0 citations

Geometric mechanisms enabling spin- and enantio-sensitive observables in one photon ionization of chiral molecules

Philip Caesar M. Flores, Stefanos Carlström, Serguei Patchkovskii +3 more

We examine spin-resolved photoionization of randomly oriented chiral molecules via circularly polarized light, and revisit earlier predictions of Cherepkov (J. Phys. B: Atom. Mol. Phys. 16, 1543, 1983). We will show that the dynamical origin of spin- and enantio-sensitive observables arise from two intrinsic mechanisms that are quantified by two pseudovectors stemming from the geometric properties of the photoionization dipoles in spin space and in real space, and an extrinsic mechanism which is a directional bias introduced by the well-defined direction of light polarization. These mechanisms arise solely from electric dipole interactions. Consequently, this means that the ten independent parameters that was earlier predicted by Cherepkov to fully describe spin-resolved photoionization of chiral molecules can be reduced as moments of these three pseudovectors. We also find that the molecular pseudoscalars describing the spin- and enantio-sensitive components of the yield can be described by the flux of these pseudovectors through the energy shell, which changes sign upon switching enantiomers. Our results provide compact expressions for these observables which provide an intuitive picture on what determines the strength of these spin- and enantio-sensitive observables. The approach can be readily generalized to photoexcitation, multiphoton processes, and arbitrary field polarizations. Regardless of the specific driving conditions, the resulting spin- and enantio-sensitive observables are still controlled by the same three pseudovectors, underscoring their universal role as the primary generators of chirality-induced spin asymmetries, emphasizing their fundamental geometric origin and the universality of the mechanism identified here.

physics.atom-phCross-listedarXiv:2603.02735•Mar 4, 2026

Measures of Chirality in Mixed-State Topological Phases

Shijun Sun, Bader Aldossari, Rasmit Devkota +1 more

What does it mean for a mixed-state topological phase to be chiral? Mathematically, chirality can be sharply characterized through the symmetry algebra of the mixed state. Physically, however, the question is far more subtle. In pure states, chirality in topological phase is tied to a web of familiar diagnostics, involving bulk-boundary correspondence, a gapless entanglement spectrum, a nontrivial modular commutator, and a quantized thermal Hall response. We show that none of these diagnostics remain reliable in mixed states. Instead, for decohered topological phases with a known error-free parent state, we propose two relative-entropy-based measures that can diagnose chirality, with one of them further extracting the chiral central charge. As a concrete example, we use these measures to analyze the $em^2$-decohered $\mathbb{Z}_3$ toric code, identifying the chirality transition to be in the random-bond Potts class for the particle-hole symmetric channel, and the polarized random bond Potts class for asymmetric channels. Our results emphasize how mixed-state topology demands intrinsically new diagnostics beyond direct analogues of pure-state probes.

quant-pharXiv:2606.26235•Jun 26, 2026•0 citations

Properties of tensorial free cumulants

Thomas Buc-d’Alché, Luca Lionni

In the past two years, several points of view have been proposed to address the question of the generalization of the theory of free probability to random tensors with different invariances, and it is unclear at this point whether they lead to the same notions of tensorial free cumulants and freeness. One way to approach this problem, developed by Collins, Gurau and the second named author for local unitary invariant random tensors, relies on finite size quantities involving averages over the invariance group, and whose asymptotics naturally possess the properties expected for tensorial generalizations of free cumulants of arbitrary orders. At this point, this approach has only been carried out for certain distributions, and for a subset of the moments that define such theories, and a more systematic and exhaustive study is lacking. This is the program initiated in this paper: we link this approach to the one proposed by Nechita and Park; extend a number of their results as well as those of the aforementioned paper to arbitrary orders of fluctuations, thereby generalizing higher order free cumulants; push further the study of distributions with larger invariance groups; detail the link with the asymptotics of the free-energies of the tensor HCIZ and BGW integrals; and provide formulae for tensorial free cumulants of products of tensors. Another important question is that of the definition of concrete distributions whose tensorial free-cumulants take non-trivial values. We compute the tensorial free cumulants for Gaussian random tensors with non-trivial covariances, and show that they provide such examples.

arXiv:2605.01887•May 3, 2026•0 citations

Quantum limits to chiroptical molecular discrimination

Mikael P. Backlund

Discriminating enantiomer pairs is of central importance in the molecular sciences. The preferential interaction between chiral light and matter is commonly employed in this discrimination, despite fundamental challenges. Here we present quantitative error bounds for classifying the handedness of a chiral, randomly oriented, quantum optical emitter from the perspective of classical and quantum hypothesis testing. Most interestingly, we find that a collective measurement on $N$ photons can provide an orders-of-magnitude improvement in error rate relative to a corresponding separable measurement.

quant-pharXiv:2607.19136•Jul 22, 2026•0 citations

Position measurement of a levitated particle with vectorial light

Daniel Tandeitnik, Lucas Bianchi, Sebastian Gutierrez-Bernal +3 more

We develop a fully vectorial, semiclassical scattering formalism for optically levitated dipolar scatterers, expressed within the angular spectrum representation and applicable to arbitrary trapping-field configurations as well as to high--numerical-aperture focusing. Within this framework, we introduce the information radiation pattern to characterize the angular distribution of position-dependent information and use a Richards--Wolf projection of the scattered field onto the local-oscillator mode to quantify the resulting mode-matching efficiency, yielding experimentally realistic forward- and backward-detection efficiencies. As a worked example, we apply the formalism to a radially polarized trapping beam and confirm that the axial recoil heating rate is reduced relative to a conventional linearly polarized Gaussian tweezer. The theoretical framework is implemented in LevitationToolbox, an open-source Python package intended to support the design and optimization of near-Heisenberg-limited levitated optomechanical experiments.

physics.opticsCross-listedarXiv:2607.23833•Jul 28, 2026•0 citations
We develop a family of chiral measures to quantify the chirality of a distribution and assign it a handedness. Our measures are built using the tensorial moments of the distribution, which naturally encode its spatial character, not only via its angular shape consistently with existing multipolar-moment approaches, but also its radial dependence. We combine these tensorial moments into a rotationally-invariant pseudoscalar using a newly-defined cross product and triple product for arbitrary symmetric tensors. We analyze these measures for a variety of toy-model distributions, providing intuition for the geometry and guiding the choice of chiral measure optimal for a given distribution. We also apply our measures to a physically-motivated example coming from photoionization in polychromatic chiral light. Our work provides a robust, flexible, intuitive, highly geometrical, and physically-driven framework for understanding and quantifying the chirality of a wide variety of distributions, together with an open-source software package that makes this toolbox readily applicable for the analysis of numerical or experimental data.
We introduce chiral rotational wavepackets: coherent superpositions of a few low-lying rotational states of a molecule for which the expectation value of a molecular axis traces a three-dimensional chiral trajectory in the laboratory frame. The handedness is a dynamical property of the quantum state rather than of the equilibrium structure, and we show that it can be imprinted on linear rotors as well as on spherical and symmetric tops. We derive the action of space inversion, time reversal, and their product on such wavepackets in the Wigner DMKJD^J_{MK}DMKJ​ basis, and define the rotational enantiomers of a given wavepacket. To quantify their handedness we introduce two derivative-based pseudoscalar measures: a geometrical measure built from the curvature and torsion of the trajectory, which is even under time reversal, and a dynamical measure, which is odd under time reversal. The latter is shown to be proportional to the geodesic curvature of the trajectory projected onto the unit sphere, which links it, via the Gauss--Bonnet theorem, to the solid angle enclosed by the projected trajectory and to the parallel-transport holonomy of a molecule-fixed vector. Finally we show that a nonzero geometrical measure is a sufficient condition for the wavepacket to exhibit true chirality through its orientation trajectory in the sense of Barron.
We examine spin-resolved photoionization of randomly oriented chiral molecules via circularly polarized light, and revisit earlier predictions of Cherepkov (J. Phys. B: Atom. Mol. Phys. 16, 1543, 1983). We will show that the dynamical origin of spin- and enantio-sensitive observables arise from two intrinsic mechanisms that are quantified by two pseudovectors stemming from the geometric properties of the photoionization dipoles in spin space and in real space, and an extrinsic mechanism which is a directional bias introduced by the well-defined direction of light polarization. These mechanisms arise solely from electric dipole interactions. Consequently, this means that the ten independent parameters that was earlier predicted by Cherepkov to fully describe spin-resolved photoionization of chiral molecules can be reduced as moments of these three pseudovectors. We also find that the molecular pseudoscalars describing the spin- and enantio-sensitive components of the yield can be described by the flux of these pseudovectors through the energy shell, which changes sign upon switching enantiomers. Our results provide compact expressions for these observables which provide an intuitive picture on what determines the strength of these spin- and enantio-sensitive observables. The approach can be readily generalized to photoexcitation, multiphoton processes, and arbitrary field polarizations. Regardless of the specific driving conditions, the resulting spin- and enantio-sensitive observables are still controlled by the same three pseudovectors, underscoring their universal role as the primary generators of chirality-induced spin asymmetries, emphasizing their fundamental geometric origin and the universality of the mechanism identified here.
What does it mean for a mixed-state topological phase to be chiral? Mathematically, chirality can be sharply characterized through the symmetry algebra of the mixed state. Physically, however, the question is far more subtle. In pure states, chirality in topological phase is tied to a web of familiar diagnostics, involving bulk-boundary correspondence, a gapless entanglement spectrum, a nontrivial modular commutator, and a quantized thermal Hall response. We show that none of these diagnostics remain reliable in mixed states. Instead, for decohered topological phases with a known error-free parent state, we propose two relative-entropy-based measures that can diagnose chirality, with one of them further extracting the chiral central charge. As a concrete example, we use these measures to analyze the em2em^2em2-decohered Z3\mathbb{Z}_3Z3​ toric code, identifying the chirality transition to be in the random-bond Potts class for the particle-hole symmetric channel, and the polarized random bond Potts class for asymmetric channels. Our results emphasize how mixed-state topology demands intrinsically new diagnostics beyond direct analogues of pure-state probes.
In the past two years, several points of view have been proposed to address the question of the generalization of the theory of free probability to random tensors with different invariances, and it is unclear at this point whether they lead to the same notions of tensorial free cumulants and freeness. One way to approach this problem, developed by Collins, Gurau and the second named author for local unitary invariant random tensors, relies on finite size quantities involving averages over the invariance group, and whose asymptotics naturally possess the properties expected for tensorial generalizations of free cumulants of arbitrary orders. At this point, this approach has only been carried out for certain distributions, and for a subset of the moments that define such theories, and a more systematic and exhaustive study is lacking. This is the program initiated in this paper: we link this approach to the one proposed by Nechita and Park; extend a number of their results as well as those of the aforementioned paper to arbitrary orders of fluctuations, thereby generalizing higher order free cumulants; push further the study of distributions with larger invariance groups; detail the link with the asymptotics of the free-energies of the tensor HCIZ and BGW integrals; and provide formulae for tensorial free cumulants of products of tensors. Another important question is that of the definition of concrete distributions whose tensorial free-cumulants take non-trivial values. We compute the tensorial free cumulants for Gaussian random tensors with non-trivial covariances, and show that they provide such examples.
Discriminating enantiomer pairs is of central importance in the molecular sciences. The preferential interaction between chiral light and matter is commonly employed in this discrimination, despite fundamental challenges. Here we present quantitative error bounds for classifying the handedness of a chiral, randomly oriented, quantum optical emitter from the perspective of classical and quantum hypothesis testing. Most interestingly, we find that a collective measurement on NNN photons can provide an orders-of-magnitude improvement in error rate relative to a corresponding separable measurement.
We develop a fully vectorial, semiclassical scattering formalism for optically levitated dipolar scatterers, expressed within the angular spectrum representation and applicable to arbitrary trapping-field configurations as well as to high--numerical-aperture focusing. Within this framework, we introduce the information radiation pattern to characterize the angular distribution of position-dependent information and use a Richards--Wolf projection of the scattered field onto the local-oscillator mode to quantify the resulting mode-matching efficiency, yielding experimentally realistic forward- and backward-detection efficiencies. As a worked example, we apply the formalism to a radially polarized trapping beam and confirm that the axial recoil heating rate is reduced relative to a conventional linearly polarized Gaussian tweezer. The theoretical framework is implemented in LevitationToolbox, an open-source Python package intended to support the design and optimization of near-Heisenberg-limited levitated optomechanical experiments.