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arXiv:2603.19631

Beyond-Ten-Hour Coherence in a Decoherence-Free Trapped-Ion Clock Qubit

Jiahao Pi, Xiangjia Liu, Junle Cao, Pengfei Wang, Lingfeng Ou, Erfu Gao, Hengchao Tu, Menglin Zou, Xiang Zhang, Junhua Zhang, Kihwan Kim

quant-phSubmitted Mar 20, 2026• Announced Mar 23, 2026• 0 citations
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Abstract

Quantum systems promise to revolutionize information processing science and technology [1-3]. The preservation of quantum coherence, the defining property of qubits, fundamentally constrains the performance of quantum information processing with quantum memories [4]. While trapped atomic ions theoretically support million-year coherence based on spontaneous emission [5-7], experimental demonstrations have reached far less, only about an hour [8-13]. Here we combine clock-state qubits with decoherence-free subspace (DFS) encoding to achieve coherence exceeding ten hours. Using correlation-based phase tracking in 171Yb+ ion pairs sympathetically cooled by 138Ba+ ion, we demonstrate this without magnetic shielding or enhanced microwave phase stabilization that previously limited coherence times. DFS encoding references the qubit phase to the inter-ion energy difference to reject microwave phase noise and common-mode magnetic fluctuations, while clock states provide environmental insensitivity. Throughout measurements extended to 1600 seconds, we observe minimal coherence decay, with exponential fits yielding a coherence time of (3.77 +/- 1.09) x 10^4 seconds. Our results establish DFS encoding as a form of passive error correction that eliminates technical noise constraints, unlocking the million-year coherence potential of atomic ions for scalable quantum information processing.

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•Feb 1, 2018•3 citations
Quantum systems promise to revolutionize information processing science and technology [1-3]. The preservation of quantum coherence, the defining property of qubits, fundamentally constrains the performance of quantum information processing with quantum memories [4]. While trapped atomic ions theoretically support million-year coherence based on spontaneous emission [5-7], experimental demonstrations have reached far less, only about an hour [8-13]. Here we combine clock-state qubits with decoherence-free subspace (DFS) encoding to achieve coherence exceeding ten hours. Using correlation-based phase tracking in 171Yb+ ion pairs sympathetically cooled by 138Ba+ ion, we demonstrate this without magnetic shielding or enhanced microwave phase stabilization that previously limited coherence times. DFS encoding references the qubit phase to the inter-ion energy difference to reject microwave phase noise and common-mode magnetic fluctuations, while clock states provide environmental insensitivity. Throughout measurements extended to 1600 seconds, we observe minimal coherence decay, with exponential fits yielding a coherence time of (3.77 +/- 1.09) x 10^4 seconds. Our results establish DFS encoding as a form of passive error correction that eliminates technical noise constraints, unlocking the million-year coherence potential of atomic ions for scalable quantum information processing.
Abstract Realizing a long coherence time quantum memory is a major challenge of current quantum technology. Until now, the longest coherence-time of a single qubit was reported as 660 s in a single 171 Yb + ion-qubit through the technical developments of sympathetic cooling and dynamical decoupling pulses, which addressed heating-induced detection inefficiency and magnetic field fluctuations. However, it was not clear what prohibited further enhancement. Here, we identify and suppress the limiting factors, which are the remaining magnetic-field fluctuations, frequency instability and leakage of the microwave reference-oscillator. Then, we observe the coherence time of around 5500 s for the 171 Yb + ion-qubit, which is the time constant of the exponential decay fit from the measurements up to 960 s. We also systematically study the decoherence process of the quantum memory by using quantum process tomography and analyze the results by applying recently developed resource theories of quantum memory and coherence. Our experimental demonstration will accelerate practical applications of quantum memories for various quantum information processing, especially in the noisy-intermediate-scale quantum regime.
Quantum memory device capable of storing quantum information for a long period of time is one of the fundamental ingredients to realize large-scale quantum computation and quantum communication. Comparing with other quantum computation platforms, one of the advantages of the trapped-ion system is the long intrinsic coherence time. Before our work, the longest single-qubit coherence time in trapped-ion systems has been achieved to be less than 1 minute. It is discovered that the main limitation for the coherence time is the motional mode heating and the environment noise that includes the contributions from the magnetic field fluctuation and the phase noise of the microwaves. In a hybrid trapping system simultaneously trapping 171Yb+ and 138Ba+ ions, single-qubit quantum memories with coherence time longer than 10 minutes can be realized by applying sympathetic cooling and dynamical decoupling. This technique may have some value as the building blocks for quantum cryptography protocols and hybrid quantum computation platforms.
A quantum memory is an essential element for quantum computation, quantum network and quantum metrology. Previously, a single-qubit quantum memory with a coherence time of about an hour has been realized in a dual-species setup where a coolant ion provides sympathetic cooling for a memory ion of different species. However, the frequent random position hopping between the ions in the room-temperature trap limits the technique there only applicable to single-qubit storage. Here we report a multi-ion quantum memory in a cryogenic trap based on the dual-type scheme, and demonstrate a coherence time above two hours for a logical qubit encoded in the decoherence-free subspace, i.e. two-ion entangled states, after correcting the dominant leakage error. Our scheme alleviates the necessity of an ultra-stable frequency reference for the stored qubit, and has a preferable scalability owing to the same mass of the metastable-state memory ions and the ground-state coolant ion.
The maintenance of quantum entanglement lays the elementary building block of quantum information processing, requiring an integration of long coherence time, sufficient storage capacity, and high-fidelity entangling gates. Here we encode two-qubit entangled states into the decoherence-free subspaces (DFS) of four ions in a cryogenic trap. By crosstalk-free sympathetic cooling under dual-type encoding and multi-state detection which discards the collision-induced leakage error, we achieve a storage lifetime of about one hour for the entangled logical states. We further study the second-order DFS and show its advantage in suppressing the spatially nonuniform noise over the first-order DFS. Our work paves the way for applications of DFS quantum memories in quantum computing, quantum network and precision measurement.
A quantum memory is an essential element for quantum computation, quantum networks, and quantum metrology. Previously, a single-qubit quantum memory with a coherence time of about an hour has been realized in a dual-species setup where a coolant ion provides sympathetic cooling for a memory ion of a different species. However, the frequent random position hopping between the ions in the room-temperature trap limits the technique to be applicable only to single-qubit storage. Here, we report a multi-ion quantum memory in a cryogenic trap based on the dual-type scheme and demonstrate a coherence time above two hours for a qubit encoded in the decoherence-free subspace, i.e., two-ion entangled states, after correcting the dominant leakage error. Our scheme alleviates the necessity of an ultrastable frequency reference for the stored qubit, and it has a preferable scalability owing to the same mass of the metastable-state memory ions and the ground-state coolant ion.
Trapped atomic ions are a promising candidate system for developing a quantum computer. All elementary operations for quantum information processing have al- ready been achieved in trapped-ion systems with errors below the “fault-tolerant threshold”, meaning that these errors are sufficiently small to be removed with quan- tum error correction. However, the preservation of quantum information over the short timescales that are relevant for quantum computing has not, to our knowledge, been measured before in trapped-ion qubits. Previous investigations have measured decoherence over long times and extrapolated an exponential decay model to short times. We directly measure the qubit memory error rate over short timescales, which is made possible by the high-fidelity single-qubit gates and state preparation and mea- surement in our system. Our qubit is a hyperfine “atomic clock” transition in 43Ca+, and gates are applied with near-field microwaves. We find that the assumption of exponential decay of qubit state coherence does not apply in our system. The data is fit well by a model of 1/f frequency noise with a low-frequency cutoff. The small- est memory error that we measure is 3(1)×10−6 over 2ms. The time at which our qubit memory error is 1×10−3, an important threshold for viable quantum error correction, is ≈400ms. We also present a design study into a new ion trap electrode geometry for applying near-field microwave two-qubit gates. This design features an ‘S’-shaped meander electrode to passively null the microwave field at the ions’ locations. It has improved isolation between the meander and other electrodes compared to previous work on this, which should reduce the sensitivity of the microwave field distribution to the boundary conditions of these electrodes. We show that the trap would allow for ion chains to be trapped, transported and split with feasible DC and RF voltages.