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arXiv:2603.07190

Long-time storage of entangled logical states in decoherence-free subspaces

L. Zhang, Y. -L. Xu, Y. -K. Wu, C. Zhang, Z. -B. Cui, Y. -Y. Chen, W. -Q. Lian, J. -Y. Ma, B. -X. Qi, Y. -F. Pu, Z. -C. Zhou, L. He, P. -Y. Hou, L. -M. Duan

quant-phSubmitted Mar 7, 2026• Announced Mar 10, 2026• 0 citations
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Abstract

The maintenance of quantum entanglement lays the elementary building block of quantum information processing, requiring an integration of long coherence time, sufficient storage capacity, and high-fidelity entangling gates. Here we encode two-qubit entangled states into the decoherence-free subspaces (DFS) of four ions in a cryogenic trap. By crosstalk-free sympathetic cooling under dual-type encoding and multi-state detection which discards the collision-induced leakage error, we achieve a storage lifetime of about one hour for the entangled logical states. We further study the second-order DFS and show its advantage in suppressing the spatially nonuniform noise over the first-order DFS. Our work paves the way for applications of DFS quantum memories in quantum computing, quantum network and precision measurement.

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The maintenance of quantum entanglement lays the elementary building block of quantum information processing, requiring an integration of long coherence time, sufficient storage capacity, and high-fidelity entangling gates. Here we encode two-qubit entangled states into the decoherence-free subspaces (DFS) of four ions in a cryogenic trap. By crosstalk-free sympathetic cooling under dual-type encoding and multi-state detection which discards the collision-induced leakage error, we achieve a storage lifetime of about one hour for the entangled logical states. We further study the second-order DFS and show its advantage in suppressing the spatially nonuniform noise over the first-order DFS. Our work paves the way for applications of DFS quantum memories in quantum computing, quantum network and precision measurement.
A quantum memory is an essential element for quantum computation, quantum networks, and quantum metrology. Previously, a single-qubit quantum memory with a coherence time of about an hour has been realized in a dual-species setup where a coolant ion provides sympathetic cooling for a memory ion of a different species. However, the frequent random position hopping between the ions in the room-temperature trap limits the technique to be applicable only to single-qubit storage. Here, we report a multi-ion quantum memory in a cryogenic trap based on the dual-type scheme and demonstrate a coherence time above two hours for a qubit encoded in the decoherence-free subspace, i.e., two-ion entangled states, after correcting the dominant leakage error. Our scheme alleviates the necessity of an ultrastable frequency reference for the stored qubit, and it has a preferable scalability owing to the same mass of the metastable-state memory ions and the ground-state coolant ion.
Quantum systems promise to revolutionize information processing science and technology [1-3]. The preservation of quantum coherence, the defining property of qubits, fundamentally constrains the performance of quantum information processing with quantum memories [4]. While trapped atomic ions theoretically support million-year coherence based on spontaneous emission [5-7], experimental demonstrations have reached far less, only about an hour [8-13]. Here we combine clock-state qubits with decoherence-free subspace (DFS) encoding to achieve coherence exceeding ten hours. Using correlation-based phase tracking in 171Yb+ ion pairs sympathetically cooled by 138Ba+ ion, we demonstrate this without magnetic shielding or enhanced microwave phase stabilization that previously limited coherence times. DFS encoding references the qubit phase to the inter-ion energy difference to reject microwave phase noise and common-mode magnetic fluctuations, while clock states provide environmental insensitivity. Throughout measurements extended to 1600 seconds, we observe minimal coherence decay, with exponential fits yielding a coherence time of (3.77 +/- 1.09) x 10^4 seconds. Our results establish DFS encoding as a form of passive error correction that eliminates technical noise constraints, unlocking the million-year coherence potential of atomic ions for scalable quantum information processing.
A quantum memory is an essential element for quantum computation, quantum network and quantum metrology. Previously, a single-qubit quantum memory with a coherence time of about an hour has been realized in a dual-species setup where a coolant ion provides sympathetic cooling for a memory ion of different species. However, the frequent random position hopping between the ions in the room-temperature trap limits the technique there only applicable to single-qubit storage. Here we report a multi-ion quantum memory in a cryogenic trap based on the dual-type scheme, and demonstrate a coherence time above two hours for a logical qubit encoded in the decoherence-free subspace, i.e. two-ion entangled states, after correcting the dominant leakage error. Our scheme alleviates the necessity of an ultra-stable frequency reference for the stored qubit, and has a preferable scalability owing to the same mass of the metastable-state memory ions and the ground-state coolant ion.
We demonstrate a decoherence-free quantum memory of one qubit. By encoding the qubit into the decoherence-free subspace (DFS) of a pair of trapped 9Be+ ions, we protect the qubit from environment-induced dephasing that limits the storage time of a qubit composed of a single ion. We measured the storage time under ambient conditions and under interaction with an engineered noisy environment and observed that encoding into the DFS increases the storage time by up to an order of magnitude. The encoding reversibly transfers an arbitrary qubit stored in a single ion to the DFS of two ions.
We demonstrate a decoherence-free quantum memory of one qubit. By encoding the qubit into the decoherence-free subspace (DFS) of a pair of trapped 9Be+ ions, we protect the qubit from environment-induced dephasing that limits the storage time of a qubit composed of a single ion. We measured the storage time under ambient conditions and under interaction with an engineered noisy environment and observed that encoding into the DFS increases the storage time by up to an order of magnitude. The encoding reversibly transfers an arbitrary qubit stored in a single ion to the DFS of two ions.
We review recent experiments on entanglement, Bell's inequality, and decoherence-free subspaces in a quantum register of trapped \be ions. We have demonstrated entanglement of up to four ions using the technique of Mølmer and Sørensen. This method produces the state |down down> + |up up> for two ions and the state |down down down down> + |up up up up> for four ions. We generate the entanglement deterministically in each shot of the experiment. Measurements on the two-ion entangled state violates Bell's inequality at the 8σ8σ8σ level. Because of the high detector efficiency of our apparatus, this experiment closes the detector loophole for Bell's inequality measurements for the first time. This measurement is also the first violation of Bell's inequality by massive particles that does not implicitly assume results from quantum mechanics. Finally, we have demonstrated reversible encoding of an arbitrary qubit, originally contained in one ion, into a decoherence-free subspace (DFS) of two ions. The DFS-encoded qubit resists applied collective dephasing noise and retains coherence under ambient conditions 3.6 times longer than does an unencoded qubit. The encoding method, which uses single-ion gates and the two-ion entangling gate, demonstrates all the elements required for two-qubit universal quantum logic.