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arXiv:2603.10415

Tight Quantum Speed Limit for Ergotropy Charging in the N-Qubit Dicke Battery

Anass Jad, Abderrahim El Allati

quant-phmath-phSubmitted Mar 11, 2026• Announced Mar 12, 2026• 0 citations• Revised Mar 17, 2026 (v2)
v1 · Mar 11, 2026v2 · Mar 17, 2026v3 · Oct 20, 2026
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Abstract

We derive and analytically prove a tight quantum speed limit (QSL) for ergotropy charging in the $N$-qubit Dicke quantum battery: the first-passage time to normalised ergotropy $ε$ satisfies $τ^{*}(ε) \geq \sqrt{Nε}/(2λ\sqrt{\bar{n}})$, where $λ$ is the coupling and $\bar{n}$ is the mean charger photon number. The bound follows from an exact perturbative identity $ε(t) = Aλ^2\bar{n}t^2 + \mathcal{O}((λt)^4)$, where $A=4/N$ is the short-time ergotropy coefficient, combined with a global upper bound proved analytically for all $N$. The composite parameter $Γ_N = 2λ\sqrt{\bar{n}/N}$ is the unique figure of merit for charging speed; all protocols collapse onto $Γ_N τ^{*} \geq \sqrtε$, with the bound saturated to within 1% at small $ε$.

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Abstract Quantum batteries (QBs)—small-scale energy storage devices based on quantum systems—offer the potential for enhanced charging performance through quantum effects such as coherence and collectivity. In this work, we study the collective charging of QBs consisting of N qubits, coupled to a driven qubit charger in a star configuration, with controlled pure dephasing acting on the charger. We investigate how an ‘asymptotic freedom’-like behavior—in which all the energy deposited into the battery can be extracted as work, resulting in the ergotropy-to-energy ratio approaching unity—can emerge in the steady state of the battery. We show that the ergotropy-to-energy ratio increases with the number of qubits and approaches unity asymptotically as 1 − O ( 1 / N ) . In the large- N limit, the emergence of approximate ground-state degeneracy of the collective battery system leads to this asymptotic freedom behavior, despite the battery state remaining mixed. We also discuss the scaling behavior of the charging time of the battery with N .
A quantum battery (QB) is an energy storage and extraction device that is governed by the principles of quantum mechanics. Here we propose a three-level Dicke QB and investigate its charging process by considering three quantum optical states: a Fock state, a coherent state, and a squeezed state. The performance of the QB in a coherent state is significantly superior to that in a Fock or squeezed state. We show that the locked energy is positively related to the entanglement between the charger and the battery, and diminishing the entanglement increases the ergotropy. The role of quantum phase transitions in the charging process of the QB system is analyzed and we find that the behavior of maximum stored energy is jointly determined by ground and excited-state quantum phase transitions. We further demonstrate that, no matter what the initial state is, the stored energy can be completely extracted when NNN is small (N=10N=10N=10), far below the thermodynamic limit, and the charging power follows a behavior consistent with that of the stored energy.
We reconsider the quantum energetics and quantum thermodynamics of the charging process of a simple, two-component quantum battery model made up of a charger qubit and a single--cell battery qubit. We allow for the initial quantum state of the charger to lie anywhere on the surface of the Bloch sphere, and find the generalized analytical expressions describing the stored energy, ergotropy and capacity of the battery, all of which depend upon the initial Bloch sphere polar angle in a manner evocative of the quantum area theorem. The origin of the ergotropy produced, as well as the genesis of the battery capacity, can be readily traced back to the quantum coherences and population inversions generated (and the balance between these two mechanisms is contingent upon the starting Bloch polar angle). Importantly, the ergotropic charging power and its associated optimal charging time display notable deviations from standard results which disregard thermodynamic considerations. Our theoretical groundwork may be useful for guiding forthcoming experiments in quantum energy science based upon coupled two-level systems.
We explore coherent ergotropy extraction in quantum batteries from a resource-geometric point of view. For an initial state ρρρ, we quantify the coherent extraction process by the coherent ergotropy Ec(ρ)\mathcal{E}_c(ρ)Ec​(ρ) and the coherent extraction distance Dcext(ρ)D_c^{\rm ext}(ρ)Dcext​(ρ) between the active state σρσ_ρσρ​ and the passive state PρP_ρPρ​. This defines the geometric power capacity Πc(ρ)=Ec(ρ)/Dcext(ρ)Π_c(ρ)=\mathcal{E}_c(ρ)/D_c^{\rm ext}(ρ)Πc​(ρ)=Ec​(ρ)/Dcext​(ρ), which measures the coherent ergotropy released unit minimal unitary distance. We prove that, for any driving Hamiltonian satisfying ∥Vt∥≤ν\|V_t\|\leqν∥Vt​∥≤ν, the actual coherent discharging power is bounded by Pcext(ρ;Vt)≤νΠc(ρ)P_c^{\rm ext}(ρ;V_t)\leq νΠ_c(ρ)Pcext​(ρ;Vt​)≤νΠc​(ρ), showing that Πc(ρ)Π_c(ρ)Πc​(ρ) is a capacity under unit driving norm rather than the power of a particular protocol. General bounds on Πc(ρ)Π_c(ρ)Πc​(ρ) are derived by combining relative entropy bounds on coherent ergotropy with geometric bounds on the coherent extraction distance. We also formulate coherence measure induced bounds and protocol-corrected capacities involving the effective speed of a given Hamiltonian. Qubit and qutrit examples demonstrate that Πc(ρ)Π_c(ρ)Πc​(ρ) captures a resource-geometric feature of coherent discharging beyond coherent ergotropy or coherence measures alone.
We consider a central-spin battery where Nb{N}_{b}Nb​ central spins serve as battery cells and Nc{N}_{c}Nc​ bath spins serve as charging units. It is shown that the energy stored in the battery that can be extractable is quantified by the ergotropy, and that battery-charger entanglement is quantified via the Von Neumann entropy. By using an exact approach to a one-cell and two-cell battery, our analytical results suggest that, during the charging process, the extractable work slowly increases before the battery-charger entanglement reaches its maximum and then it will rapidly increase when the entanglement begins to decrease. In particular, we rigorously show that there is an inverse relationship between the extractable work and the entanglement at the end of the charging process. Moreover, we investigate different approaches to realize optimal work extraction without wasted energy. Among them a central-spin battery with an unpolarized Dicke state as the charger possesses a universal charging time $\ensuremath{\propto}1/{N}_{c}$, large extractable work and Nc\sqrt{{N}_{c}}Nc​​-improvement of charging power compared with the battery in the Tavis-Cummings limit. The above-mentioned results have also been numerically verified in multicell batteries. Our results pave the way to improve extractable work storage in the central-spin battery and highlight a competitive relation between the extractable work and the battery-charger entanglement.
We propose charging protocols for quantum batteries based on quantum superpositions of trajectories. Specifically, we consider that a qubit (the battery) interacts with multiple cavities or a single cavity at various positions, where the cavities act as chargers. Further, we introduce a quantum control prepared in a quantum superposition state, allowing the battery to be simultaneously charged by multiple cavities (the multiple-charger protocol) or a single cavity with different entry positions (the single-charger protocol). To assess the battery's performance, we evaluate the maximum extractable work, referred to as ergotropy. The primary discovery lies in the quick charging effect, wherein we prove that the increase in ergotropy stems from the quantum coherence initially present in the quantum control. Moreover, the induced “Dicke-type interference effect” in the single-charger protocol can further lead to a “perfect charging phenomenon”, enabling a complete conversion of the stored energy into extractable work across the entire charging process, with just two entry positions in superposition. Furthermore, we propose circuit models for these charging protocols and conduct proof-of-principle demonstrations on IBMQ and IonQ quantum processors. The results validate our theoretical predictions, demonstrating a clear enhancement in ergotropy. Published by the American Physical Society 2024