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arXiv:2603.08458 · The Journal of Chemical Physics

The Transfer Tensor Method: an Analytical Study Case

Marcel Morillas-Rozas, Alberto López-García, Gonzalo Reina Rivero, Jianshu Cao, Javier Cerrillo

quant-phSubmitted Mar 9, 2026• Announced Mar 10, 2026• 1 citation• Revised Sep 17, 2026 (v2)

v1 · Mar 9, 2026 v2 · Sep 17, 2026

Abstract

The transfer tensor method is a versatile tool for analyzing and propagating general open quantum systems. It captures in a compact manner all memory effects in a non-Markovian system through a straightforward transformation of a set of dynamical maps. Transfer tensors provide the exact convolutional propagator associated with a given time discretization over the past evolution of an open quantum system. Here we show that, for any finite time discretization, the memory kernel of the Nakajima Zwanzig equation deviates from the exact transfer tensors, although both converge in the continuous-time limit, as expected. We examine this behaviour in the context of an analytically solvable model: a two level atom resonant with a lossy cavity in the Jaynes Cummings limit. The atomic dynamics separate into two decoupled degrees of freedom -- the coherence and the population inversion. We derive exact expressions for the dynamical map, the transfer tensors and the memory kernel governing the coherence, and we relate them to their counterparts for the population inversion. As a function of the ratio between the cavity loss rate and the atom-cavity coupling strength, we identify regions of enhanced non-Markovianity in which the system can be described as fully Markovian for certain time-step choices.

Journal reference: J. Chem. Phys. 165, 054108 (2026)
DOI: 10.1063/5.0340784
Comments: Comments are welcome. 9 pages, 7 figures

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The dynamics of an open quantum system is non-Markovian when memory effect is non-negligible. The quantum memory effect is a very complex issue and presently there is no universally accepted method to quantify it. By examining the memory kernel of the Nakajima-Zwanzig master equation, we study the memory effect in a theoretical model consisting of a spin coupled to an environment of an Ising spin chain subject to a transverse field. We find that it can be dictated by either the time correlation in the environment, or the system-environment correlation, depending on the strength of the transverse field and the state of the environment. We analyze the information loss to the environment and backflow from it, and discover that the information flow is not always a reliable indicator for the nature of the dynamics.

We extend the Nakajima-Zwanzig projection operator technique to the determination of multitime correlation functions of open quantum systems. The correlation functions are expressed in terms of certain multitime homogeneous and inhomogeneous memory kernels for which suitable equations of motion are derived. We show that under the condition of finite memory times, these equations can be used to determine the memory kernels by employing an exact stochastic unraveling of the full system-environment dynamics. The approach thus allows us to combine exact stochastic methods, feasible for short times, with long-time master equation simulations. The applicability of the method is demonstrated by numerical simulations of two-dimensional spectra for a donor-acceptor model, and by comparison of the results with those obtained from the reduced hierarchy equations of motion. We further show that the formalism is also applicable to the time evolution of a periodically driven two-level system initially in equilibrium with its environment.