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arXiv:2603.04660

Photon statistics in waveguide QED: II Exact solutions in a thermodynamic limit

M. Eltohfa, F. Robicheaux

quant-phphysics.atom-phSubmitted Mar 4, 2026• Announced Mar 6, 2026• 0 citations
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Abstract

Waveguide quantum electrodynamics (WQED) offers a powerful framework for controlling light-matter interactions and realizing collective phenomena such as super- and subradiance. In general waveguide settings, the quantum dynamics spans the full Hilbert space, rendering exact theoretical treatments exponentially difficult and currently out of reach, and only a few models have exact, analytical solutions. Motivated by recent experiments, we treat the thermodynamic limit of the number of atoms, $N \rightarrow \infty$, while the homogeneous atom-waveguide coupling $β\rightarrow 0$ keeping the optical depth $4Nβ$ fixed. In this limit, a second order mean field method is exact, giving analytical solutions for the statistics of the photons emitted in the waveguide both for chiral and symmetric configurations starting from full inversion. As $N \rightarrow \infty$, the emission in freespace approaches that of an independent ensemble. However, until a special time, $\approx 1.59 \times$ the lifetime of a single-atom, we show an exponentially enhanced superradiance in the waveguide as the optical depth increases. After the special time, the emission into the waveguide exhibits subradiance. We also show that the initial shot-to-shot fluctuations in the rate of emission into the waveguide diminish in a chiral system and vanish in a symmetric system as $N$ approaches $\infty$. Additionally, the equal-time second-order correlation becomes trivial, showing that finite-size effects are essential to observe the emergence of second-order coherence. Finally, going beyond the thermodynamic limit requires higher order mean field methods. Our results illustrate finite- and infinite-body collective effects in symmetric and symmetry-lacking systems.

Related papers

Photon statistics in chiral waveguide QED: I Mean field and perturbative expansions

M. Eltohfa, F. Robicheaux

Waveguide Quantum Electrodynamics (WQED) offers a suitable stage for controlling the interaction of light with atoms, allowing for collective phenomena such as super- and subradiance. In a chiral waveguide setup, the quantum state evolves through all the Hilbert space, rendering an exact theoretical treatment exponentially hard and unobtained to date for more than $\sim 20$ atoms. In this work, we use a computationally efficient higher order mean-field approximation to model the radiation dynamics in a chirally coupled array of atoms, showing good agreement with recent experimental results. Further, based on a perturbative approximation of the full dynamics, we develop an analytical solution that captures photon statistics for a moderate atom number, $N$, and a homogeneous atom-waveguide coupling, $β$. Finally, we show that capturing the onset of second-order coherence from a fully inverted state requires a fourth-order mean-field approximation, as lower-order treatments fail to account for the necessary four-body correlations. These results illustrate the complex behavior of a symmetry-lacking system, and the methods discussed here provide systematic analytical solutions to which semi-classical methods such as the cumulant expansion or the truncated Wigner approximation can be benchmarked.

quant-pharXiv:2603.04591•Mar 6, 2026•0 citations

Three-Body Thermalization in One Dimension & Realistic Effects on Subradiance and Superradinace in Many-Atom Systems

M. Eltohfa

This thesis investigates two largely independent topics in many-body and quantum optical physics. The first concerns the thermalization of classical one-dimensional (1D) gases through three-body collisions, while the second explores collective light–matter interactions in atomic arrays and waveguide quantum electrodynamics, with an emphasis on subradiance, superradiance, and computational methods for many-body dynamics. The first part studies thermalization in dilute classical 1D gases, where conventional twobody collisions cannot establish thermal equilibrium. Using Monte Carlo calculations of the three-body collision kernel together with the Boltzmann equation and molecular dynamics simulations, we characterize the thermalization dynamics for particles interacting through inverse power-law and Lennard–Jones potentials. We show that the Boltzmann and molecular dynamics approaches agree in the dilute limit and derive the thermalization rate for inverse power-law interactions.The second part investigates realistic effects in collective light–matter systems. We first study the influence of finite trapping potentials on subradiant states in atomic arrays coupled through free space or a one-dimensional waveguide. We show that atomic motion fundamentally limits subradiant lifetimes through wavefunction delocalization, recoil heating, and dipole-force-induced motion, leading to decoherence and reduced quantum memory fidelity. These results identify optimal trapping and array configurations for long-lived collective excitations.The final chapters develop theoretical methods for describing photon emission in chiral and symmetric waveguide QED systems. Using higher-order mean-field approximations, we model collective emission in experimentally relevant chiral waveguides, obtaining agreement with recent experiments and deriving analytical expressions for photon statistics. We demonstrate that fourth-order correlations are required to capture the emergence of second-order coherence from a fully inverted state. Finally, in the thermodynamic limit of large atom number and fixed optical depth, we show that a second-order mean-field theory becomes exact, yielding analytical solutions for photon emission statistics in both chiral and symmetric waveguides. We characterize the crossover between enhanced superradiant and subradiant emission, establish the suppression of emission fluctuations in the large-system limit, and clarify the role of finite-size effects in generating nontrivial photon correlations.

•Aug 4, 2026•0 citations

Higher-order mean-field theory of chiral waveguide QED

Kasper Kusmierek, Sahand Mahmoodian, Martin Cordier +6 more

Waveguide QED with cold atoms provides a potent platform for the study of non-equilibrium, many-body, and open-system quantum dynamics. Even with weak coupling and strong photon loss, the collective enhancement of light-atom interactions leads to strong correlations of photons arising in transmission, as shown in recent experiments. Here we apply an improved mean-field theory based on higher-order cumulant expansions to describe the experimentally relevant, but theoretically elusive, regime of weak coupling and strong driving of large ensembles. We determine the transmitted power, squeezing spectra and the degree of second-order coherence, and systematically check the convergence of the results by comparing expansions that truncate cumulants of few-particle correlations at increasing order. This reveals the important role of many-body and long-range correlations between atoms in steady state. Our approach allows to quantify the trade-off between anti-bunching and output power in previously inaccessible parameter regimes. Calculated squeezing spectra show good agreement with measured data, as we present here.

SciPost Physics Core•Jun 7, 2023•21 citations

Higher-order mean-field theory of chiral waveguide QED

Kasper Kusmierek, Sahand Mahmoodian, Martin Cordier +6 more

Waveguide QED with cold atoms provides a potent platform for the study of non-equilibrium, many-body, and open-system quantum dynamics. Even with weak coupling and strong photon loss, the collective enhancement of light-atom interactions leads to strong correlations of photons arising in transmission, as shown in recent experiments. Here we apply an improved mean-field theory based on higher-order cumulant expansions to describe the experimentally relevant, but theoretically elusive, regime of weak coupling and strong driving of large ensembles. We determine the transmitted power, squeezing spectra and the degree of second-order coherence, and systematically check the convergence of the results by comparing expansions that truncate cumulants of few-particle correlations at increasing order. This reveals the important role of many-body and long-range correlations between atoms in steady state. Our approach allows to quantify the trade-off between anti-bunching and output power in previously inaccessible parameter regimes. Calculated squeezing spectra show good agreement with measured data, as we present here.

arXiv:2207.10439•Jul 21, 2022•1 citation

Waveguide quantum electrodynamics

Vanessa Paulisch

Waveguide quantum electrodynamics (waveguide QED) describes the interaction between an electromagnetic field confined to a one-dimensional waveguide with atom-like quantum emitters close by. The characteristics of these kinds of systems are the possibility for strong and even ultrastrong interactions between the photonic and atom-like systems, and practically infinite range interactions between the emitters. These properties are valuable for a wide range of quantum optical applications, like quantum communication, quantum networks and quantum metrology. In this thesis we focus on two challenges in quantum optics, namely the generation and scattering of multiphoton states. In the first part of this thesis we demonstrate how waveguide QED systems can be exploited for the generation of multiphoton states, in particular of single-mode Fock states and superpositions thereof as well as multi-mode photonic states with metrological applications. The basic setup for this goal is an ensemble of quantum emitters coupled to a waveguide. In the so-called atomic mirror configuration symmetric Dicke states (or a superposition thereof) decay superradiantly to the ground state and emit the desired multiphoton state, which can be efficiently collected at the ends of the waveguide. We propose various protocols for the preparation of these Dicke states in waveguide QED systems and characterize the emitted photonic state. It turns out that in the low excitation regime, that is, if the number of photons is much lower than the ensemble size, the photonic state is emitted into a single mode. This single-mode structure is fundamental to current proposals for applications in quantum metrology with optical interferometers. Outside the low excitation regime, a multi-mode photonic state is generated, for which the metrological capabilities were unknown. We were able to show that these states still lead to quantum-enhanced optical interferometry. In the second part of this thesis we demonstrate how the scattering of multiphoton states on a single quantum emitter coupled to the waveguide can be used for testing the limits of the light-matter interaction strength. In particular, we investigate systems in the so-called ultrastrong coupling regime, where the coupling strength between the photonic and atom-like system is of the order of the emitter's transition energy. In this regime, many methods and approximations used in quantum optics, especially the Rotating Wave Approximation, break down and one needs to develop new analytical and numerical methods to study these systems. One approach is the so-called polaron Transformation. We show how this transformation can be applied for predicting the scattering amplitude of few photons scattering on the emitter. The comparison of these results with numerical simulations using matrix product states shows a good agreement for moderate coupling strengths. Both parts together show that waveguide QED systems are promising candidates for the generation of multiphoton states as well as for the investigation of fundamental limits probed through the scattering of multiphoton states. The latter also finds application in the implementation of photon-photon nonlinearities induced by the interaction with the quantum emitters. Apart from these and many other theoretical predictions, waveguide QED systems are also undergoing rapid progress in experiments. Therefore, we expect these kinds of systems to bring forth several advances in the field of quantum optics.

•Jan 1, 2018•1 citation

Mutual Interaction Induced Multi-particle Physics in QED Systems – Cooperative Spontaneous Emission and Photonic Dimer Enhanced Two-photon Excitation

Zhou, Yao

In recent years, the study of quantum electrodynamics (QED) in light-matter interactions has discovered various interesting phenomenons that orient many applications. However, due to the ambient entanglement among photons and atoms, few-particle dynamics remains challenging to analyze precisely and limits the progress in several fields. In few-particle systems, different number of atoms interacting with the light field generates drastically different results, even when there is only a single photon involved in the system. The interference between individual atom’s spontaneous emission wavefunctions can cooperatively alter the effective atom-light coupling strength. Depending on the spatial distance between individual of atoms and the involved cavities in the interaction progresses, the collective spontaneous emission rate can alter drastically from superradiance, where the emission rate is enhanced to a high value proportional to the atom number, to subradiance, where the excited atom ensemble stays in a dark state with the light trapped forever. Superradiance provides a promising mechanism to create an ultra-strong light-matter coupling environment, which is an important ingredient for the design of ultra-fast optical devices, frequency comb generation and quantum mirrors. The dark state of subradiance, on the other hand, is essential for the quantum memory implementation. Also, nontrivial phenomenons also occur when multiple photons interacting with a single atom simultaneously. When a finite number of photons incidents on an atom, their scattering through an atom is highly nonlinear, and one special eigenstate component of such nonlinear process, namely photonic bound states, exhibits many interesting properties in nonlinear quantum optical systems. The photons in such state are strongly bunched with each other, as if a virtual attractive force is in effect. Also, the frequency of photons are anti-correlated so that their total frequency remains a constant value, no matter how arbitrary the frequency of any individual is. Thesefeatures benefit certain nonlinear quantum processes for quantum computing and quantum imaging. Specially for two-photon excitation imaging, the same-parity two-level fluorophore molecules suffers from extremely low excitation efficiencies due to the far off-resonant intermediate states. However, by replacing the current commonly used ultrashort laser pulse illuminations with two photon bound state photon pairs, namely photonic dimers, the efficiency can be enhanced to orders of magnitude higher. Such exceptionally high excitation efficiency can potentially bring the current in vivo deep brain imaging depth from millimeter level to several centimeters. To obtain a stable source of such photonic dimers, it is found that a laser structure with gain medium of two-photon emission materials is capable of generating the coherent state of photonic dimer and can serve as a promising light source for nonlinear quantum optical devices.

•Oct 11, 2021•0 citations
Waveguide quantum electrodynamics (WQED) offers a powerful framework for controlling light-matter interactions and realizing collective phenomena such as super- and subradiance. In general waveguide settings, the quantum dynamics spans the full Hilbert space, rendering exact theoretical treatments exponentially difficult and currently out of reach, and only a few models have exact, analytical solutions. Motivated by recent experiments, we treat the thermodynamic limit of the number of atoms, N→∞N \rightarrow \inftyN→∞, while the homogeneous atom-waveguide coupling β→0β\rightarrow 0β→0 keeping the optical depth 4Nβ4Nβ4Nβ fixed. In this limit, a second order mean field method is exact, giving analytical solutions for the statistics of the photons emitted in the waveguide both for chiral and symmetric configurations starting from full inversion. As N→∞N \rightarrow \inftyN→∞, the emission in freespace approaches that of an independent ensemble. However, until a special time, ≈1.59×\approx 1.59 \times≈1.59× the lifetime of a single-atom, we show an exponentially enhanced superradiance in the waveguide as the optical depth increases. After the special time, the emission into the waveguide exhibits subradiance. We also show that the initial shot-to-shot fluctuations in the rate of emission into the waveguide diminish in a chiral system and vanish in a symmetric system as NNN approaches ∞\infty∞. Additionally, the equal-time second-order correlation becomes trivial, showing that finite-size effects are essential to observe the emergence of second-order coherence. Finally, going beyond the thermodynamic limit requires higher order mean field methods. Our results illustrate finite- and infinite-body collective effects in symmetric and symmetry-lacking systems.
Waveguide Quantum Electrodynamics (WQED) offers a suitable stage for controlling the interaction of light with atoms, allowing for collective phenomena such as super- and subradiance. In a chiral waveguide setup, the quantum state evolves through all the Hilbert space, rendering an exact theoretical treatment exponentially hard and unobtained to date for more than ∼20\sim 20∼20 atoms. In this work, we use a computationally efficient higher order mean-field approximation to model the radiation dynamics in a chirally coupled array of atoms, showing good agreement with recent experimental results. Further, based on a perturbative approximation of the full dynamics, we develop an analytical solution that captures photon statistics for a moderate atom number, NNN, and a homogeneous atom-waveguide coupling, βββ. Finally, we show that capturing the onset of second-order coherence from a fully inverted state requires a fourth-order mean-field approximation, as lower-order treatments fail to account for the necessary four-body correlations. These results illustrate the complex behavior of a symmetry-lacking system, and the methods discussed here provide systematic analytical solutions to which semi-classical methods such as the cumulant expansion or the truncated Wigner approximation can be benchmarked.
This thesis investigates two largely independent topics in many-body and quantum optical physics. The first concerns the thermalization of classical one-dimensional (1D) gases through three-body collisions, while the second explores collective light–matter interactions in atomic arrays and waveguide quantum electrodynamics, with an emphasis on subradiance, superradiance, and computational methods for many-body dynamics. The first part studies thermalization in dilute classical 1D gases, where conventional twobody collisions cannot establish thermal equilibrium. Using Monte Carlo calculations of the three-body collision kernel together with the Boltzmann equation and molecular dynamics simulations, we characterize the thermalization dynamics for particles interacting through inverse power-law and Lennard–Jones potentials. We show that the Boltzmann and molecular dynamics approaches agree in the dilute limit and derive the thermalization rate for inverse power-law interactions.The second part investigates realistic effects in collective light–matter systems. We first study the influence of finite trapping potentials on subradiant states in atomic arrays coupled through free space or a one-dimensional waveguide. We show that atomic motion fundamentally limits subradiant lifetimes through wavefunction delocalization, recoil heating, and dipole-force-induced motion, leading to decoherence and reduced quantum memory fidelity. These results identify optimal trapping and array configurations for long-lived collective excitations.The final chapters develop theoretical methods for describing photon emission in chiral and symmetric waveguide QED systems. Using higher-order mean-field approximations, we model collective emission in experimentally relevant chiral waveguides, obtaining agreement with recent experiments and deriving analytical expressions for photon statistics. We demonstrate that fourth-order correlations are required to capture the emergence of second-order coherence from a fully inverted state. Finally, in the thermodynamic limit of large atom number and fixed optical depth, we show that a second-order mean-field theory becomes exact, yielding analytical solutions for photon emission statistics in both chiral and symmetric waveguides. We characterize the crossover between enhanced superradiant and subradiant emission, establish the suppression of emission fluctuations in the large-system limit, and clarify the role of finite-size effects in generating nontrivial photon correlations.
Waveguide QED with cold atoms provides a potent platform for the study of non-equilibrium, many-body, and open-system quantum dynamics. Even with weak coupling and strong photon loss, the collective enhancement of light-atom interactions leads to strong correlations of photons arising in transmission, as shown in recent experiments. Here we apply an improved mean-field theory based on higher-order cumulant expansions to describe the experimentally relevant, but theoretically elusive, regime of weak coupling and strong driving of large ensembles. We determine the transmitted power, squeezing spectra and the degree of second-order coherence, and systematically check the convergence of the results by comparing expansions that truncate cumulants of few-particle correlations at increasing order. This reveals the important role of many-body and long-range correlations between atoms in steady state. Our approach allows to quantify the trade-off between anti-bunching and output power in previously inaccessible parameter regimes. Calculated squeezing spectra show good agreement with measured data, as we present here.
Waveguide QED with cold atoms provides a potent platform for the study of non-equilibrium, many-body, and open-system quantum dynamics. Even with weak coupling and strong photon loss, the collective enhancement of light-atom interactions leads to strong correlations of photons arising in transmission, as shown in recent experiments. Here we apply an improved mean-field theory based on higher-order cumulant expansions to describe the experimentally relevant, but theoretically elusive, regime of weak coupling and strong driving of large ensembles. We determine the transmitted power, squeezing spectra and the degree of second-order coherence, and systematically check the convergence of the results by comparing expansions that truncate cumulants of few-particle correlations at increasing order. This reveals the important role of many-body and long-range correlations between atoms in steady state. Our approach allows to quantify the trade-off between anti-bunching and output power in previously inaccessible parameter regimes. Calculated squeezing spectra show good agreement with measured data, as we present here.
Waveguide quantum electrodynamics (waveguide QED) describes the interaction between an electromagnetic field confined to a one-dimensional waveguide with atom-like quantum emitters close by. The characteristics of these kinds of systems are the possibility for strong and even ultrastrong interactions between the photonic and atom-like systems, and practically infinite range interactions between the emitters. These properties are valuable for a wide range of quantum optical applications, like quantum communication, quantum networks and quantum metrology. In this thesis we focus on two challenges in quantum optics, namely the generation and scattering of multiphoton states. In the first part of this thesis we demonstrate how waveguide QED systems can be exploited for the generation of multiphoton states, in particular of single-mode Fock states and superpositions thereof as well as multi-mode photonic states with metrological applications. The basic setup for this goal is an ensemble of quantum emitters coupled to a waveguide. In the so-called atomic mirror configuration symmetric Dicke states (or a superposition thereof) decay superradiantly to the ground state and emit the desired multiphoton state, which can be efficiently collected at the ends of the waveguide. We propose various protocols for the preparation of these Dicke states in waveguide QED systems and characterize the emitted photonic state. It turns out that in the low excitation regime, that is, if the number of photons is much lower than the ensemble size, the photonic state is emitted into a single mode. This single-mode structure is fundamental to current proposals for applications in quantum metrology with optical interferometers. Outside the low excitation regime, a multi-mode photonic state is generated, for which the metrological capabilities were unknown. We were able to show that these states still lead to quantum-enhanced optical interferometry. In the second part of this thesis we demonstrate how the scattering of multiphoton states on a single quantum emitter coupled to the waveguide can be used for testing the limits of the light-matter interaction strength. In particular, we investigate systems in the so-called ultrastrong coupling regime, where the coupling strength between the photonic and atom-like system is of the order of the emitter's transition energy. In this regime, many methods and approximations used in quantum optics, especially the Rotating Wave Approximation, break down and one needs to develop new analytical and numerical methods to study these systems. One approach is the so-called polaron Transformation. We show how this transformation can be applied for predicting the scattering amplitude of few photons scattering on the emitter. The comparison of these results with numerical simulations using matrix product states shows a good agreement for moderate coupling strengths. Both parts together show that waveguide QED systems are promising candidates for the generation of multiphoton states as well as for the investigation of fundamental limits probed through the scattering of multiphoton states. The latter also finds application in the implementation of photon-photon nonlinearities induced by the interaction with the quantum emitters. Apart from these and many other theoretical predictions, waveguide QED systems are also undergoing rapid progress in experiments. Therefore, we expect these kinds of systems to bring forth several advances in the field of quantum optics.
In recent years, the study of quantum electrodynamics (QED) in light-matter interactions has discovered various interesting phenomenons that orient many applications. However, due to the ambient entanglement among photons and atoms, few-particle dynamics remains challenging to analyze precisely and limits the progress in several fields. In few-particle systems, different number of atoms interacting with the light field generates drastically different results, even when there is only a single photon involved in the system. The interference between individual atom’s spontaneous emission wavefunctions can cooperatively alter the effective atom-light coupling strength. Depending on the spatial distance between individual of atoms and the involved cavities in the interaction progresses, the collective spontaneous emission rate can alter drastically from superradiance, where the emission rate is enhanced to a high value proportional to the atom number, to subradiance, where the excited atom ensemble stays in a dark state with the light trapped forever. Superradiance provides a promising mechanism to create an ultra-strong light-matter coupling environment, which is an important ingredient for the design of ultra-fast optical devices, frequency comb generation and quantum mirrors. The dark state of subradiance, on the other hand, is essential for the quantum memory implementation. Also, nontrivial phenomenons also occur when multiple photons interacting with a single atom simultaneously. When a finite number of photons incidents on an atom, their scattering through an atom is highly nonlinear, and one special eigenstate component of such nonlinear process, namely photonic bound states, exhibits many interesting properties in nonlinear quantum optical systems. The photons in such state are strongly bunched with each other, as if a virtual attractive force is in effect. Also, the frequency of photons are anti-correlated so that their total frequency remains a constant value, no matter how arbitrary the frequency of any individual is. Thesefeatures benefit certain nonlinear quantum processes for quantum computing and quantum imaging. Specially for two-photon excitation imaging, the same-parity two-level fluorophore molecules suffers from extremely low excitation efficiencies due to the far off-resonant intermediate states. However, by replacing the current commonly used ultrashort laser pulse illuminations with two photon bound state photon pairs, namely photonic dimers, the efficiency can be enhanced to orders of magnitude higher. Such exceptionally high excitation efficiency can potentially bring the current in vivo deep brain imaging depth from millimeter level to several centimeters. To obtain a stable source of such photonic dimers, it is found that a laser structure with gain medium of two-photon emission materials is capable of generating the coherent state of photonic dimer and can serve as a promising light source for nonlinear quantum optical devices.