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arXiv:2601.22583 · Physical Review A

Multipartite entanglement measures based on the thermodynamic framework

Chen-Ming Bai, Yu Luo

quant-phSubmitted Jan 30, 2026• Announced Feb 2, 2026• 2 citations
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Abstract

In this work, we introduce a unified method to characterize and measure multipartite entanglement using the framework of thermodynamics. A family of the new entanglement measures is proposed: \textit{ergotropic-gap concentratable entanglement}. Furthermore, we establish that ergotropic-gap concentratable entanglement constitutes a well-defined entanglement measure within a specific parameter regime, satisfying key properties including continuity, majorization monotonicity and monogamy. We demonstrate the utility of this measure by showing it effectively distinguishes between multi-qubit Greenberger-Horne-Zeilinger states and W states. It also proves effective in detecting entanglement in specific classes of four-partite star quantum network states.

Journal reference
Physical Review A 112, 032424 (2025)
DOI
10.1103/rg65-sh1f
Comments
12 pages, 5 figures

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In this work, we introduce a unified method to characterize and measure multipartite entanglement using the framework of thermodynamics. A family of the new entanglement measures is proposed: \textit{ergotropic-gap concentratable entanglement}. Furthermore, we establish that ergotropic-gap concentratable entanglement constitutes a well-defined entanglement measure within a specific parameter regime, satisfying key properties including continuity, majorization monotonicity and monogamy. We demonstrate the utility of this measure by showing it effectively distinguishes between multi-qubit Greenberger-Horne-Zeilinger states and W states. It also proves effective in detecting entanglement in specific classes of four-partite star quantum network states.
Multipartite entanglement is regarded as a crucial physical resource in quantum network communication. However, due to the intrinsic complexity of quantum many-body systems, identifying a multipartite entanglement measure that is both efficiently computable and capable of accurately characterizing entanglement remains a challenging problem. To address these issues, we propose a family of two-parameter multipartite entanglement measures for mixed states, termed unified-entropy concentratable entanglements. Many well-known multipartite entanglement measures are recovered as special cases of this family of measures, such as the entanglement of formation and the concentratable entanglements introduced in [Phys. Rev. Lett. 127, 140501 (2021)]. We demonstrate that the unified-entropy concentratable entanglements constitutes a well-defined entanglement monotones, and establish several desirable properties it satisfies, such as subadditivity and continuity. We further investigate the ordering relations of unified-entropy concentratable entanglements and discuss how these quantities can be efficiently estimated on near-term quantum devices. As an application, we demonstrate that the unified-entropy concentratable entanglements can effectively distinguish between multi-qubit Greenberger-Horne-Zeilinger (GHZ) states and W states. The ordering relations of these entanglement measures are further validated using four-partite star quantum network states and four-qubit Dicke states. Moreover, we find that the unified-entropy concentratable entanglements exhibit greater sensitivity than the original concentratable entanglements in detecting certain four-partite star quantum network states.
ABSTRACT Multipartite entanglement is widely recognized as a fundamental resource for various quantum protocols, including those in quantum communication and quantum computing. However, a unified characterization of multipartite entanglement remains elusive. In this paper, we introduce ‐Concentratable Entanglements, a one‐parameter family of measures for multipartite entanglement. This framework generalizes the Concentratable Entanglements framework, recovering the original measure at the limit of . We prove that ‐Concentratable Entanglements is a valid entanglement measure satisfying local operations and classical communication monotonicity and continuity. While linear cluster states are known to exhibit higher concentratable entanglements than Greenberger‐Horne‐Zeilinger (GHZ) states at the specific point , To demonstrate the versatility of the ‐Concentratable Entanglements framework, we performed a comprehensive analysis of several paradigmatic multipartite states. Our comparison of ‐qubit GHZ and W states shows that the measure can distinguish them well, while the investigation of the 4‐partite star network illustrates the role of as a tunable parameter for probing structural subtleties. Most significantly, by analyzing the 4‐qubit linear cluster state () and the 4‐qubit GHZ states, we find that the hierarchical ordering is a robust feature in the parameter range .
We introduce a unified, computable measure of multipartite entanglement based on the spectral properties of an entanglement graph and its associated entanglement matrix. This framework quantifies quantum correlations among arbitrary subsystems and partitions of a composite system. We prove that the resulting spectral entanglement measure satisfies the fundamental requirements of entanglement measures. Furthermore, we derive a generic multipartite monogamy relation that extends residual entanglement beyond qubit systems and introduces spectral residual entanglement for arbitrary multipartite states.
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In this paper, we investigate the characterization of multipartite entanglement based on the unified (q,s)(q,s)(q,s)-entropy framework. For bipartite quantum states, we propose an entanglement measure Eq,sA∣B(ρ)E_{q,s}^{A|B}(ρ)Eq,sA∣B​(ρ) based on unified entropy and derive several analytical lower bounds for it using local orthonormal observables. We demonstrate with concrete examples that our lower bounds provide tighter estimates of quantum entanglement than several existing analytical bounds. For multipartite quantum states, based on unified entropy, we propose two measures Aq,sk(ρ)A^k_{q,s}(ρ)Aq,sk​(ρ) and Gq,sk(ρ)G^k_{q,s}(ρ)Gq,sk​(ρ) for quantifying kkk-nonseparability, and prove that these measures satisfy several desirable properties, such as faithfulness, local unitary invariance, and convexity. Moreover, we rigorously prove that when the parameters qqq and sss are in certain ranges, Aq,sk(ρ)A^k_{q,s}(ρ)Aq,sk​(ρ) and Gq,sk(ρ)G^k_{q,s}(ρ)Gq,sk​(ρ) also satisfy monotonicity and strong monotonicity. Furthermore, we establish the order relations of the measures Aq,sk(ρ)A^k_{q,s}(ρ)Aq,sk​(ρ) and Gq,sk(ρ)G^k_{q,s}(ρ)Gq,sk​(ρ) with respect to the parameters qqq and sss for fixed quantum states. In addition, for fixed qqq and sss, we also give their order relations for any two pure states.
The presence of quantum multipartite entanglement implies the existence of a thermodynamic quantity known as the ergotropic gap, which is defined as the difference between the maximal global and local extractable works from the system. We establish a direct relation between the geometric measure of entanglement and the ergotropic gaps. We show that all the marginal ergotropic gaps form a convex polytope for each class of quantum states that are equivalent under stochastic local operations and classical communication (SLOCC). We finally introduce the concept of multipartite ergotropic gap indicators and use them to present a refined criterion for classifying entanglement under SLOCC.