The maximum work extractable from a quantum system is achieved when the system is driven adiabatically. Frictional work then quantifies the difference in work output between adiabatic and non-adiabatic driving. Here we show that frictional work in a non-integrable spin chain is well-described by the diagonal entropy production associated with the build up of quantum coherence. The relationship is characterized by an effective temperature of the final adiabatic state and holds for slow to moderate driving protocols. For fast protocols, the frictional work is instead described by the quantum relative entropy between the final non-adiabatic and adiabatic states. We compare our results to those obtained from an integrable spin chain, in which case the adiabatic state is no longer described by a single temperature. In this case, the frictional work is described by a sum of terms for each independent subspace of the spin chain, which are at different effective temperatures. We show how integrability breaking can enhance work extraction in the adiabatic limit, but degrade work extraction in sufficiently non-adiabatic regimes.
The maximum work extractable from a quantum system is achieved when the system is driven adiabatically. Frictional work then quantifies the difference in work output between adiabatic and non-adiabatic driving. Here we show that frictional work in a non-integrable spin chain is well-described by the diagonal entropy production associated with the build up of quantum coherence. The relationship is characterized by an effective temperature of the final adiabatic state and holds for slow to moderate driving protocols. For fast protocols, the frictional work is instead described by the quantum relative entropy between the final non-adiabatic and adiabatic states. We compare our results to those obtained from an integrable spin chain, in which case the adiabatic state is no longer described by a single temperature. In this case, the frictional work is described by a sum of terms for each independent subspace of the spin chain, which are at different effective temperatures. We show how integrability breaking can enhance work extraction in the adiabatic limit, but degrade work extraction in sufficiently non-adiabatic regimes.
Although the idea of combining thermodynamics with quantum mechanics is more than a century old, quantum thermodynamics has seen significant development over the past few decades. Understanding work, heat, and entropy in the quantum regime has become increasingly important, particularly in light of advances in quantum technologies. This thesis investigates work processes in quantum spin chains. Quantum work processes can involve genuinely quantum features such as entanglement, coherence, and measurement back-action, which are absent in classical thermodynamic descriptions, making their characterization an area of ongoing interest in quantum thermodynamics. Focusing first on a single work step, we show that the frictional work due to finite-time driving for a non-integrable quantum spin chain can be well quantified by the diagonal entropy production. We further demonstrate that integrability breaking enhances work extraction in the adiabatic limit, while suppressing it in the non-adiabatic regime. We then study a quantum Otto cycle using the transverse-field Ising model as the working substance. We determine how different types of operation (engine, refrigerator, accelerator, heater) can emerge for different parameter regimes. We show that with infinitesimal work strokes, a thermal machine behaves either as an engine or an accelerator, and that these regimes can be characterized by equilibrium transverse magnetization. At low temperatures, these regimes are governed by low-energy excitations, while at high temperatures they follow from a free-energy expansion in inverse temperature. Frictional effects can emerge and suppress the engine performance during non-adiabatic driving. We show that these effects can be mitigated using an optimised drive protocol based on a geometric formulation of the path of the system through parameter space. Overall, this thesis provides a comprehensive understanding of how integrability, coherence, finite-time driving, and non-adiabatic transitions govern work extraction and thermal machine operation in quantum spin chains, and paves the way for understanding these processes in other quantum many-body systems.
Abstract Thermodynamics of quantum systems out-of-equilibrium is very important for the progress of quantum technologies, however, the effects of many-body interactions and their interplay with temperature, different drives and dynamical regimes is still largely unknown. Here we present a systematic study of these interplays in the case of driven Hubbard chains subject to a variety of interaction (from non-interacting to strongly correlated) and dynamical regimes (from sudden quench to quasi-adiabatic), and discuss which effects all these ingredients have on the work extraction and entropy production. As treatment of many-body interacting systems is highly challenging, we introduce a simple approximation which includes, for the average quantum work, many-body interactions only via the initial state, while the dynamics is fully non-interacting. We demonstrate that this simple approximation is surprisingly good for estimating both the average quantum work and the related entropy production, even when many-body correlations are significant.
Thermodynamics of quantum systems out-of-equilibrium is very important for the progress of quantum technologies, however, the effects of many body interactions and their interplay with temperature, different drives and dynamical regimes is still largely unknown.Here we present a systematic study of these interplays in the case of driven Hubbard chains subject to a variety of interaction (from non-interacting to strongly correlated) and dynamical regimes (from sudden quench to quasi-adiabatic), and discuss which effects all these ingredients have on the work extraction and entropy production.As treatment of many-body interacting systems is highly challenging, we introduce a simple approximation which includes, for the average quantum work, many-body interactions only via the initial state, while the dynamics is fully non-interacting.We demonstrate that this simple approximation is surprisingly good for estimating both the average quantum work and the related entropy production, even when many-body correlations are significant.
We show that ferromagnetic interactions can enhance the adiabatic performance of a quantum spin chain engine at low temperatures. The enhancement in work output is particular pronounced, increasing exponentially with interaction strength. The performance enhancement occurs in the paramagnetic phase and is qualitatively explained by considering just the ground and first excited state, in which case the system exhibits bipartite entanglement. As the temperature is increased, thermal occupation of higher energy states diminishes performance. We find that these thermal fluctuations are smallest for long-range interactions, resulting in the highest efficiency. Diabatic work extraction degrades performance due to quantum friction. We identify an approximate, experimentally realisable counterdiabatic drive that can mitigate friction for weak interactions.
We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed along ideal adiabatic and isothermal transformations. The comparison with the latter leads to the introduction of irreversible work, while that with the former leads to the introduction of inner friction. We show that these two quantities can be treated on an equal footing, as both can be linked with the heat exchanged in thermalization processes and both can be expressed as relative entropies. Furthermore, we show that a specific fluctuation relation for the entropy production associated with the inner friction exists, which allows the inner friction to be written in terms of its cumulants.
Recent years have seen an enormously revived interest in the study of thermodynamic notions in the quantum regime. This applies both to the study of notions of work extraction in thermal machines in the quantum regime, as well as to questions of equilibration and thermalisation of interacting quantum many-body systems as such. In this work we bring together these two lines of research by studying work extraction in a closed system that undergoes a sequence of quenches and equilibration steps concomitant with free evolutions. In this way, we incorporate an important insight from the study of the dynamics of quantum many body systems: the evolution of closed systems is expected to be well described, for relevant observables and most times, by a suitable equilibrium state. We will consider three kinds of equilibration, namely to (i) the time averaged state, (ii) the Gibbs ensemble and (iii) the generalised Gibbs ensemble, reflecting further constants of motion in integrable models. For each effective description, we investigate notions of entropy production, the validity of the minimal work principle and properties of optimal work extraction protocols. While we keep the discussion general, much room is dedicated to the discussion of paradigmatic non-interacting fermionic quantum many-body systems, for which we identify significant differences with respect to the role of the minimal work principle. Our work not only has implications for experiments with cold atoms, but also can be viewed as suggesting a mindset for quantum thermodynamics where the role of the external heat baths is instead played by the system itself, with its internal degrees of freedom bringing coarse-grained observables to equilibrium.