We unveil a fundamental temperature bias in transient quantum thermometry under Markovian dynamics. For qubit probes evolving in a thermal Markovian environment, we prove that transient precision beyond the steady-state benchmark can be achieved if and only if the probe is initially colder than the bath temperature to be estimated. Cold probes are therefore both necessary and sufficient for enhanced transient precision in the Markovian regime. We then investigate the fate of this bias in the presence of environmental memory. In particular, in a non-Markovian scenario generated by an auxiliary-mediated system-bath coupling, we find that the cold-probe requirement for enhanced transient precision persists, indicating that the temperature bias survives certain forms of memory effects. In contrast, for a non-Markovian collisional model with perfect swap interactions between bath ancillas, transient enhancement is entirely absent regardless of the probe's initial temperature. This indicates that strong non-Markovianity can lead to the complete disappearance of the enhancement effect, placing hot and cold probes on equal footing, with neither capable of achieving enhanced precision in this regime.
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16 pages, 3 figures. New results have been added, and typographical errors have been corrected
We unveil a fundamental temperature bias in transient quantum thermometry under Markovian dynamics. For qubit probes evolving in a thermal Markovian environment, we prove that transient precision beyond the steady-state benchmark can be achieved if and only if the probe is initially colder than the bath temperature to be estimated. Cold probes are therefore both necessary and sufficient for enhanced transient precision in the Markovian regime. We then investigate the fate of this bias in the presence of environmental memory. In particular, in a non-Markovian scenario generated by an auxiliary-mediated system-bath coupling, we find that the cold-probe requirement for enhanced transient precision persists, indicating that the temperature bias survives certain forms of memory effects. In contrast, for a non-Markovian collisional model with perfect swap interactions between bath ancillas, transient enhancement is entirely absent regardless of the probe's initial temperature. This indicates that strong non-Markovianity can lead to the complete disappearance of the enhancement effect, placing hot and cold probes on equal footing, with neither capable of achieving enhanced precision in this regime.
We investigate a nonequilibrium quantum thermometry protocol in which an ensemble of qubits, acting as temperature probes, is weakly coupled to a macroscopic thermal bath. The temperature of the bath, the parameter of interest, is encoded in the dissipator of a Markovian thermalization process. For some relevant initial states, we observe a peak in the Quantum Fisher Information (QFI) during the transient of the thermalization, indicating enhanced sensitivity in early-time dynamics. This effect becomes more pronounced at higher bath temperatures and is further enhanced when the initial reduced state of the qubits has a large ground-state population and/or it is highly coherent. We also focus on the role of initial quantum correlations in the thermometric performance, which emerge as a central feature of this work. We find strong numerical evidence that, given same single-qubit reduced states, the inclusion of quantum correlations among the qubits of the ensemble always yields an enhanced QFI. Moreover, even if none of the considered states outperform the (pure, separable) ground state, maximally entangled states display QFIs values remarkably close to the standard quantum limit when probing extremely hot thermal baths. Finally, although the Markovian dynamics does not permit superlinear scaling of the QFI with the number of probes, we identify the most effective initial states for designing high-precision quantum thermometers within this setting. We also provide concrete guidelines for experimental implementations.
Accurate temperature estimation in the quantum and cryogenic regimes remains a fundamental challenge. Here, we investigate nonequilibrium quantum thermometry using a single-qubit probe coupled to a bosonic bath through noncommuting interaction operators, which unify pure dephasing and dissipative dynamics within a spin-boson model. We show that the interference between these two coupling channels induces strong non-Markovian feedback between populations and coherences, leading to coherence trapping and enhanced thermal sensitivity. Remarkably, by tuning the coupling structure, the probe's temperature sensitivity exhibits a quadratic low-temperature scaling, even under weak coupling. Moreover, while coherence-based measurements are formally suboptimal, they become the most informative in the early nonequilibrium regime, where memory effects dominate. Our findings identify noncommutative system-bath couplings as a practical and tunable resource for achieving high-precision quantum thermometry in realistic open-system architectures.
We study the role of bath-induced correlations in temperature estimation of cold bosonic baths. Our protocol includes multiple probes, that are not interacting, nor are they initially correlated to each other. They interact with a bosonic sample and reach a nonthermal steady state, which is measured to estimate the temperature of the sample. It is well known that in the steady state such noninteracting probes may get correlated to each other and even entangled. Nonetheless, the impact of these correlations in metrology has not been deeply investigated yet. Here, we examine their role for thermometry of cold bosonic gases and show that, although being classical, bath-induced correlations can lead to significant enhancement of precision for thermometry. The improvement is especially important at low temperatures, where attaining high precision thermometry is particularly demanding. The proposed thermometry scheme does not require any precise dynamical control of the probes and tuning the parameters and is robust to noise in initial preparation, as it is built upon the steady state generated by the natural dissipative dynamics of the system. Therefore, our results put forward new possibilities in thermometry at low temperatures, of relevance, for instance, in cold gases and Bose-Einstein condensates.
The metrological limits of thermometry operated in nonequilibrium dynamical regimes are analyzed. We consider a finite-dimensional quantum system, employed as a quantum thermometer, in contact with a thermal bath inducing Markovian thermalization dynamics. The quantum thermometer is initialized in a generic quantum state, possibly including quantum coherence with respect to the Hamiltonian basis. We prove that the precision of the thermometer, quantified by the Quantum Fisher Information, is enhanced by the quantum coherence in its initial state. We analytically show this in the specific case of qubit thermometers for which the maximization of the Quantum Fisher Information occurs at a finite time during the transient thermalization dynamics. Such a finite-time precision enhancement can be better than the precision that is achieved asymptotically.
Quantum thermometry provides a key capability for nanoscale devices and quantum technologies, but most existing strategies rely on probes initialized near equilibrium. This equilibrium paradigm imposes intrinsic limitations: sensitivity is tied to long-time thermalization and often cannot be improved in fast, noisy, or nonstationary settings. In contrast, the \textit{Mpemba effect}, the counterintuitive phenomenon where hotter states relax faster than colder ones, has mostly been viewed as a thermodynamic anomaly. Here, we bridge this gap by proving that Mpemba-type inversions generically yield a finite-time enhancement of the quantum Fisher information (QFI) for temperature estimation, thereby converting an anomalous relaxation effect into a concrete metrological resource. Through explicit analyses of two-level and Λ-level probes coupled to bosonic baths, we show that nonequilibrium initializations can transiently outperform both equilibrium strategies and colder states, realizing a \emph{metrological Mpemba effect}. Our results establish anomalous relaxation as a general design principle for nonequilibrium quantum thermometry, enabling ultrafast and nanoscale sensing protocols that exploit, rather than avoid, transient dynamics.
We investigate quantum thermometry using a single-qubit probe embedded in a non-Markovian environment, employing the numerically exact hierarchical equations of motion (HEOM) to overcome the limitations of Born-Markov approximations. Through a systematic analysis of the dynamical and steady-state behavior of the quantum signal-to-noise ratio (QSNR) for temperature estimation, we identify several key findings that challenge the conventional expectation that strong coupling necessarily enhances thermometric performance. In nonequilibrium dynamical thermometry, weak system-environment coupling generally yields the optimal QSNR, whereas in the steady-state regime, strong coupling enhances sensitivity only in the ultralow-temperature limit, while weak coupling significantly improves precision at moderately low temperatures. To optimize performance across coupling regimes, we develop a hybrid computational framework that integrates HEOM with quantum-enhanced particle swarm optimization, enabling precise quantum dynamical control under varying coupling strengths. Our results reveal fundamental constraints and opportunities in quantum thermometry, offering practical strategies for the design of high-performance quantum thermometers operating in realistic open quantum systems.