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arXiv:2512.21502

Quantum Mean-Fields Spin Systems in a Random External Field

Chokri Manai

math-phmath.PRquant-phSubmitted Dec 25, 2025• Announced Dec 26, 2025• 0 citations
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Abstract

In this work, we consider general exchangeable quantum mean-field Hamiltonian such as the prominent quantum Curie-Weiss model under the influence of a random external field. Despite being arguably the simplest class of disordered quantum systems, the random external field breaks the symmetry of the mean-field Hamiltonian and hence standard quantum de Finetti type or semiclassical arguments are not directly applicable. We introduce a novel strategy in this context, which can be seen as non-commutative large deviation analysis, allowing us to characterize the limiting free energy in terms of a simple and explicit variational formula. The proposed method is general enough to be used for other classes of mean-field models such as multi species Hamiltonians.

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25 pages

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In this work, we consider general exchangeable quantum mean-field Hamiltonian such as the prominent quantum Curie-Weiss model under the influence of a random external field. Despite being arguably the simplest class of disordered quantum systems, the random external field breaks the symmetry of the mean-field Hamiltonian and hence standard quantum de Finetti type or semiclassical arguments are not directly applicable. We introduce a novel strategy in this context, which can be seen as non-commutative large deviation analysis, allowing us to characterize the limiting free energy in terms of a simple and explicit variational formula. The proposed method is general enough to be used for other classes of mean-field models such as multi species Hamiltonians.
These notes deal with the mean-field approximation for equilibrium states of N-body systems in classical and quantum statistical mechanics. A general strategy for the justification of effective models based on statistical independence assumptions is presented in details. The main tools are structure theorems {à} la de Finetti, describing the large N limits of admissible states for these systems. These rely on the symmetry under exchange of particles, due to their indiscernability. Emphasis is put on quantum aspects, in particular the mean-field approximation for the ground states of large bosonic systems, in relation with the Bose-Einstein condensation phenomenon. Topics covered in details include: the structure of reduced density matrices for large bosonic systems, Fock-space localization methods, derivation of effective energy functionals of Hartree or non-linear Schr{ö}dinger type, starting from the many-body Schr{ö}dinger Hamiltonian.
The statistical thermodynamics of the quantum spin- s XXZ Heisenberg model in the Weiss (mean-field) limit rests on the outer multiplicities of the irreducible representations in the Clebsch–Gordan decomposition of the n -fold spin- s tensor product, which determine the energy-level degeneracies and hence the partition function. Using known closed forms for these multiplicities in terms of generalized binomial coefficients of order 2 s + 1 , we write the exact finite-size partition function of the effective collective Hamiltonian and evaluate its thermodynamic limit by a large-deviation (Laplace) analysis validated against direct summations for systems of up to n = 10 4 spins. The free energy then follows from a two-parameter variational principle in the total spin and the magnetization per site. The ferromagnetic ordering is driven by the rotationally invariant part of the Hamiltonian, so that the Curie temperature T c = 1 3 J s ( s + 1 ) is independent of the anisotropy Δ, and the transition is of second order for every spin s , with classical mean-field exponents. The anisotropy reshapes the phase diagram: for Δ < 1 the field-driven first-order line of the isotropic ( Δ = 1 ) model opens into a dome of easy-plane ferromagnetic order, bounded by a continuous transition that restores the residual U(1) symmetry, and no first-order transitions or metastability occur throughout − 1 ≤ Δ < 1 ; the isotropic Curie-Weiss ferromagnet is recovered as Δ → 1. In two appendices we detail the asymptotics of the outer multiplicities down to the Gaussian-fluctuation prefactor and discuss the q -number and Jacobi-theta structures underlying the model, including the partial-theta-type structure that obstructs a standard theta-function reduction of the residual total-spin sum.
In many statistical models (but not all) one can introduce a local order parameter associated with a finite, discrete or continuous group of symmetries. The higher the temperature, the more important the fluctuations. One expects therefore in general to find pure phases at low temperature, with a reduced symmetry group, as a consequence of a nonvanishing expectation value of some order parameter. This situation is referred to as spontaneous symmetry breaking. A typical example is the classical Heisenberg model describing short-range interactions of an n -vector field ϕ, with an orthogonal O(n) symmetry group. For n = 1, 2, 3, this can account for a Curie transition from a ferromagnetic to a paramagnetic phase. In particle physics the σ-model of Gell-Mann and Levy involves a spontaneous symmetry breaking of chiral invariance, typical of massless spinor fields, accompanied by soft excitation modes, the so-called Goldstone modes, associated to a π-meson triplet and leading to a nonvanishing dynamical fermion mass. In a first and rather crude approximation, one can analyse the action itself or an effective one incorporating some fluctuation effects, and look for extrema as a function of field configurations, generally translationally invariant. The remaining fluctuations are then treated perturbatively. This mean field method is common to a great variety of domains, ranging from the Clausius–Mossotti formula for a polarizable medium, the Weiss molecular field in the theory of magnetism, Landau's effective action in various statistical contexts, the effective medium approximation in disordered systems, the Hartree–Fock method in atomic or many-body physics, to the semiclassical approximation in the study of quantum systems.
We consider the free energy of a class of spin glass models with $ p$-spin interactions in a transverse magnetic field. As $ p \to \infty $, the infinite system-size free energy is proven to converge to that of the quantum random energy model. This is accomplished by combining existing analytical techniques addressing the non-commutative properties of such quantum glasses, with the description of the typical geometry of extreme negative deviations of the classical $ p $-spin glass. We also review properties of the corresponding classical free energy and conjectures addressing $ 1/p $-corrections in the quantum case.
Given an arbitrary finite dimensional Hamiltonian H 0 , we consider the model H = H 0 +Δ H , where Δ H is a generic fully connected interaction. By using the strong law of large numbers, we easily prove that, for all such models, a generalized Curie-Weiss mean-field equation holds. Unlike traditional mean-field models, the term H 0 gives rise to short-range correlations and, furthermore, when H 0 has negative couplings, first-order phase transitions and inverse transition phenomena may take place even when only two-body interactions are present. The dependence from a non-uniform external field and finite-size effects are also explicitly calculated. Partially, these results were derived long ago by using min-max principles but remained almost unknown.
We investigate the effect of a unidirectional quenched random field on the anisotropic quantum spin-1/2 XYXYXY model, which magnetizes spontaneously in the absence of the random field. We adopt a mean-field approach for this analysis. In general, the models considered have Ising symmetry, and as such they exhibit ferromagnetic order in two and three dimensions in the presence of not too large disorder. Even in the special case when the model without disorder has U(1)\text{U}(1)U(1) symmetry, a small U(1)\text{U}(1)U(1)-symmetry-breaking random field induces ferromagnetic long-range order in two dimensions. The mean-field approach, consequently, provides a rather good qualitative and even quantitative description when applied not too close to the criticality. We show that spontaneous magnetization persists even in the presence of the random field, but the magnitude of magnetization gets suppressed due to disorder, and the system magnetizes in the directions parallel and transverse to the random field. Our results are obtained via analytical calculations within a perturbative framework and by numerical simulations. Interestingly, we show that it is possible to enhance a component of magnetization in the presence of the disorder field provided that we apply an additional constant field in the XYXYXY plane. Moreover, we derive generalized expressions for the critical temperature and the scalings of the magnetization near the critical point for the XYXYXY spin system with arbitrary fixed quantum spin angular momentum.