In trapped Bose-Einstein condensates (BECs), \emph{condensate growth} refers to the process in which an increasing number of quasi-particles are immediately transferred from the non-condensate state (the thermal cloud) into the condensate state following the initial formation of the BEC. Despite its physical significance, this phenomenon has not yet been studied rigorously from a mathematical standpoint. In this work, we investigate a kinetic equation whose collision operator includes three types of wave interactions: one corresponding to a 3-wave process, and two classified as 4-wave processes. This wave kinetic equation models the evolution of the density function of the thermal cloud. We establish the immediate formation of condensation in solutions to this equation, thus providing a rigorous demonstration of the condensate growth phenomenon.
In trapped Bose-Einstein condensates (BECs), \emph{condensate growth} refers to the process in which an increasing number of quasi-particles are immediately transferred from the non-condensate state (the thermal cloud) into the condensate state following the initial formation of the BEC. Despite its physical significance, this phenomenon has not yet been studied rigorously from a mathematical standpoint. In this work, we investigate a kinetic equation whose collision operator includes three types of wave interactions: one corresponding to a 3-wave process, and two classified as 4-wave processes. This wave kinetic equation models the evolution of the density function of the thermal cloud. We establish the immediate formation of condensation in solutions to this equation, thus providing a rigorous demonstration of the condensate growth phenomenon.
The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
A detailed analysis of the growth of a Bose-Einstein condensate is given, based on quantum kinetic theory, in which we take account of the evolution of the occupations of lower trap levels, and of the full Bose-Einstein formula for the occupations of higher trap levels, as well as the Bose-stimulated direct transfer of atoms to the condensate level introduced by Gardiner et al. [Phys. Rev. Lett. 79, 1793 (1997); 81, 5266 (1998)]. We find good agreement with experiment at higher temperatures, but at lower temperatures the experimentally observed growth rate is somewhat more rapid. We also confirm the picture of the ``kinetic'' region of evolution, introduced by Kagan, Svistunov, and Shlyapnikov (Zh. Eksp. Teor. Fiz. 101, 528 (1992) [Sov. Phys. JETP 75, 387 (1992)]), for the time up to the initiation of the condensate. The behavior after initiation essentially follows our original growth equation, but with a substantially increased rate coefficient. Our modeling of growth implicitly gives a model of the spatial shape of the density profile of the condensate-vapor system as the condensate grows, and thus provides an alternative to the present phenomenological fitting procedure, based on the sum of a zero-chemical potential vapor and a Thomas-Fermi-shaped condensate. Our method gives substantially different results for condensate numbers and temperatures obtained from phenomenological fits, but fits the published column density data very well.
When a gas of bosonic atoms is cooled sufficiently near to absolute zero, it undergoes a startling transition from a collection of randomly-behaved individual atoms to a phase in which thousands, even millions, of atoms act in collective unison. In this new phase, known as a Bose-Einstein condensate (BEC), the atoms all occupy the exact same quantum mechanical ground state and can be collectively described by a single phase-coherent wavefunction of macroscopic size. But how exactly does this harmonious behaviour arise within a collection of incoherent atoms as their temperature decreases? Does the condensate wavefunction grow from a single central nucleus, or does it emerge simultaneously throughout the system? And how does the situation differ when the gas is cooled suddenly, away from thermodynamic equilibrium? Can non-equilibrium behaviour be inherited by the condensate that forms? In this thesis we aim to answer these and other questions by studying the formation dynamics of Bose-Einstein condensates and the development of phase coherence. The research described herein makes use of several theoretical tools, which we lay out on the workbench in Chapter 2: Semi-classical Hartree-Fock theory provides a mean-field description of a condensate and thermal cloud at equilibrium; Quantum kinetic theory is used to calculate the dynamics of condensate growth into an equilibrium state, from a non-equilibrium thermal cloud; The stochastic projected Gross-Pitaevskii equation (SPGPE) employs a classical-field description to encapsulate the non-equilibrium dynamics of the condensate and low-energy region of the atom cloud, coupled to an equilibrium thermal cloud. This thesis is composed of four principal studies, each constituting a separate chapter.In Chapter 3 we study the formation of a Bose-Einstein condensate in a cigar-shaped 3D harmonic trap, induced by the controlled addition of an attractive ``dimple'' potential along the weak axis in a recent experiment [Garrett et al., Phys. Rev. A 83, 013630 (2011)]. In this manner condensation is induced without cooling due to a localized increase in the phase space density. We perform a quantitative analysis of the thermodynamic transformation in both the sudden and adiabatic regimes for a range of dimple widths and depths. We find good agreement with equilibrium calculations based on self-consistent semi-classical Hartree-Fock theory describing the condensate and thermal cloud. We observe there is an optimal dimple depth that results in a maximum in the condensate fraction. We also study the non-equilibrium dynamics of condensate formation in the sudden turn-on regime, finding good agreement for the observed time dependence of the condensate fraction with calculations based on quantum kinetic theory. In Chapter 4 we study the onset of phase coherence during the formation of a BEC following a sudden quench to below the transition temperature. Using the SPGPE, we simulate a recent experiment performed at ANU in which a sudden RF quench is applied to a dilute gas of metastable Helium atoms confined in an elongated 3D harmonic magnetic trap. At regularly-spaced intervals following the quench, broadband RF pulses are applied to homogeneously outcouple small (<5%) pulses of atoms, which expand and fall to a microchannel plate detector. The second-order correlation function at the detector, postulated to provide a measure of phase coherence of the in-situ cloud from which they were outcoupled, is measured versus time and compared with the condensate growth curve. A delay was observed in the relaxation of the second-order correlation function, relative to the peak in the number of condensate atoms. In our simulations we incorporate the effects of periodic outcoupling both the condensate and thermal cloud, and monitor the time-dependence of first- and second-order correlation functions in both position and momentum space. We observe long-range phase coherence in the final equilibrium state, though mild persistent phase fluctuations are present. We also observe the curious phenomenon of ``superbunching'' - an enhancement of density fluctuations - at specific values of the momentum, which we relate to anomalous correlations of fluctuations. Despite obtaining a good quantitative fit to the experimentally-measured condensate growth curve in our SPGPE simulations, we do not observe any evidence of the delay in coherence observed in the experiment, which remains unexplained. In Chapter 5 we use the SPGPE to study the crossover from a true BEC with long-range phase coherence to a quasicondensate dominated by phase fluctuations, for the case of a Bose gas in an highly-elongated 3D harmonic trap. We use parameters corresponding to an experiment in which a sudden quench resulted in the formation of a non-equilibrium condensate, the dynamics of which we study in the chapter that follows. Sweeping through a range of temperatures and chemical potentials within the crossover region, we reveal the behaviour of phase fluctuations through analysis of correlation functions. We compare the ideal-gas approximation for the transition temperature with the more accurate value obtained via the Binder cumulant. By comparing the phase coherence length with the spatial extent across which density fluctuations are suppressed, we identify the BEC/quasicondensate crossover point. We compare directly with predictions of mean-field theory [Petrov et al., Phys. Rev. Lett. 87, 050404 (2001)] and find that phase fluctuations persist to lower temperatures in our SPGPE simulations. We calculate anomalous correlations of the fluctuation field and show that the resulting correction to the mean-field condensate self-interaction energy is significant within the quasicondensate regime. In Chapter 6 we study the formation of a BEC into a non-equilibrium state by simulating an experiment in which a dilute gas of Rubidium-87 atoms in a highly-elongated 3D harmonic magnetic trap is rapidly quenched to below the transition temperature. Following the quench, a condensate is observed to form with an excessively elongated shape, and subsequently undergo damped quadrupole shape oscillations [Shvarchuck et al., Phys. Rev. Lett. 89, 270404 (2002)]. We simulate this experiment by modifying the SPGPE to incorporate a hydrodynamic thermal cloud, parametrized by axially and temporally-dependent temperature and chemical potential. Comparison against simulations without this axial dependence suggests the hydrodynamic behaviour of the thermal cloud plays a crucial role in the formation of a non-equilibrium condensate. Analyses of the first-order correlation function and the condensate wavefunction reveal the spontaneous formation of quantum vortices, as well as strong phase fluctuations at equilibrium indicating quasicondensate behaviour.
The kinetics of the formation of coherent correlation properties associated with Bose condensation is studied in detail. The evolution of a nonequilibrium state with no “condensate-seed” is related to a hierarchy of relaxation times. At the first stage, a particle flux in energy space toward low energies sets in. The evolution in this case is described by a nonlinear Boltzmann equation, with a characteristic time given by interparticle collisions. When the particles which will later form the condensate have a kinetic energy which is less than the potential energy, a quasicondensate starts to form. In this stage, fluctuations of the density (but not of the phase) are suppressed and short-range coherent correlation properties are governed by the equation of motion for a quasiclassical complex field. The next stage is connected with the formation of the long-range order. The time for forming topological order and therefore genuine superfluidity proves to be dependent on the system size. The off-diagonal long-range order, arising after the attenuation of long-wave phase fluctuations, has a size-dependent relaxation time as well. Introduction The problem of Bose–Einstein Condensation (BEC) kinetics, being interesting in itself, has acquired a special significance in connection with experimental efforts to observe this condensation in a number of systems with particles with a finite lifetime. Such systems include spin-polarized atomic hydrogen [1], excitons [2] and biexcitons [3] in semiconductors and, more recently, laser-cooled atomic systems [4].
In this chapter,∗ we will analyze strongly nonequilibrium kinetics of Bose-Einstein condensate (BEC) formation in a weakly interacting Bose gas (WIBG). The process takes place as a result of self-evolution when occupation numbers in the initial state are large enough to ensure finite condensate density upon thermalization. In WIBG, the scenario of BEC formation involves several stages taking place at different wavenumber intervals. The key stages of the ordering process are of classicalfield character and are described by the Gross-Pitaevskii equation (GPE), with turbulent initial condition.
In a major extension of our previous model [Phys. Rev. Lett. 79, 1793 (1997)] of condensate growth, we take account of the evolution of the occupations of lower trap levels, and of the full Bose-Einstein formula for the occupations of higher trap levels. We find good agreement with experiment, especially at higher temperatures. We also confirm the picture of the ``kinetic'' region of evolution, introduced by Kagan et al., for the time up to the initiation of the condensate. The behavior after initiation essentially follows our original growth equation, but with a substantially increased rate coefficient W+.