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arXiv:2512.11522 · Physical Review A

Equilibration and the Eigenstate Thermalization Hypothesis as Limits to Observing Macroscopic Quantum Superpositions

Gabriel Dias Carvalho, Pedro S. Correia, Thiago R. de Oliveira

quant-phSubmitted Dec 12, 2025• Announced Dec 15, 2025• 0 citations
v1 · Dec 12, 2025v2 · Jun 5, 2026
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Abstract

Macroscopic quantum superpositions are widely believed to be unobservable because large systems cannot be perfectly isolated from their environments. Here, we show that even under perfect isolation, intrinsic unitary dynamics with the eigenstate thermalization hypothesis suppress the observable signatures of macroscopic coherence. Using the GHZ state as a representative example, we demonstrate that while fully correlated measurements can initially distinguish a macroscopic superposition from its corresponding classical mixture, generic many-body evolution renders them operationally indistinguishable for most times during the evolution. By analyzing both distinguishability measures and established quantifiers of macroscopic quantumness, we find that equilibration not only hides coherence from accessible observables but also suppresses macroscopic superpositions themselves. These results identify unitary thermalization, independent of environmental decoherence, as a fundamental mechanism that limits the emergence of macroscopic quantum effects.

DOI
10.1103/qlz3-4tfx

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Macroscopic quantum superpositions are widely believed to be unobservable because large systems cannot be perfectly isolated from their environments. Here, we show that even under perfect isolation, intrinsic unitary dynamics with the eigenstate thermalization hypothesis suppress the observable signatures of macroscopic coherence. Using the GHZ state as a representative example, we demonstrate that while fully correlated measurements can initially distinguish a macroscopic superposition from its corresponding classical mixture, generic many-body evolution renders them operationally indistinguishable for most times during the evolution. By analyzing both distinguishability measures and established quantifiers of macroscopic quantumness, we find that equilibration not only hides coherence from accessible observables but also suppresses macroscopic superpositions themselves. These results identify unitary thermalization, independent of environmental decoherence, as a fundamental mechanism that limits the emergence of macroscopic quantum effects.
Schrödinger's illustration of an imaginary cat in a box, neither alive nor dead, leads to a question of whether and how long a macroscopic quantum superposition can exist in various situations. It is well known that a macroscopic superposition is destroyed very quickly by environmental effects called decoherence. On the contrary, it is often believed that a macroscopic superposition continues to "survive" if it is ideally isolated from its environment. In this paper, using a well-established measure of macroscopic superpositions and the eigenstate thermalization hypothesis, we show that macroscopic superpositions even in ideally closed systems are destroyed by thermalization processes. We further investigate specific examples of a disordered Heisenberg spin chain varied between the thermalization phase and the many-body localized (MBL) phase. This leads to consistent results; initial macroscopic superpositions disappear under thermalization while they may be preserved in the MBL phase in which thermalization does not occur.
The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition
Schr\odinger's illustration of an imaginary cat in a box, neither alive nor dead, leads to a question of whether and how long a macroscopic quantum superposition can exist in various situations. It is well known that a macroscopic superposition is destroyed very quickly by environmental effects called decoherence. On the contrary, it is often believed that a macroscopic superposition continues to survive if it is ideally isolated from its environment. In this paper, using a well-established measure of macroscopic superpositions and the eigenstate thermalization hypothesis, we show that macroscopic superpositions even in ideally closed systems are destroyed by thermalization processes. We further investigate specific examples of a disordered Heisenberg spin chain varied between the thermalization phase and the many-body localization (MBL) phase. Consistent results are obtained that initial macroscopic superpositions that undergo thermalization disappear while they are preserved in the MBL phase in which thermalization does not occur.
The eigenstate thermalization hypothesis explains the emergence of the thermodynamic equilibrium in isolated quantum many-body systems by assuming a particular structure of the observable's matrix elements in the energy eigenbasis. Schematically, it postulates that off-diagonal matrix elements are random numbers and the observables can be described by random matrix theory (RMT). To what extent a RMT description applies, more precisely at which energy scale matrix elements of physical operators become truly uncorrelated, is, however, not fully understood. We study this issue by introducing a novel numerical approach to probe correlations between matrix elements for Hilbert-space dimensions beyond those accessible by exact diagonalization. Our analysis is based on the evaluation of higher moments of operator submatrices, defined within energy windows of varying width. Considering nonintegrable quantum spin chains, we observe that matrix elements remain correlated even for narrow energy windows corresponding to timescales of the order of thermalization time of the respective observables. We also demonstrate that such residual correlations between matrix elements are reflected in the dynamics of out-of-time-ordered correlation functions.
The eigenstate thermalization hypothesis (ETH), which asserts that every eigenstate of a many-body quantum system is indistinguishable from a thermal ensemble, plays a pivotal role in understanding thermalization of isolated quantum systems. Yet, no evidence has been obtained as to whether the ETH holds for all few-body operators in a chaotic system; such few-body operators include key quantities in statistical mechanics, such as the total magnetization, the momentum distributions, and their low-order thermal and quantum fluctuations. Here, we formulate a conjecture that for a generic nonintegrable system the ETH holds simultaneously for all mmm-body operators with m<α∗Nm < α_{\ast} Nm<α∗​N in the thermodynamic limit for some nonzero constant α∗>0α_{\ast} > 0α∗​>0. We first show the existence of such nontrivial constants for idealized (pseudo) random-matrix descriptions of many-body eigenstates. We then verify the conjecture for generic spin, Bose, and Fermi systems with local and few-body interactions by large-scale numerical calculations. Our results imply that generic systems satisfy the ETH simultaneously for all few-body operators, including their thermal and quantum fluctuations.
Can one certify the preparation of a coherent, many-body quantum state by measurements with bounded accuracy in the presence of noise and decoherence? Here, we introduce a criterion to assess the fragility of large-scale quantum states which is based on the distinguishability of orthogonal states after the action of very small amounts of noise. States which do not pass this criterion are called asymptotically incertifiable. We show that, if a coherent quantum state is asymptotically incertifiable, there exists an incoherent mixture (with entropy at least log 2) which is experimentally indistinguishable from the initial state. The Greenberger-Horne-Zeilinger states are examples of such asymptotically incertifiable states. More generally, we prove that any so-called macroscopic superposition state is asymptotically incertifiable. We also provide examples of quantum states that are experimentally indistinguishable from highly incoherent mixtures, i.e., with an almost-linear entropy in the number of qubits. Finally we show that all unique ground states of local gapped Hamiltonians (in any dimension) are certifiable.