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arXiv:2512.02775

Intrinsic Second-Order Topological Superconductors with Tunable Majorana Zero Modes

Xiao-Jiao Wang, Yijie Mo, Zhi Wang, Zhigang Wu, Zhongbo Yan

cond-mat.supr-concond-mat.mes-hallcond-mat.mtrl-scicond-mat.quant-gasquant-phSubmitted Dec 2, 2025• Announced Dec 3, 2025
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Abstract

Dirac semimetals, with their protected Dirac points, present an ideal platform for realizing intrinsic topological superconductivity. In this work, we investigate superconductivity in a two-dimensional, square-lattice nonsymmorphic Dirac semimetal. In the normal state near half-filling, the Fermi surface consists of two distinct pockets, each enclosing a Dirac point at a time-reversal invariant momentum ($\textbf{X}=(π,0)$ and $\textbf{Y}=(0,π)$). Considering an on-site repulsive and nearest-neighbor attractive interaction, we use self-consistent mean-field theory to determine the ground-state pairing symmetry. We find that an even-parity, spin-singlet $d_{x^{2}-y^{2}}$-wave pairing is favored as it gives rise to a fully gapped superconducting state. Since the pairing amplitude has opposite signs on the two Dirac Fermi pockets, the superconducting state is identified as a second-order topological superconductor. The hallmark of this topological phase is the emergence of Majorana zero modes at the system's boundaries. Notably, the positions of these Majorana modes are highly controllable and can be manipulated simply by tailoring the boundary sublattice terminations. Our results highlight the promise of nonsymmorphic Dirac semimetals for realizing and manipulating Majorana modes.

Comments
9+7 pages, 8 figures

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A time-reversal invariant Kitaev-type model is introduced in which spins (Dirac matrices) on the square lattice interact via anisotropic nearest-neighbor and next-nearest-neighbor exchange interactions. The model is exactly solved by mapping it onto a tight-binding model of free Majorana fermions coupled with static Z2{\mathbb{Z}}_{2}Z2​ gauge fields. The Majorana fermion model can be viewed as a model of time-reversal-invariant superconductor and is classified as a member of symmetry class DIII in the Altland-Zirnbauer classification. The ground-state phase diagram has two topologically distinct gapped phases which are distinguished by a Z2{\mathbb{Z}}_{2}Z2​ topological invariant. The topologically nontrivial phase supports both a Kramers' pair of gapless Majorana edge modes at the boundary and a Kramers' pair of zero-energy Majorana states bound to a 0-flux vortex in the $\ensuremath{\pi}$-flux background. Power-law decaying correlation functions of spins along the edge are obtained by taking the gapless Majorana edge modes into account. The model is also defined on the one-dimension ladder, in which case again the ground-state phase diagram has Z2{\mathbb{Z}}_{2}Z2​ trivial and nontrivial phases.
Proximity-induced superconductivity in low-dimensional systems offers a powerful pathway to engineer topological superconducting phases in, otherwise, non-superconducting systems. These exotic phases are of fundamental and technological interest due to the presence of robust zero-energy modes, the Majorana bound states. In this work, we propose a theoretical framework to realize Majorana bound states from the edge states of a two-dimensional semi-Dirac system. This anisotropic system, under specific conditions, can host non-chiral edge states that propagate only along particular edges, effectively forming separated one-dimensional channels. We show that the interplay between Rashba spin-orbit coupling and a Zeeman field on this setup provides the right conditions to get an effective p-wave pairing between the edge states by proximity with a s-wave superconductor. In finite geometries, each edge can independently undergo a topological phase transition into a one-dimensional topological superconductor and give rise to four zero-energy modes localized at the strip corners. At low energies, the edge states subspace admits a description in terms of coupled Kitaev chains, providing a clear picture of the origin, robustness, and tunability of the corner Majorana modes. Our results establish semi-Dirac materials as a natural platform for realizing Majorana modes in two dimensions without relying on engineered nanostructures, vortices, or crystalline higher-order topology.
The ground state behavior of the spinless fermion chain with an interaction between fermions at neighboring sites is studied for free open boundaries. For the strong enough repulsion boundary gapless states (bound state of Majorana operators from opposite sites of the chain) can exist inside the gap for bulk excitations, i.e., in the topological insulator regime. We propose to use those Majorana zero modes as topological qubits, similar to the ones in one-dimensional topological superconductors. Possible physical realizations of the considered model are discussed.
We systematically study topological phases of insulators and superconductors (or superfluids) in three spatial dimensions. We find that there exist three-dimensional (3D) topologically nontrivial insulators or superconductors in five out of ten symmetry classes introduced in seminal work by Altland and Zirnbauer within the context of random matrix theory, more than a decade ago. One of these is the recently introduced Z2{\mathbb{Z}}_{2}Z2​ topological insulator in the symplectic (or spin-orbit) symmetry class. We show that there exist precisely four more topological insulators. For these systems, all of which are time-reversal invariant in three dimensions, the space of insulating ground states satisfying certain discrete symmetry properties is partitioned into topological sectors that are separated by quantum phase transitions. Three of the above five topologically nontrivial phases can be realized as time-reversal invariant superconductors. In these the different topological sectors are characterized by an integer winding number defined in momentum space. When such 3D topological insulators are terminated by a two-dimensional surface, they support a number (which may be an arbitrary nonvanishing even number for singlet pairing) of Dirac fermion (Majorana fermion when spin-rotation symmetry is completely broken) surface modes which remain gapless under arbitrary perturbations of the Hamiltonian that preserve the characteristic discrete symmetries, including disorder. In particular, these surface modes completely evade Anderson localization from random impurities. These topological phases can be thought of as three-dimensional analogs of well-known paired topological phases in two spatial dimensions such as the spinless chiral $({p}_{x}\ifmmode\pm\else\textpm\fi{}i{p}_{y})$-wave superconductor (or Moore-Read Pfaffian state). In the corresponding topologically nontrivial (analogous to ``weak pairing'') and topologically trivial (analogous to ``strong pairing'') 3D phases, the wave functions exhibit markedly distinct behavior. When an electromagnetic U(1) gauge field and fluctuations of the gap functions are included in the dynamics, the superconducting phases with nonvanishing winding number possess nontrivial topological ground-state degeneracies.
Abstract A 3D fermionic topological insulator has a gapless Dirac surface state protected by time-reversal symmetry and charge conservation symmetry. The surface state can be gapped by introducing ferromagnetism to break time-reversal symmetry, introducing superconductivity to break charge conservation, or entering a topological phase. In this paper, we construct a minimal gapped topological phase that preserves both time-reversal and charge conservation symmetries and supports Ising-type non-Abelian anyons. This phase can be understood heuristically as emerging from a surface s-wave superconducting state via the condensation of eight-vortex composites. The topological phase inherits vortices supporting Majorana zero modes from the surface superconducting state. However, since it is time-reversal invariant, the surface topological phase is a distinct phase from the Ising topological phase, which can be viewed as a quantum-disordered spin-polarized p x + ip y superconductor. We discuss the anyon model of this topological phase and the manner in which time-reversal symmetry is realized in it. We also study the interfaces between the topological state and other surface gapped phases.
The issue on the effect of interactions in topological states concerns not only interacting topological phases but also novel symmetry-breaking phases and phase transitions. Here we study the interaction effect on Majorana zero modes (MZMs) bound to a square vortex lattice in two-dimensional topological superconductors. Under the neutrality condition, where single-body hybridization between MZMs is prohibited by an emergent symmetry, a minimal square-lattice model for MZMs can be faithfully mapped to a quantum spin model, which has no sign problem in the world-line quantum Monte Carlo simulation. Guided by an insight from a further duality mapping, we demonstrate that the interaction induces a Majorana stripe state, a gapped state spontaneously breaking lattice translational and rotational symmetries, as opposed to the previously conjectured topological quantum criticality. Away from neutrality, a mean-field theory suggests a quantum critical point induced by hybridization.