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arXiv:2511.23217

Refinements of the Eigenstate Thermalization Hypothesis under Local Rotational Invariance via Free Probability

Elisa Vallini, Laura Foini, Silvia Pappalardi

cond-mat.stat-mechhep-thquant-phSubmitted Nov 28, 2025• Announced Dec 1, 2025• 1 citation• Revised Jul 1, 2026 (v2)
v1 · Nov 28, 2025v2 · Jul 1, 2026
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Abstract

The Eigenstate Thermalization Hypothesis (ETH) was developed as a framework for understanding how the principles of statistical mechanics emerge in the long-time limit of isolated quantum many-body systems. Since then, ETH has shifted the attention towards the study of matrix elements of physical observables in the energy eigenbasis. In this work, we revisit recent developments leading to the formulation of full ETH, a generalization of the original ETH ansatz that accounts for multi-point correlation functions. Using tools from free probability, we explore the implications of local rotational invariance, a property that emerges from the statistical invariance of observables under random basis transformations induced by small perturbations of the Hamiltonian. This approach allows us to make quantitative predictions and derive an analytical characterization of subleading corrections to matrix-element correlations, thereby refining the ETH ansatz. Moreover, our analysis links the statistical properties of matrix elements under random basis changes to the empirical averages over energy windows that are usually considered when dealing with a single instance of the ensemble. We validate our analytical predictions through comparison with numerical simulations in non-integrable Floquet systems.

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The Eigenstate Thermalization Hypothesis (ETH) was developed as a framework for understanding how the principles of statistical mechanics emerge in the long-time limit of isolated quantum many-body systems. Since then, ETH has shifted the attention towards the study of matrix elements of physical observables in the energy eigenbasis. In this work, we revisit recent developments leading to the formulation of full ETH, a generalization of the original ETH ansatz that accounts for multi-point correlation functions. Using tools from free probability, we explore the implications of local rotational invariance, a property that emerges from the statistical invariance of observables under random basis transformations induced by small perturbations of the Hamiltonian. This approach allows us to make quantitative predictions and derive an analytical characterization of subleading corrections to matrix-element correlations, thereby refining the ETH ansatz. Moreover, our analysis links the statistical properties of matrix elements under random basis changes to the empirical averages over energy windows that are usually considered when dealing with a single instance of the ensemble. We validate our analytical predictions through comparison with numerical simulations in non-integrable Floquet systems.
The eigenstate thermalization hypothesis (ETH) was developed as a framework for understanding how the principles of statistical mechanics emerge in the long-time limit of isolated quantum many-body systems. Since then, ETH has shifted the attention toward the study of matrix elements of physical observables in the energy eigenbasis. In this work, we revisit recent developments leading to the formulation of full ETH, a generalization of the original ETH ansatz that accounts for multi-point correlation functions. Using tools from free probability, we explore the implications of local rotational invariance, a property that emerges from the statistical invariance of observables under random basis transformations induced by small perturbations of the Hamiltonian. This approach allows us to make quantitative predictions and derive an analytical characterization of subleading corrections to matrix-element correlations, thereby refining the ETH ansatz. Moreover, our analysis links the statistical properties of matrix elements under random basis changes to the empirical averages over energy windows that are usually considered when dealing with a single instance of the ensemble. We validate our analytical predictions through comparison with numerical simulations in non-integrable Floquet systems.
This repository contains codes and data for "Refinements of the Eigenstate Thermalization Hypothesis under Local Rotational Invariance via Free Probability", Elisa Vallini, Laura Foini and Silvia Pappalardi Abstract: The Eigenstate Thermalization Hypothesis (ETH) was developed as a framework for understanding how the principles of statistical mechanics emerge in the long-time limit of isolated quantum many-body systems. Since then, ETH has shifted the attention toward the study of matrix elements of physical observables in the energy eigenbasis. In this work, we revisit recent developments leading to the formulation of full ETH, a generalization of the original ETH ansatz that accounts for multi-point correlation functions. Using tools from free probability, we explore the implications of local rotational invariance, a property that emerges from the statistical invariance of observables under random basis transformations induced by small perturbations of the Hamiltonian. This approach allows us to make quantitative predictions and derive an analytical characterization of subleading corrections to matrix-element correlations, thereby refining the ETH ansatz.Moreover, our analysis links the statistical properties of matrix elements under random basis changes to the empirical averages over energy windows that are usually considered when dealing with a single instance of the ensemble.We validate our analytical predictions through comparison with numerical simulations in non-integrable Floquet systems. RefinementsETH.zip contains: - ReadMe.txt: detailed instructions for usage.- Figures: 4 figures presented in the manuscript.- Data: datasets used to generate the figures.- Codes: Python scripts for generating the data and reproducing the figures.
Despite the unitary evolution of closed quantum systems, long-time expectation of local observables are well described by thermal ensembles, providing the foundation of quantum statistical mechanics. A promising route to understanding this quantum thermalization is the eigenstate thermalization hypothesis (ETH), which posits that individual energy eigenstates already appear locally thermal. Subsequent studies have extended this concept to the full ETH, which captures higher-order correlations among matrix elements through nontrivial relations. In this work, we perform a detailed exact-diagonalization study of finite-size corrections to these relations in the canonical ensemble. We distinguish two distinct sources of corrections: those arising from energy fluctuations, which decay polynomially with system size, and those originating from fluctuations within each energy window, which decay exponentially with system size. In particular, our analysis resolves the puzzle that, for certain observables, finite-size corrections exhibit anomalous growth with increasing system size even in chaotic systems. Our results provide a systematic and practical methodology for validating the full ETH in quantum many-body systems.
The eigenstate thermalization hypothesis (ETH) has been established as the general framework to understand quantum statistical mechanics. Only recently has the attention been paid to so-called full ETH, which accounts for higher-order correlations among matrix elements, and that can be rationalized theoretically using the language of free probability. In this work, we perform the first numerical investigation of the full ETH in physical many-body systems with local interactions by testing the decomposition of higher-order correlators into thermal free cumulants for local operators. We perform exact diagonalization on two classes of local nonintegrable (chaotic) quantum many-body systems: spin chain Hamiltonians and Floquet brickwork unitary circuits. We show that the dynamics of four-time correlation functions are encoded in fourth-order free cumulants, as predicted by ETH. Their dependence on frequency encodes the physical properties of local many-body systems and distinguishes them from structureless, rotationally invariant ensembles of random matrices.
The Eigenstate Thermalization Hypothesis (ETH) is a standard tool to understand the thermalization properties of an isolated quantum system. Its generalization to higher order correlations of matrix elements of local operators, dubbed the full ETH, relates the ETH free cumulants to the corresponding thermal free cumulants in the thermodynamic limit. In this work, we numerically test the full ETH predictions using exact diagonalization of two integrable spin models: the Ising and the XXZ Heisenberg models. The differences from the behavior predicted by full ETH in chaotic systems are highlighted and contrasted along the way. We further study the out-of-time-ordered correlator (OTOC) through its approximate decomposition into contributions involving the second- and fourth-order ETH free cumulants. We find that, although the fourth-order contribution governs the late-time behavior of the OTOC in these integrable models, its dynamics differs significantly from that found in nonintegrable systems.
The eigenstate thermalization hypothesis (ETH) provides a fundamental mechanism for emergent statistical mechanics in isolated chaotic quantum systems, asserting that individual energy eigenstates behave as pseudorandom vectors within an energy window. This enables a complete characterization of nontrivial correlations among matrix elements in the energy eigenbasis, as described by the full ETH ansatz. Nevertheless, this description breaks down in systems exhibiting quantum many-body scars, which host non-thermal eigenstates with extensive energy. In this Letter, we address this problem by formulating the \textit{scar full ETH}, which captures correlations among matrix elements involving scar states. The corresponding scaling forms and factorization properties are established using typicality arguments. Multi-time correlation functions for scar states are then organized in terms of both thermal and scar cumulants, providing a nontrivial reorganization of higher-order correlations. We numerically demonstrate the validity of this framework in the paradigmatic model of quantum scars, the PXP model. Our results pave the way for a systematic understanding of intriguing correlations in systems with quantum many-body scars.