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arXiv:2511.13038 · The Journal of Chemical Physics

A Fractional Calculus Framework for Open Quantum Dynamics: From Liouville to Lindblad to Memory Kernels

Bo Peng, Yu Zhang

quant-phSubmitted Nov 17, 2025• Announced Nov 18, 2025• 3 citations• Revised Dec 17, 2025 (v2)
v1 · Nov 17, 2025v2 · Dec 17, 2025
arXivHTMLPDF

Abstract

Open quantum systems exhibit dynamics ranging from unitary evolution to irreversible dissipation. While the Gorini--Kossakowski--Sudarshan--Lindblad (GKSL) equation uniquely characterizes Markovian CPTP evolution, many physical platforms display non-Markovian features such as algebraic relaxation and coherence backflow. Fractional calculus provides a natural way to model such long-memory behavior through power-law temporal kernels introduced by fractional time derivatives. Here we develop a unified framework that embeds fractional master equations within the broader hierarchy of open-system formalisms. The fractional equation forms a structured subclass of memory-kernel models, reduces to the Lindblad form at unit order, and, through Bochner--Phillips subordination, admits a CPTP representation as an average over Lindblad semigroups. Its resolvent structure further connects fractional dynamics to established non-Markovian approaches, including Nakajima--Zwanzig kernels and hierarchical equations of motion, providing a compact surrogate for long-memory effects. This formulation positions fractional calculus as a rigorous and practical language for quantum dynamics with intrinsic memory, supporting both analytical insight and efficient quantum simulation.

DOI
10.1063/5.0312309

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Open quantum systems exhibit dynamics ranging from unitary evolution to irreversible dissipation. While the Gorini--Kossakowski--Sudarshan--Lindblad (GKSL) equation uniquely characterizes Markovian CPTP evolution, many physical platforms display non-Markovian features such as algebraic relaxation and coherence backflow. Fractional calculus provides a natural way to model such long-memory behavior through power-law temporal kernels introduced by fractional time derivatives. Here we develop a unified framework that embeds fractional master equations within the broader hierarchy of open-system formalisms. The fractional equation forms a structured subclass of memory-kernel models, reduces to the Lindblad form at unit order, and, through Bochner--Phillips subordination, admits a CPTP representation as an average over Lindblad semigroups. Its resolvent structure further connects fractional dynamics to established non-Markovian approaches, including Nakajima--Zwanzig kernels and hierarchical equations of motion, providing a compact surrogate for long-memory effects. This formulation positions fractional calculus as a rigorous and practical language for quantum dynamics with intrinsic memory, supporting both analytical insight and efficient quantum simulation.
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In this paper, we propose a fractional time extension of the Quan tum Master Equation. We introduce a Caputo-type fractional derivative in time as an extension of the exponential decay of the Lindblad framework through the incorporation of fractional derivatives into the Lindblad framework. We show that the analytical and numerical results of our analytical and numerical models, demonstrate that fractional dynamics produces long-memory coherence decay naturally and provides an interpretable and flexible model of non-Markovianity.
This preprint presents a self-contained and mathematically explicit reconstruction of the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) master equation starting from exact microscopic unitary dynamics through the Nakajima-Zwanzig projection operator formalism. Beginning with the exact non-local generalized master equation, we systematically analyze the hierarchy of approximations required for the emergence of a Markovian quantum dynamical semigroup. The Born (weak-coupling), Markov (time-localization), and secular approximations are derived and interpreted as successive information-reduction steps, each associated with clearly identifiable mathematical assumptions and physical consequences. Particular attention is devoted to the role of secularization in transforming the Redfield generator into a completely positive GKSL structure. To provide a concrete worked example, the formalism is applied to a damped two-level system coupled to a bosonic thermal reservoir, where the Redfield and GKSL equations are derived explicitly and compared at the microscopic level. Beyond the derivation itself, the work develops a systematic map of validity limits and failure regimes. The breakdown of the Born, Markov, secular, factorization, and stationarity assumptions is analyzed in terms of environmental correlation times, spectral-density structure, non-Markovian memory effects, information backflow, and loss of semigroup behavior. The resulting framework clarifies the precise operational domain in which GKSL dynamics can be regarded as a physically reliable effective description and provides a rigorous foundation for applications involving entropy-production theorems, quantum thermodynamics, and open-system information theory.
This monograph delivers a rigorous, non-perturbative closed-form analytical solution to the generalized non-Markovian Lindblad-Nakajima-Zwanzig master equation governing open quantum-classical systems coupled to arbitrary non-equilibrium thermal baths. By lifting the dissipative Liouville-von Neumann evolution onto an extended non-Hermitian supersymmetric (SUSY) fibre bundle equipped with a Cartan-Darboux connection, the environmental memory kernel is mapped onto the characteristic flow of an exceptional point foliation. We prove two foundational theorems: (1) Global Closed-Form Integrability, reducing non-local integro-differential dynamics to exact meromorphic Wilson holonomy loops with O(N^3) deterministic complexity, and (2) Strict Complete Positivity and Trace Preservation (CPTP) across all finite and asymptotic temporal regimes, definitively overcoming the unphysical negative-probability breakdown during informational backflow intervals. The formulation includes a production-certified, zero-heap embedded ISO C99 deterministic kernel executing in 1.85 microseconds on standard bare-metal controllers, establishing a new foundation for decoherence-resilient autonomous cybernetic computing.
These notes are a short introduction to the mathematical theory of open quantum systems. They are meant to serve as an entry point into a broad research area which has applications across the quantum sciences dealing with systems subjected to external noise. The guiding idea is to let the key structures of the theory emerge from a concrete model. By working through the dissipative Jaynes-Cummings model the reader will dis- cover explicitly how irreversible dynamics arises from a unitary system-reservoir evolution. The notions of the continuous mode limit, correlation functions, spectral density appear in a natural manner and lead to the evolution equation of the open system in form of a master equation. This sets the stage for the more general analysis of completely positive, trace preserving (CPTP) maps and the study of quantum dynamical semigroups. We motivate and prove the Kraus representation theorem, the dilation theorem and the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) theorem. Working through the exercises (for which full solutions are supplied) will reinforce the ideas introduced in the main text.