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arXiv:2511.09369

Thermodynamic uncertainty relations for relativistic quantum thermal machines

Dimitris Moustos, Obinna Abah

quant-phcond-mat.stat-mechgr-qcSubmitted Nov 12, 2025• Announced Nov 13, 2025• Revised Mar 12, 2026 (v2)
v1 · Nov 12, 2025v2 · Mar 12, 2026
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Abstract

We investigate a two-qubit SWAP thermal machine -- a streamlined analogue of the four-stroke Otto cycle -- whose working medium comprises inertially moving Unruh-DeWitt qubit detectors, each coupled to a thermal quantum field bath prepared at a different temperature. In the presence of relative motion between the working medium and the thermal baths, we derive thermodynamic uncertainty relations (TURs) that quantify the trade-off between performance, entropy production, and power fluctuations. Our analysis identifies regimes where relativistic motion leads to stronger violation of classical TURs, previously observed in static quantum setups. In addition, we establish generalized performance bounds for the thermal machine operating as either a heat engine or a refrigerator, and discuss how relativistic motion can enhance their performances beyond the standard Carnot limits defined by rest-frame temperatures.

Journal reference
Phys. Rev. D 113, 065005 (2026)
DOI
10.1103/25jj-1h67

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We investigate a two-qubit SWAP thermal machine -- a streamlined analogue of the four-stroke Otto cycle -- whose working medium comprises inertially moving Unruh-DeWitt qubit detectors, each coupled to a thermal quantum field bath prepared at a different temperature. In the presence of relative motion between the working medium and the thermal baths, we derive thermodynamic uncertainty relations (TURs) that quantify the trade-off between performance, entropy production, and power fluctuations. Our analysis identifies regimes where relativistic motion leads to stronger violation of classical TURs, previously observed in static quantum setups. In addition, we establish generalized performance bounds for the thermal machine operating as either a heat engine or a refrigerator, and discuss how relativistic motion can enhance their performances beyond the standard Carnot limits defined by rest-frame temperatures.
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Abstract In the quest for high-performance quantum thermal machines, looking for an optimal thermodynamic efficiency is only part of the issue. Indeed, at the level of quantum devices, fluctuations become extremely relevant and need to be taken into account. In this paper we study the thermodynamic uncertainty relations for a quantum thermal machine with a quantum harmonic oscillator as a working medium, connected to two thermal baths, one of which is dynamically coupled. We show that parameters can be found such that the machine operates both as a quantum engine or refrigerator, with both sizeable efficiency and small fluctuations.
The thermodynamic uncertainty relation (TUR) imposes a fundamental constraint between current fluctuations and entropy production, providing a refined formulation of the second law for micro- and nanoscale systems. Quantum violations of the classical TUR reveal genuinely quantum thermodynamic effects, which are essential for improving performance and enabling optimization in quantum technologies. In this work, we analyze the TUR in a class of paradigmatic quantum thermal-machine models whose operation is enabled by coherent coupling between two energy levels forming a virtual qubit. Steady-state coherences are confined to this virtual-qubit subspace, while in the absence of coherent coupling the system satisfies detailed balance with the thermal reservoirs and supports no steady-state heat currents. We show that the steady-state currents and entropy production can be fully reproduced by an effective classical Markov process, whereas current fluctuations acquire an additional purely quantum correction originating from coherence. As a result, the thermodynamic uncertainty naturally decomposes into a classical (diagonal) contribution and a coherent contribution. The latter becomes negative under resonant conditions and reaches its minimum at the coupling strength that maximizes steady-state coherence. We further identify the conditions for minimizing the thermodynamic uncertainty, and the criteria for surpassing the classical TUR bound in the vicinity of the reversible limit.
We study the work fluctuations in ergotropic heat engines, namely two-stroke quantum Otto engines where the work stroke is designed to extract the ergotropy (the maximum amount of work by a cyclic unitary evolution) from a couple of quantum systems at canonical equilibrium at two different temperatures, whereas the heat stroke thermalizes back the systems to their respective reservoirs. We provide an exhaustive study for the case of two qutrits whose energy levels are equally spaced at two different frequencies by deriving the complete work statistics. By varying the values of temperatures and frequencies, only three kinds of optimal unitary strokes are found: the swap operator U1, an idle swap U2 (where one of the qutrits is regarded as an effective qubit), and a non-trivial permutation of energy eigenstates U3, which indeed corresponds to the composition of the two previous unitaries, namely U3=U2U1. While U1 and U2 are Hermitian (and hence involutions), U3 is not. This point has an impact on the thermodynamic uncertainty relations (TURs), which bound the signal-to-noise ratio of the extracted work in terms of the entropy production. In fact, we show that all TURs derived from a strong detailed fluctuation theorem are violated by the transformation U3.
For a four-stroke asymmetrically driven quantum Otto engine with working medium modeled by a single qubit, we study the bounds on nonequilibrium fluctuations of work and heat. We find strict relations between the fluctuations of work and individual heat for hot and cold reservoirs in arbitrary operational regimes. Focusing on the engine regime, we show that the ratio of nonequilibrium fluctuations of output work to input heat from the hot reservoir is both upper and lower bounded. As a consequence, we establish a hierarchical relation between the relative fluctuations of work and heat for both cold and hot reservoirs and further make a connection with the thermodynamic uncertainty relations. We discuss the fate of these bounds also in the refrigerator regime. The reported bounds, for such asymmetrically driven engines, emerge once both the time-forward and the corresponding reverse cycles of the engine are considered on an equal footing. We also extend our study and report bounds for a parametrically driven harmonic oscillator Otto engine.