Recent advances in Kitaev materials have highlighted their potential to host Majorana fermions without or high-temperature of superconductivity. In this research, we propose $Li_2IrO_3$ as a promising High-temperature superconducting platform supporting Majorana edge modes due to its strong spin-orbit coupling, honeycomb lattice structure, and proximity to a quantum spin liquid (QSL) phase. A theoretical and numerical framework based on the Kitaev-Heisenberg Hamiltonian is developed to model spin interactions in $Li_2IrO_3$. Here, the existence of topological zero-energy states is demonstrated, and their signatures in the edge-localized spectral weight are identified. A device concept based on this material is also proposed with potential industrial applications in spintronics, magnetic field sensing, and topological quantum memory.
High-temperature superconducting Majorana fermions platforms in the layered Kitaev Materials: Case study of Li2IrO3
Recent advances in Kitaev materials have highlighted their potential to host Majorana fermions without or high-temperature of superconductivity. In this research, we propose Li2IrO3 as a promising High-temperature superconducting platform supporting Majorana edge modes due to its strong spin-orbit coupling, honeycomb lattice structure, and proximity to a quantum spin liquid (QSL) phase. A theoretical and numerical framework based on the Kitaev-Heisenberg Hamiltonian is developed to model spin interactions in Li2IrO3. Here, the existence of topological zero-energy states is demonstrated, and their signatures in the edge-localized spectral weight are identified. A device concept based on this material is also proposed with potential industrial applications in spintronics, magnetic field sensing, and topological quantum memory.
Proximity-induced superconductivity in low-dimensional systems offers a powerful pathway to engineer topological superconducting phases in, otherwise, non-superconducting systems. These exotic phases are of fundamental and technological interest due to the presence of robust zero-energy modes, the Majorana bound states. In this work, we propose a theoretical framework to realize Majorana bound states from the edge states of a two-dimensional semi-Dirac system. This anisotropic system, under specific conditions, can host non-chiral edge states that propagate only along particular edges, effectively forming separated one-dimensional channels. We show that the interplay between Rashba spin-orbit coupling and a Zeeman field on this setup provides the right conditions to get an effective p-wave pairing between the edge states by proximity with a s-wave superconductor. In finite geometries, each edge can independently undergo a topological phase transition into a one-dimensional topological superconductor and give rise to four zero-energy modes localized at the strip corners. At low energies, the edge states subspace admits a description in terms of coupled Kitaev chains, providing a clear picture of the origin, robustness, and tunability of the corner Majorana modes. Our results establish semi-Dirac materials as a natural platform for realizing Majorana modes in two dimensions without relying on engineered nanostructures, vortices, or crystalline higher-order topology.
A Majorana fermion is a fermionic particle that is its own antiparticle. Since the theoretical discovery in 1937, the exotic particle has long been searched in particle physics. In the last few decades, however, it has attracted renewed interest in condensed matter physics, where it can be realized as an elementary excitation (quasiparticle) in quantum states of matter. In this review, we discuss another platform for Majorana fermions, the quantum spin liquid, in which interacting magnetic moments remain disordered down to the lowest temperature under strong quantum fluctuations. They are characterized by topological entanglement and fractional excitations, whose possible application to topological quantum computation is recently discussed intensively. As a prime candidate for such exotic states, we here focus on the Kitaev magnets, a subgroup of the spin-orbit Mott insulators. After a brief overview of the Kitaev model and the fractionalization of spins in the exact ground state, we review recent explosive development in this rapidly growing field, with a focus on numerical solutions of the Kitaev model at finite temperatures and the comparison with experiments. The key concept is thermal fractionalization --- two types of fractional excitations manifest themselves at largely different temperatures. This leads to distinct thermodynamics and spin dynamics in a variety of experimentally measurable quantities. We discuss such peculiar behaviors as the signatures of fractional quasiparticles, in careful comparison with the available experimental data for the candidate materials of the Kitaev magnets. Our review gives an overview of the current status of the identification of Majorana fermions in the Kitaev magnets, which would serve as a basis for further experimental and theoretical studies toward the manipulation of the exotic particles for topological quantum computation.
Quantum spin liquids, a highly topologically entangled, dynamically correlated state where quantum fluctuations preclude any long-range ordering down to absolute zero. In the search for a topologically robust qubit, the scientific community has been in continuous hunt for real quantum spin liquid systems. Alexei Kitaev in his exactly solvable model for a spin-1/2 two-dimensional honeycomb lattice, presented a system that hosts a topologically protected state (Majorana zero-modes). Under an applied external field, the Kitaev spin liquids turn into a topologically non-trivial chiral spin-liquid state with non-abelian anionic excitations, which is crucial for quantum computing. Earlier theoretical predictions advocated that Kitaev physics can be realized in spin-orbit-coupled Mott insulators such as honeycomb irradiates and ruthenates. However, the experimental findings continuously challenge the theoretical aspects, indicating the presence of non-Kitaev interactions in real materials, where the dimensionality, disorder (vacancy), chemical composition, generalized spin-S, and external perturbations (pressure, magnetic field, temperature) can actively tune the Kitaev interactions and the ground state excitations. In this review article, a comprehensive discussion is included with an updated literature survey in the context of the potential of Raman spectroscopy as a probe for Kitaev quantum spin liquids.
The Kitaev honeycomb model realizes a quantum spin liquid where spin degrees of freedom are fractionalized into itinerant Majorana fermions and localized vortices. The entanglement among these particles holds promise for executing fault-tolerant topological quantum computation. While several materials have been proposed to host a quantum spin liquid phase, concrete evidence confirming its existence remains elusive. To aid in identifying this phase, we propose an electrical test using the charge profile, offering a signature for the Z2 vortices in Kitaev materials. This study explores the electric charge response in Kitaev materials, considering a generalized spin model including Heisenberg, off-diagonal exchange interactions, and magnetic Zeeman field. Majorana mean-field theory is employed to analyze spin correlations around vortices, revealing spatial anisotropy in the charge distribution, quantified by the electric quadrupole moment. This mean-field approach remains exact in the pure Kitaev limit and captures the fundamental physics across the Kitaev spin liquid phase. The quadrupole-quadrupole interaction between distant vortices is shown to be either repulsive or attractive, depending on the parameters. We predict that electrically biased scanning probe tips can help create vortices at predetermined locations. The findings of our study pave the way for electrically manipulating Ising anyons in Kitaev spin liquids, offering a promising path for technological applications of Kitaev materials.
We determine the phase diagrams of anisotropic Kitaev-Heisenberg models on the honeycomb lattice using parton mean-field theories based on different Majorana fermion representations of the S=1/2 spin operators. First, we use a two-dimensional Jordan-Wigner transformation (JWT) involving a semi-infinite snake string operator. To ensure that the fermionized Hamiltonian remains local, we consider the limit of extreme Ising exchange anisotropy in the Heisenberg sector. Second, we use the conventional Kitaev representation in terms of four Majorana fermions subject to local constraints, which we enforce through Lagrange multipliers. For both representations, we self-consistently decouple the interaction terms in the bond and magnetization channels and determine the phase diagrams as a function of the anisotropy of the Kitaev couplings and the relative strength of the Ising exchange. While both mean-field theories produce identical phase boundaries for the topological phase transition between the gapless and gapped Kitaev quantum spin liquids, the JWT fails to correctly describe the magnetic instability and finite-temperature behavior. Our results show that the magnetic phase transition is first order at low temperatures but becomes continuous above a certain temperature. At this energy scale, we also observe a finite-temperature crossover on the quantum-spin-liquid side, from a fractionalized paramagnet at low temperatures, in which gapped flux excitations are frozen out, to a conventional paramagnet at high temperatures. Published by the American Physical Society 2024
A one-dimensional fermionic system, such as a superconducting wire, may host Majorana zero-energy edge modes (MZMs) at its edges when it is in the topological phase. MZMs provide a path to realising fault-tolerant quantum computation, and so are the focus of intense experimental and theoretical studies. However, given a Hamiltonian, determining whether MZMs exist is a daunting task as it relies on knowing the spectral properties of the Hamiltonian in the thermodynamic limit. The Kitaev chain is a paradigmatic non-interacting model that supports MZMs and the Hamiltonian can be fully diagonalised. However, for interacting models, the situation is far more complex. Here we consider a different classification of models, namely, ones with frustration-free Hamiltonians. Within this class of models, interacting and non-interacting systems are treated on an equal footing, and we identify exactly which Hamiltonians can realise MZMs.