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arXiv:2511.01358 · Physical Review Research

Non-Markovian dynamics in nonstationary Gaussian baths

Vladisalv Sukharnikov, Stasis Chuchurka, Frank Schlawin

quant-phSubmitted Nov 3, 2025• Announced Nov 4, 2025• 0 citations
v1 · Nov 3, 2025v2 · Nov 24, 2025v3 · Mar 12, 2026
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Abstract

Building on the standard hierarchy of pure states (HOPS) approach, we construct a generalized formulation suitable for open quantum systems interacting with nonstationary Gaussian baths, potentially extending its applicability to nonequilibrium baths. This is achieved by extending the conventional exponential decomposition of bath correlation functions (BCF) to allow explicitly time-dependent forms. We demonstrate the method's performance on two examples of nonstationary squeezed reservoirs generated via uniform squeezing and degenerate parametric amplification. Benchmarking against the associated hierarchy of master equations shows that HOPS achieves superior efficiency under hierarchy truncation. In cases where each contribution in the BCF expansion can be associated with an independent physical bath, the formalism can be simplified in a pseudomode representation which is more efficient in a strongly non-Markovian regime. Our results highlight HOPS as a versatile and powerful tool for simulating open quantum systems in nonstationary baths, with potential applications ranging from squeezed light-matter interactions to driven quantum materials and dissipative phase transitions.

DOI
10.1103/yt37-s9hz

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We unite two of the most widely used approaches for strongly damped, non-Markovian open quantum dynamics, the Hierarchical Equations of Motion (HEOM) and the pseudomode method by proving two statements: First, every physical bath correlation function (BCF) that can be written as a sum of NNN exponential terms can be obtained from a physical model with NNN interacting pseudomodes which are damped in Lindblad form. Second, for every such BCF there exists a non-unitary, linear transformation which mirrors the evolution of the system-pseudomode state onto the HEOM hierarchy, and vice versa. Our proofs are constructive and we give explicit expressions for the mirror transformation as well as for the pseudomode Lindbladian corresponding to a given exponential BCF. This approach also gives insight and provides elegant derivations of the corresponding Hierarchy of stochastic Pure States (HOPS) method and its nearly-unitary version, nuHOPS. Our result opens several avenues for further optimization of non-Markovian open quantum system dynamics methods.
We show that the general and numerically exact Hierarchy of Pure States method (HOPS) is very well applicable to calculate the reduced dynamics of an open quantum system. In particular, we focus on environments with a sub-Ohmic spectral density (SD) resulting in an algebraic decay of the bath correlation function (BCF). The universal applicability of HOPS, reaching from weak to strong coupling for zero and nonzero temperature, is demonstrated by solving the spin-boson model for which we find perfect agreement with other methods, each one suitable for a special regime of parameters. The challenges arising in the strong coupling regime are not only reflected in the computational effort needed for the HOPS method to converge but also in the necessity for an importance sampling mechanism, accounted for by the nonlinear variant of HOPS. In order to include nonzero-temperature effects in the strong coupling regime we found that it is highly favorable for the HOPS method to use the zero-temperature BCF and include temperature via a stochastic Hermitian contribution to the system Hamiltonian.
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We study non-Markovian dynamics of an open quantum system system interacting with a nonstationary squeezed bosonic reservoir. We derive exact and approximate descriptions for the open system dynamics. Focusing on the spin boson model, we compare exact dynamics with Redfield theory and a quantum optical master equation for both short and long time dynamics and in non-Markovian and Markov regimes. The squeezing of the bath results in asymptotic oscillations in the stationary state, which are captured faithfully by the Redfield master equation in the case of weak coupling. Furthermore, we find that the bath squeezing direction modifies the effective system-environment coupling strength and, thus, the strength of the dissipation.
We derive a hierarchy of stochastic evolution equations for pure states (quantum trajectories) for open quantum system dynamics with non-Markovian structured environments. This hierarchy of pure states (HOPS) is generally applicable and provides the exact reduced density operator as an ensemble average over normalized states. The corresponding nonlinear equations are presented. We demonstrate that HOPS provides an efficient theoretical tool and apply it to the spin-boson model, the calculation of absorption spectra of molecular aggregates, and energy transfer in a photosynthetic pigment-protein complex.
Embedding non-Markovian open quantum dynamics into an enlarged Markovian space offers a powerful route to nonperturbative simulations, where the dynamics of the extended space can be governed by multiple distinct Markovian equations. We show that these distinct embeddings arise from different unravelings of Gaussian bath self-energies, generating a family of deterministic, time-local equations for the extended system. Using the Brownian-oscillator spectral density as an illustrative example, we clarify the relationships among existing approaches, including the Hierarchical Equations of Motion (HEOM) and the Lindblad--pseudomode formalism, and demonstrate how this framework enables numerically stable and efficient simulations. This work provides both a transparent theoretical foundation for embedding techniques and a flexible platform for developing new methods to simulate non-Markovian quantum dynamics.