Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2510.26956

Engineering Biquadratic Interactions in Spin-1 Chains by Spin-1/2 Spacers

Yasser Saleem, Weronika Pasek, Marek Korkusiński, Moritz Cygorek, Paweł Potasz

Published Oct 30, 2025• 0 citations
arXivHTMLPDF

Abstract

Low-dimensional quantum systems host a variety of exotic states, such as symmetry-protected topological ground states in spin-1 Haldane chains. Real-world realizations of such states could serve as practical quantum simulators for quantum phases if the interactions can be controlled. However, many proposed models, such as the Affleck-Kennedy-Lieb-Tasaki (AKLT) state, require unconventional forms of spin interactions beyond standard Heisenberg terms, which do not naturally emerge from microscopic (Coulomb) interactions. Here, we demonstrate a general strategy to induce a biquadratic term between two spin-1 sites and to tune its strength $β$ by placing pairs of spin-1/2 spacers in between them. $β$ is controlled by the ratio of the Heisenberg couplings between the spin-1 sites and the spacer spins, and between the spacer spins themselves. Increasing this ratio increases the magnitude of $|β|$ and decreases the correlation length of edge states. Detailed atomistic calculations reveal that chains of nanographene flakes with 22 and 13 atoms, respectively, which could be realized by state-of-the-art bottom-up growth technology, yield precisely the couplings required to approach the AKLT state. These findings deliver a blueprint for engineering unconventional interactions in bottom-up synthesized quantum simulators.

DOI
10.48550/arxiv.2510.26956

Related papers

Symmetry-Protected Topological Haldane Phase on a Qudit Quantum Processor

Claire Edmunds, E. Rico, Íñigo Arrazola +4 more

Symmetry-protected topological phases have fundamentally changed our understanding of quantum matter. An archetypal example of such a quantum phase of matter is the Haldane phase, containing the spin-1 Heisenberg chain. The intrinsic quantum nature of such phases, however, often makes it challenging to study them using classical means. Here, we use trapped-ion qutrits to natively engineer spin-1 chains within the Haldane phase. Using a scalable deterministic procedure to prepare the Affleck-Kennedy-Lieb-Tasaki (AKLT) state within the Haldane phase, we study the topological features of this system on a qudit quantum processor. Notably, we verify the long-range string order of the state, despite its short-range correlations, and observe spin fractionalization of the physical spin-1 particles into effective qubits at the chain edges, a defining feature of this system. The native realization of Haldane physics on a qudit quantum processor and the scalable preparation procedures open the door to the efficient exploration of a wide range of systems beyond spin-1/2.

arXiv:2408.04702•PRX Quantum•Jun 11, 2025•13 citations

Two topological phases in exchange alternating spin-1 nanographene chains

J. C. G. Henriques, Y. del Castillo, Ricardo Segundo +2 more

Magnetic nanographenes are emerging as versatile building blocks for artificial spin lattices, enabling the exploration of flagship one-dimensional quantum-magnetism models with unprecedented control. The spin-1 Heisenberg model, including bilinear and biquadratic exchange, was first realized using [3]-triangulenes, revealing the Haldane phase. More recently, Clar’s goblets enabled the spin-1/2 Heisenberg model with exchange alternation, uncovering additional topological phases. Here we show that spin-1 nanographenes can be used to explore bond-alternating chains both in the Haldane phase and beyond it, in a dimerized phase with emergent edge spin-1. We use density matrix renormalization group (DMRG) to analyze how biquadratic exchange, which is known to be large in spin-1 nanographenes, determines the phase transition boundary. Combining multiconfigurational and first-principles calculations, we identify two realistic candidates to realize these two different phases: the recently synthesized extended Clar’s goblet and a passivated [4]-triangulene. We demonstrate how to distinguish these phases experimentally using inelastic electron tunneling spectroscopy, paving the way for their observation.

arXiv:2510.23555•SciPost Physics•Jul 7, 2026•2 citations

Spin quantum Hall effects in featureless nonfractionalized spin-1 magnets

Yuan-Ming Lu, D. H. Lee

The Affleck-Kennedy-Lieb-Tasaki state (or Haldane phase) in a spin-1 chain represents a large class of gapped topological paramagnets that host symmetry-protected gapless excitations on the boundary. In this work, we show how to realize this type of featureless spin-1 state on a generic two-dimensional lattice. These states have a gapped spectrum in the bulk, but they support gapless edge states protected by spin rotational symmetry along a certain direction, and they exhibit the spin quantum Hall effect. Using a fermion representation of integer spins, we show a concrete example of such spin-1 topological paramagnets on a kagome lattice, and we suggest a microscopic spin-1 Hamiltonian that may realize it.

arXiv:1212.0863•Physical Review B•May 27, 2014•22 citations

Tunable topological phases in nanographene-based spin-1/2 alternating-exchange Heisenberg chains

Chenxiao Zhao, Gonçalo Catarina, Jinjiang Zhang +8 more

Unlocking the potential of topological order within many-body spin systems has long been a central pursuit in the realm of quantum materials. Despite extensive efforts, the quest for a versatile platform enabling site-selective spin manipulation, essential for tuning and probing diverse topological phases, has persisted. Here, we utilize on-surface synthesis to construct spin-1/2 alternating-exchange Heisenberg (AH) chains[1] with antiferromagnetic couplings $J_1$ and $J_2$ by covalently linking Clar's goblets -- nanographenes each hosting two antiferromagnetically-coupled unpaired electrons[2]. Utilizing scanning tunneling microscopy, we exert atomic-scale control over the spin chain lengths, parities and exchange-coupling terminations, and probe their magnetic response by means of inelastic tunneling spectroscopy. Our investigation confirms the gapped nature of bulk excitations in the chains, known as triplons[3]. Besides, the triplon dispersion relation is successfully extracted from the spatial variation of tunneling spectral amplitudes. Furthermore, depending on the parity and termination of chains, we observe varying numbers of in-gap $S=1/2$ edge spins, enabling the determination of the degeneracy of distinct topological ground states in the thermodynamic limit-either 1, 2, or 4. By monitoring interactions between these edge spins, we identify the exponential decay of spin correlations. Our experimental findings, corroborated by theoretical calculations, present a phase-controlled many-body platform, opening promising avenues toward the development of spin-based quantum devices.

arXiv:2402.13590•Feb 21, 2024•7 citations

AKLT Hamiltonian from Hubbard tripods

Claire Benjamin, Dániel Varjas, Gábor Széchenyi +2 more

We investigate how the spin-1 Affleck-Kennedy-Lieb-Tasaki (AKLT) Hamiltonian can emerge from a microscopic fermionic model based on half-filled Hubbard tripods. We first show that a single tripod hosts a robust threefold-degenerate low-energy manifold corresponding to an effective $S = 1$ degree of freedom. This manifold prevails over a broad range of interactions and remains stable against moderate disorder. We then combine exact diagonalization with fourth-order quasi-degenerate perturbation theory to derive an effective bilinear-biquadratic spin model for a pair of coupled tripods and identify coupling regimes where the target ratio is approached. In particular, tuning leg-center hopping together with two symmetry-inequivalent leg-leg hoppings yields the characteristic singlet-triplet degeneracy associated with a biquadratic-to-bilinear ratio close to 1/3. Extending the analysis to three tripods, we compare nonequivalent coupling geometries and find a strategy that suppresses unwanted longer-range and multispin terms while preserving the target nearest-neighbor couplings in the weak-coupling regime. These results establish a concrete bottom-up route from Hubbard clusters to valence-bond-solid spin physics in tunable quantum-dot arrays.

cond-mat.str-elCross-listedarXiv:2603.06455•Mar 9, 2026•0 citations

Realizing the symmetry-protected Haldane phase in Fermi–Hubbard ladders

Pimonpan Sompet, Sarah Hirthe, Dominik Bourgund +10 more

Abstract Topology in quantum many-body systems has profoundly changed our understanding of quantum phases of matter. The model that has played an instrumental role in elucidating these effects is the antiferromagnetic spin-1 Haldane chain 1,2 . Its ground state is a disordered state, with symmetry-protected fourfold-degenerate edge states due to fractional spin excitations. In the bulk, it is characterized by vanishing two-point spin correlations, gapped excitations and a characteristic non-local order parameter 3,4 . More recently it has been understood that the Haldane chain forms a specific example of a more general classification scheme of symmetry-protected topological phases of matter, which is based on ideas connected to quantum information and entanglement 5–7 . Here, we realize a finite-temperature version of such a topological Haldane phase with Fermi–Hubbard ladders in an ultracold-atom quantum simulator. We directly reveal both edge and bulk properties of the system through the use of single-site and particle-resolved measurements, as well as non-local correlation functions. Continuously changing the Hubbard interaction strength of the system enables us to investigate the robustness of the phase to charge (density) fluctuations far from the regime of the Heisenberg model, using a novel correlator.

arXiv:2103.10421•Nature•Jun 1, 2022•138 citations
Low-dimensional quantum systems host a variety of exotic states, such as symmetry-protected topological ground states in spin-1 Haldane chains. Real-world realizations of such states could serve as practical quantum simulators for quantum phases if the interactions can be controlled. However, many proposed models, such as the Affleck-Kennedy-Lieb-Tasaki (AKLT) state, require unconventional forms of spin interactions beyond standard Heisenberg terms, which do not naturally emerge from microscopic (Coulomb) interactions. Here, we demonstrate a general strategy to induce a biquadratic term between two spin-1 sites and to tune its strength βββ by placing pairs of spin-1/2 spacers in between them. βββ is controlled by the ratio of the Heisenberg couplings between the spin-1 sites and the spacer spins, and between the spacer spins themselves. Increasing this ratio increases the magnitude of ∣β∣|β|∣β∣ and decreases the correlation length of edge states. Detailed atomistic calculations reveal that chains of nanographene flakes with 22 and 13 atoms, respectively, which could be realized by state-of-the-art bottom-up growth technology, yield precisely the couplings required to approach the AKLT state. These findings deliver a blueprint for engineering unconventional interactions in bottom-up synthesized quantum simulators.
Symmetry-protected topological phases have fundamentally changed our understanding of quantum matter. An archetypal example of such a quantum phase of matter is the Haldane phase, containing the spin-1 Heisenberg chain. The intrinsic quantum nature of such phases, however, often makes it challenging to study them using classical means. Here, we use trapped-ion qutrits to natively engineer spin-1 chains within the Haldane phase. Using a scalable deterministic procedure to prepare the Affleck-Kennedy-Lieb-Tasaki (AKLT) state within the Haldane phase, we study the topological features of this system on a qudit quantum processor. Notably, we verify the long-range string order of the state, despite its short-range correlations, and observe spin fractionalization of the physical spin-1 particles into effective qubits at the chain edges, a defining feature of this system. The native realization of Haldane physics on a qudit quantum processor and the scalable preparation procedures open the door to the efficient exploration of a wide range of systems beyond spin-1/2.
Magnetic nanographenes are emerging as versatile building blocks for artificial spin lattices, enabling the exploration of flagship one-dimensional quantum-magnetism models with unprecedented control. The spin-1 Heisenberg model, including bilinear and biquadratic exchange, was first realized using [3]-triangulenes, revealing the Haldane phase. More recently, Clar’s goblets enabled the spin-1/2 Heisenberg model with exchange alternation, uncovering additional topological phases. Here we show that spin-1 nanographenes can be used to explore bond-alternating chains both in the Haldane phase and beyond it, in a dimerized phase with emergent edge spin-1. We use density matrix renormalization group (DMRG) to analyze how biquadratic exchange, which is known to be large in spin-1 nanographenes, determines the phase transition boundary. Combining multiconfigurational and first-principles calculations, we identify two realistic candidates to realize these two different phases: the recently synthesized extended Clar’s goblet and a passivated [4]-triangulene. We demonstrate how to distinguish these phases experimentally using inelastic electron tunneling spectroscopy, paving the way for their observation.
The Affleck-Kennedy-Lieb-Tasaki state (or Haldane phase) in a spin-1 chain represents a large class of gapped topological paramagnets that host symmetry-protected gapless excitations on the boundary. In this work, we show how to realize this type of featureless spin-1 state on a generic two-dimensional lattice. These states have a gapped spectrum in the bulk, but they support gapless edge states protected by spin rotational symmetry along a certain direction, and they exhibit the spin quantum Hall effect. Using a fermion representation of integer spins, we show a concrete example of such spin-1 topological paramagnets on a kagome lattice, and we suggest a microscopic spin-1 Hamiltonian that may realize it.
Unlocking the potential of topological order within many-body spin systems has long been a central pursuit in the realm of quantum materials. Despite extensive efforts, the quest for a versatile platform enabling site-selective spin manipulation, essential for tuning and probing diverse topological phases, has persisted. Here, we utilize on-surface synthesis to construct spin-1/2 alternating-exchange Heisenberg (AH) chains[1] with antiferromagnetic couplings J1J_1J1​ and J2J_2J2​ by covalently linking Clar's goblets -- nanographenes each hosting two antiferromagnetically-coupled unpaired electrons[2]. Utilizing scanning tunneling microscopy, we exert atomic-scale control over the spin chain lengths, parities and exchange-coupling terminations, and probe their magnetic response by means of inelastic tunneling spectroscopy. Our investigation confirms the gapped nature of bulk excitations in the chains, known as triplons[3]. Besides, the triplon dispersion relation is successfully extracted from the spatial variation of tunneling spectral amplitudes. Furthermore, depending on the parity and termination of chains, we observe varying numbers of in-gap S=1/2S=1/2S=1/2 edge spins, enabling the determination of the degeneracy of distinct topological ground states in the thermodynamic limit-either 1, 2, or 4. By monitoring interactions between these edge spins, we identify the exponential decay of spin correlations. Our experimental findings, corroborated by theoretical calculations, present a phase-controlled many-body platform, opening promising avenues toward the development of spin-based quantum devices.
We investigate how the spin-1 Affleck-Kennedy-Lieb-Tasaki (AKLT) Hamiltonian can emerge from a microscopic fermionic model based on half-filled Hubbard tripods. We first show that a single tripod hosts a robust threefold-degenerate low-energy manifold corresponding to an effective S=1S = 1S=1 degree of freedom. This manifold prevails over a broad range of interactions and remains stable against moderate disorder. We then combine exact diagonalization with fourth-order quasi-degenerate perturbation theory to derive an effective bilinear-biquadratic spin model for a pair of coupled tripods and identify coupling regimes where the target ratio is approached. In particular, tuning leg-center hopping together with two symmetry-inequivalent leg-leg hoppings yields the characteristic singlet-triplet degeneracy associated with a biquadratic-to-bilinear ratio close to 1/3. Extending the analysis to three tripods, we compare nonequivalent coupling geometries and find a strategy that suppresses unwanted longer-range and multispin terms while preserving the target nearest-neighbor couplings in the weak-coupling regime. These results establish a concrete bottom-up route from Hubbard clusters to valence-bond-solid spin physics in tunable quantum-dot arrays.
Abstract Topology in quantum many-body systems has profoundly changed our understanding of quantum phases of matter. The model that has played an instrumental role in elucidating these effects is the antiferromagnetic spin-1 Haldane chain 1,2 . Its ground state is a disordered state, with symmetry-protected fourfold-degenerate edge states due to fractional spin excitations. In the bulk, it is characterized by vanishing two-point spin correlations, gapped excitations and a characteristic non-local order parameter 3,4 . More recently it has been understood that the Haldane chain forms a specific example of a more general classification scheme of symmetry-protected topological phases of matter, which is based on ideas connected to quantum information and entanglement 5–7 . Here, we realize a finite-temperature version of such a topological Haldane phase with Fermi–Hubbard ladders in an ultracold-atom quantum simulator. We directly reveal both edge and bulk properties of the system through the use of single-site and particle-resolved measurements, as well as non-local correlation functions. Continuously changing the Hubbard interaction strength of the system enables us to investigate the robustness of the phase to charge (density) fluctuations far from the regime of the Heisenberg model, using a novel correlator.