The intuition that the precision of observables is constrained by thermodynamic costs has recently been formalized through thermodynamic and kinetic uncertainty relations. While such trade-offs have been extensively studied in Markovian systems, corresponding constraints in the non-Markovian regime remain largely unexplored. In this Letter, we derive universal bounds on the precision of generic observables in open quantum systems that interact with their environments at arbitrary coupling strengths and are subjected to two-point measurements. By introducing an asymmetry term that quantifies the disparity between forward and backward processes, we show that the relative fluctuation of any time-antisymmetric current is constrained not only by entropy production but also by this asymmetry. For general observables, we further prove that their relative fluctuation is always bounded from below by a generalized activity term that characterizes environmental changes. These results establish a comprehensive framework for understanding the fundamental limits of precision in a broad class of open quantum systems, beyond the traditional Markovian setting.
The intuition that the precision of observables is constrained by thermodynamic costs has recently been formalized through thermodynamic and kinetic uncertainty relations. While such trade-offs have been extensively studied in Markovian systems, corresponding constraints in the non-Markovian regime remain largely unexplored. In this Letter, we derive universal bounds on the precision of generic observables in open quantum systems that interact with their environments at arbitrary coupling strengths and are subjected to two-point measurements. By introducing an asymmetry term that quantifies the disparity between forward and backward processes, we show that the relative fluctuation of any time-antisymmetric current is constrained not only by entropy production but also by this asymmetry. For general observables, we further prove that their relative fluctuation is always bounded from below by a generalized activity term that characterizes environmental changes. These results establish a comprehensive framework for understanding the fundamental limits of precision in a broad class of open quantum systems, beyond the traditional Markovian setting.
The precision and response of trajectory observables offer valuable insights into the behavior of nonequilibrium systems. For classical systems, trade-offs between these characteristics and thermodynamic costs, such as entropy production and dynamical activity, have been established through uncertainty relations. Quantum systems, however, present unique challenges, where quantum coherence can enhance precision and violate classical uncertainty relations. In this study, we derive trade-off relations for stochastic observables in Markovian open quantum systems. Specifically, we present three key results: (i) a quantum generalization of the thermokinetic uncertainty relation, which bounds the relative fluctuations of currents in terms of entropy production and dynamical activity; (ii) a quantum inverse uncertainty relation, which constrains the relative fluctuations of arbitrary counting observables based on their instantaneous fluctuations and the spectral gap of the symmetrized Liouvillian; and (iii) a quantum response kinetic uncertainty relation, which bounds the response of general observables to kinetic perturbations in terms of dynamical activity. These fundamental bounds, validated numerically using a three-level maser and a boundary-driven X X Z spin chain, provide a comprehensive framework for understanding the interplay between precision, response, and thermodynamic costs in quantum systems.
Kinetic uncertainty relations bound current precision of stochastic processes by dynamical activity. The extension of these bounds to quantum systems has been impeded by coherence, strong system-reservoir coupling, and the subtlety of defining dynamical activity in the quantum regime. Here, we introduce a partial dynamical activity through the quantum Fisher information associated with the rescaling of the system-reservoir coupling and show that it bounds current precision via a universal susceptibility-kinetic uncertainty relation. The general validity of this relation for any open quantum system is guaranteed by the natural contribution of a susceptibility term, which is experimentally accessible by tuning the system-reservoir coupling strength. We show how the partial dynamical activity encompasses previous definitions of activity in the weak-coupling Markovian limit and that it provides an information-geometric interpretation of correlator-based activities. We illustrate the tight constraint on precision that our bound provides with the example of steady-state transport through a double quantum dot, where quantum effects invalidate previously developed kinetic uncertainty relations. We expect our bound to provide a powerful tool for optimizing precision in arbitrary quantum systems.
The thermodynamic and kinetic uncertainty relations indicate trade-offs between the relative fluctuation of observables and thermodynamic quantities such as dissipation and dynamical activity. Although these relations have been well studied for classical systems, they remain largely unexplored in the quantum regime. In this Letter, we investigate such trade-off relations for Markovian open quantum systems whose underlying dynamics are quantum jumps, such as thermal processes and quantum measurement processes. Specifically, we derive finite-time lower bounds on the relative fluctuation of both dynamical observables and their first passage times for arbitrary initial states. The bounds imply that the precision of observables is constrained not only by thermodynamic quantities but also by quantum coherence. We find that the product of the relative fluctuation and entropy production or dynamical activity is enhanced by quantum coherence in a generic class of dissipative processes of systems with nondegenerate energy levels. Our findings provide insights into the survival of the classical uncertainty relations in quantum cases.
Enhancing the precision of a thermodynamic process inevitably necessitates a thermodynamic cost. This notion was recently formulated as the thermodynamic uncertainty relation, which states that the lower bound on the relative variance of thermodynamic currents decreases as entropy production increases. From another viewpoint, the thermodynamic uncertainty relation implies that if entropy production were allowed to become infinitely large, the lower bound on the relative variance could approach zero. However, it is evident that realizing infinitely large entropy production is infeasible in reality. This indicates that physical constraints impose precision limits on the system, independent of its dynamics. In this study, we derive fundamental precision limits, dynamics-independent bounds on the relative variance and the expectations of observables, for open quantum thermal machines operating within a finite-dimensional system and environment. These bounds are set by quantities such as dimensions, energy bandwidth, and initial minimum eigenvalue, which depend only on the initial configuration and are independent of the dynamics. Using a quantum battery model, the fundamental precision limits show that there is a trade-off between the amount of energy storage and the charging precision. Additionally, we investigate how quantum coherence affects these fundamental limits, demonstrating that the presence of coherence can improve the precision limits. Our findings provide insights into fundamental limits on the precision of quantum thermal machines.
We derive a thermodynamic uncertainty relation for general open quantum dynamics, described by a joint unitary evolution on a composite system comprising a system and an environment. By measuring the environmental state after the system-environment interaction, we bound the counting observables in the environment by the survival activity, which reduces to the dynamical activity in classical Markov processes. Remarkably, the relation derived herein holds for general open quantum systems with any counting observable and any initial state. Therefore, our relation is satisfied for classical Markov processes with arbitrary time-dependent transition rates and initial states. We apply our relation to continuous measurement and the quantum walk to find that the quantum nature of the system can enhance the precision. Moreover, we can make the lower bound arbitrarily small by employing appropriate continuous measurement.
Response uncertainty relations in stochastic thermodynamics extend precision bounds to the sensitivity of observables under external perturbations. Here we derive a quantum response kinetic uncertainty relation for continuously monitored Markovian open quantum systems in the steady state of the Lindblad master equation. The response precision of a measured trajectory observable is bounded by two contributions: the conventional quantum dynamical activity and a perturbation-induced intersubspace transition term. The latter is absent in the classical limit and captures a genuinely quantum part of the response cost. We identify simple conditions under which either contribution vanishes, and we further clarify the structure of the intersubspace term through a symmetry-resolved decomposition and exact sector-selection rules. The bound and its structure are illustrated in a driven two-level atom.