The thermodynamic and kinetic uncertainty relations indicate trade-offs between the relative fluctuation of observables and thermodynamic quantities such as dissipation and dynamical activity. Although these relations have been well studied for classical systems, they remain largely unexplored in the quantum regime. In this Letter, we investigate such trade-off relations for Markovian open quantum systems whose underlying dynamics are quantum jumps, such as thermal processes and quantum measurement processes. Specifically, we derive finite-time lower bounds on the relative fluctuation of both dynamical observables and their first passage times for arbitrary initial states. The bounds imply that the precision of observables is constrained not only by thermodynamic quantities but also by quantum coherence. We find that the product of the relative fluctuation and entropy production or dynamical activity is enhanced by quantum coherence in a generic class of dissipative processes of systems with nondegenerate energy levels. Our findings provide insights into the survival of the classical uncertainty relations in quantum cases.
The thermodynamic and kinetic uncertainty relations indicate trade-offs between the relative fluctuation of observables and thermodynamic quantities such as dissipation and dynamical activity. Although these relations have been well studied for classical systems, they remain largely unexplored in the quantum regime. In this Letter, we investigate such trade-off relations for Markovian open quantum systems whose underlying dynamics are quantum jumps, such as thermal processes and quantum measurement processes. Specifically, we derive finite-time lower bounds on the relative fluctuation of both dynamical observables and their first passage times for arbitrary initial states. The bounds imply that the precision of observables is constrained not only by thermodynamic quantities but also by quantum coherence. We find that the product of the relative fluctuation and entropy production or dynamical activity is enhanced by quantum coherence in a generic class of dissipative processes of systems with nondegenerate energy levels. Our findings provide insights into the survival of the classical uncertainty relations in quantum cases.
The precision and response of trajectory observables offer valuable insights into the behavior of nonequilibrium systems. For classical systems, trade-offs between these characteristics and thermodynamic costs, such as entropy production and dynamical activity, have been established through uncertainty relations. Quantum systems, however, present unique challenges, where quantum coherence can enhance precision and violate classical uncertainty relations. In this study, we derive trade-off relations for stochastic observables in Markovian open quantum systems. Specifically, we present three key results: (i) a quantum generalization of the thermokinetic uncertainty relation, which bounds the relative fluctuations of currents in terms of entropy production and dynamical activity; (ii) a quantum inverse uncertainty relation, which constrains the relative fluctuations of arbitrary counting observables based on their instantaneous fluctuations and the spectral gap of the symmetrized Liouvillian; and (iii) a quantum response kinetic uncertainty relation, which bounds the response of general observables to kinetic perturbations in terms of dynamical activity. These fundamental bounds, validated numerically using a three-level maser and a boundary-driven X X Z spin chain, provide a comprehensive framework for understanding the interplay between precision, response, and thermodynamic costs in quantum systems.
Abstract In classical Markov jump processes, current fluctuations can only be reduced at the cost of increased dissipation. To explore how quantum effects influence this trade-off, we analyze the uncertainty of steady-state currents in Markovian open quantum systems. We first consider three instructive examples and then systematically minimize the product of uncertainty and entropy production for small open quantum systems. As our main result, we find that the thermodynamic cost of reducing fluctuations can be lowered below the classical bound by coherence. We conjecture that this cost can be made arbitrarily small in quantum systems with sufficiently many degrees of freedom. Our results thereby provide a general guideline for the design of thermal machines in the quantum regime that operate with high thermodynamic precision, meaning low dissipation and small fluctuations around average values.
The intuition that the precision of observables is constrained by thermodynamic costs has recently been formalized through thermodynamic and kinetic uncertainty relations. While such trade-offs have been extensively studied in Markovian systems, corresponding constraints in the non-Markovian regime remain largely unexplored. In this Letter, we derive universal bounds on the precision of generic observables in open quantum systems that interact with their environments at arbitrary coupling strengths and are subjected to two-point measurements. By introducing an asymmetry term that quantifies the disparity between forward and backward processes, we show that the relative fluctuation of any time-antisymmetric current is constrained not only by entropy production but also by this asymmetry. For general observables, we further prove that their relative fluctuation is always bounded from below by a generalized activity term that characterizes environmental changes. These results establish a comprehensive framework for understanding the fundamental limits of precision in a broad class of open quantum systems, beyond the traditional Markovian setting.
We use quantum estimation theory to derive a thermodynamic uncertainty relation in Markovian open quantum systems, which bounds the fluctuation of continuous measurements. The derived quantum thermodynamic uncertainty relation holds for arbitrary continuous measurements satisfying a scaling condition. We derive two relations; the first relation bounds the fluctuation by the dynamical activity and the second one does so by the entropy production. We apply our bounds to a two-level atom driven by a laser field and a three-level quantum thermal machine with jump and diffusion measurements. Our result shows that there exists a universal bound upon the fluctuations, regardless of continuous measurements.
Thermodynamic uncertainty relations (TURs) and kinetic uncertainty relations (KURs) provide tradeoff relations between measurement fluctuation and thermodynamic cost, such as entropy production and activity. Conventionally, these relations are derived using the Cramér-Rao inequality, which involves an auxiliary perturbation in deterministic differential equations governing the time evolution of the system’s probability distribution. In this study, without relying on the previous formulation based on a deterministic evolving equation, we demonstrate that the main previously discovered uncertainty relations can be derived solely through the stochastic representation of the same dynamics. For this purpose, we propose a unified method based on stochastic representations for general Markovian dynamics. Extending beyond classical systems, we apply this method to Markovian open quantum systems by unraveling their dynamics, deriving quantum uncertainty relations that are tighter than existing ones in regimes where quantum effects play a significant role. This fully establishes uncertainty relations for both classical and quantum systems as intrinsic properties of their stochastic nature. Thermodynamic and kinetic uncertainty relations describe trade-offs between measurement fluctuations and thermodynamic costs, such as entropy production and activity. In this work, the authors present a general framework for deriving uncertainty relations in classical and quantum systems, leveraging the intrinsic stochastic properties of these systems.
We derive a thermodynamic uncertainty relation for general open quantum dynamics, described by a joint unitary evolution on a composite system comprising a system and an environment. By measuring the environmental state after the system-environment interaction, we bound the counting observables in the environment by the survival activity, which reduces to the dynamical activity in classical Markov processes. Remarkably, the relation derived herein holds for general open quantum systems with any counting observable and any initial state. Therefore, our relation is satisfied for classical Markov processes with arbitrary time-dependent transition rates and initial states. We apply our relation to continuous measurement and the quantum walk to find that the quantum nature of the system can enhance the precision. Moreover, we can make the lower bound arbitrarily small by employing appropriate continuous measurement.