We propose a witness of temporal quantum entanglement using the imaginary component of the complex heat capacity—a measurable thermodynamic quantity in temperature-modulated calorimetry. By establishing a direct correspondence between complex heat capacity and the pseudodensity matrix formalism, our approach enables the characterization of both spatial and temporal quantum correlations without demanding additional state-level manipulation beyond initial tomography. We analytically demonstrate this connection for an open quantum system modeled by a qubit coupled to a thermal bath and show how both pseudodensity matrix negativity and violations of a temporal Clauser-Horne-Shimony-Holt inequality emerge as indicators of nonclassical temporal correlations. We further identify bounds on the imaginary heat capacity that guarantee temporal entanglement, providing an experimentally accessible criterion at the macroscopic scale. This framework offers a feasible route for probing temporal quantum effects in condensed-matter systems and opens a viable path toward experimental realization.
We propose a witness of temporal quantum entanglement using the imaginary component of the complex heat capacity—a measurable thermodynamic quantity in temperature-modulated calorimetry. By establishing a direct correspondence between complex heat capacity and the pseudodensity matrix formalism, our approach enables the characterization of both spatial and temporal quantum correlations without demanding additional state-level manipulation beyond initial tomography. We analytically demonstrate this connection for an open quantum system modeled by a qubit coupled to a thermal bath and show how both pseudodensity matrix negativity and violations of a temporal Clauser-Horne-Shimony-Holt inequality emerge as indicators of nonclassical temporal correlations. We further identify bounds on the imaginary heat capacity that guarantee temporal entanglement, providing an experimentally accessible criterion at the macroscopic scale. This framework offers a feasible route for probing temporal quantum effects in condensed-matter systems and opens a viable path toward experimental realization.
The heat capacity of a system quantifies how it energetically responds to changes in temperature at equilibrium. Whilst this quantity is positive and even additive for non-interacting systems, self-gravitating systems such as stars or subsystems of strongly interacting quantum systems are known to have negative or anomalous specific heat capacities. In this work, we investigate how the presence of entanglement at equilibrium can influence how an interacting system responds energetically to changes in temperature. We examine the local heat capacity of interacting quantum systems providing an analytical understanding for when anomalies occur. Most interestingly, we find a connection between local heat capacity anomalies and entanglement by deriving a separability bound based on the fluctuations of local and interaction energies. We illustrate our results with two examples (i) a nearest neighbour spin-1/2 chain and (ii) two coupled quantum harmonic oscillators. Lastly, we provide an information-theoretic formula connecting mutual information and athermality to the non-additivity of the heat capacity. Our results provide model-independent thermodynamic entanglement detection bounds and insight into the relationship between quantum correlations and the heat capacity of quantum systems.
We demonstrate that the presence of entanglement in macroscopic bodies (e.g., solids) in thermodynamical equilibrium could be revealed by measuring heat capacity. The idea is that if the system was in a separable state, then for certain Hamiltonians heat capacity would not tend asymptotically to zero as the temperature approaches absolute zero. Since this would contradict the third law of thermodynamics, one concludes that the system must contain entanglement. The separable bounds are obtained by minimalization of the heat capacity over separable states and using its universal low-temperature behavior. Our results open up a possibility to use standard experimental techniques of solid-state physics---namely, heat-capacity measurements---to detect entanglement in macroscopic samples.
We introduce a witness-based framework for certifying quantum temporal correlations via the pseudo-density matrix (PDM) formalism, which is a spatiotemporal generalization of the density matrix. We define spatial incompatibility (SI) as the minimum distance between a PDM and valid density matrices. For trace-norm distance, we show that this reduces to the PDM's negativity, enabling the construction of experimentally accessible SI witnesses. We derive a tight bound on SI for quantum channels and analyze the respective roles of state and channel coherence in witnessing SI. Our approach, unlike the LG framework, exploits measurements that generate coherence through state disturbance. We further show that channels satisfying the LG inequality for incoherent states can still exhibit detectable SI, demonstrating that measurement disturbance enhances the certification of temporal correlations.
We consider a temporal version of the Clauser–Horne–Shimony–Holt (CHSH) scenario using projective measurements on a single quantum system. It is known that quantum correlations in this scenario are fundamentally more general than correlations obtainable with the assumptions of macroscopic realism and non-invasive measurements. In this paper, we also educe some fundamental limitations of these quantum correlations. One result is that a set of correlators can appear in the temporal CHSH scenario if and only if it can appear in the usual spatial CHSH scenario. In particular, we derive the validity of the Tsirelson bound and the impossibility of Popescu–Rohrlich (PR)-box behavior. The strength of possible signaling also turns out to be surprisingly limited, giving a maximal communication capacity of approximately 0.32 bit. We also find a temporal version of Hardy's non-locality paradox with a maximal quantum value of 1/4.
Spatial Incompatibility Witnesses for Quantum Temporal Correlations: We introduce a witness-based framework for certifying quantum temporal correlations via the pseudo-density matrix (PDM) formalism, which is a spatiotemporal generalization of the density matrix. We define spatial incompatibility (SI) as the minimum distance between a PDM and valid density matrices. For trace-norm distance, we show that this reduces to the PDM’s negativity, enabling the construction of experimentally accessible SI witnesses. We derive a tight bound on SI for quantum channels and analyze the respective roles of state and channel coherence in witnessing SI. Our approach, unlike the Leggett–Garg (LG) framework, exploits incompatible measurements that generate coherence through state disturbance. We show that channels satisfying the LG inequality for incoherent states can still exhibit detectable SI, demonstrating that measurement disturbance enhances the certification of temporal correlations.
We introduce a witness-based framework for certifying quantum temporal correlations via the pseudo-density matrix (PDM) formalism, which is a spatiotemporal generalization of the density matrix. We define spatial incompatibility (SI) as the minimum distance between a PDM and valid density matrices. For trace-norm distance, we show that this reduces to the PDM's negativity, enabling the construction of experimentally accessible SI witnesses. We derive a tight bound on SI for quantum channels and analyze the respective roles of state and channel coherence in witnessing SI. Our approach, unlike the LG framework, exploits measurements that generate coherence through state disturbance. We further show that channels satisfying the LG inequality for incoherent states can still exhibit detectable SI, demonstrating that measurement disturbance enhances the certification of temporal correlations.
The Kolmogorov consistency condition (KCC) defines the statistical boundary between classical and quantum dynamics. Its violation signifies the breakdown of a classical Markov description of temporal correlations. In this work, we establish a direct analytical connection between KCC violation and non-Markovianity in open quantum dynamics, revealing how memory effects manifest as departures from classical probabilistic consistency. Within a generic two-level open quantum system framework, we establish quantitative connections between the magnitude of KCC violation and key information-theoretic and thermodynamic quantities, such as mutual information, the Fano factor, heat exchange, and entropy production rate, thereby enabling a thermodynamic interpretation of temporal quantum correlations. Furthermore, we uncover formal correspondences between KCC violation, the Leggett-Garg inequality, and the negativity of the Kirkwood-Dirac quasi-distribution, identifying them as complementary witnesses of temporal quantum non-classicality. Our results thus provide a unified framework linking information-theoretic, thermodynamic, and temporal indicators of quantumness in open quantum systems.