The heat capacity of a system quantifies how it energetically responds to changes in temperature at equilibrium. Whilst this quantity is positive and even additive for non-interacting systems, self-gravitating systems such as stars or subsystems of strongly interacting quantum systems are known to have negative or anomalous specific heat capacities. In this work, we investigate how the presence of entanglement at equilibrium can influence how an interacting system responds energetically to changes in temperature. We examine the local heat capacity of interacting quantum systems providing an analytical understanding for when anomalies occur. Most interestingly, we find a connection between local heat capacity anomalies and entanglement by deriving a separability bound based on the fluctuations of local and interaction energies. We illustrate our results with two examples (i) a nearest neighbour spin-1/2 chain and (ii) two coupled quantum harmonic oscillators. Lastly, we provide an information-theoretic formula connecting mutual information and athermality to the non-additivity of the heat capacity. Our results provide model-independent thermodynamic entanglement detection bounds and insight into the relationship between quantum correlations and the heat capacity of quantum systems.
The heat capacity of a system quantifies how it energetically responds to changes in temperature at equilibrium. Whilst this quantity is positive and even additive for non-interacting systems, self-gravitating systems such as stars or subsystems of strongly interacting quantum systems are known to have negative or anomalous specific heat capacities. In this work, we investigate how the presence of entanglement at equilibrium can influence how an interacting system responds energetically to changes in temperature. We examine the local heat capacity of interacting quantum systems providing an analytical understanding for when anomalies occur. Most interestingly, we find a connection between local heat capacity anomalies and entanglement by deriving a separability bound based on the fluctuations of local and interaction energies. We illustrate our results with two examples (i) a nearest neighbour spin-1/2 chain and (ii) two coupled quantum harmonic oscillators. Lastly, we provide an information-theoretic formula connecting mutual information and athermality to the non-additivity of the heat capacity. Our results provide model-independent thermodynamic entanglement detection bounds and insight into the relationship between quantum correlations and the heat capacity of quantum systems.
We demonstrate that the presence of entanglement in macroscopic bodies (e.g., solids) in thermodynamical equilibrium could be revealed by measuring heat capacity. The idea is that if the system was in a separable state, then for certain Hamiltonians heat capacity would not tend asymptotically to zero as the temperature approaches absolute zero. Since this would contradict the third law of thermodynamics, one concludes that the system must contain entanglement. The separable bounds are obtained by minimalization of the heat capacity over separable states and using its universal low-temperature behavior. Our results open up a possibility to use standard experimental techniques of solid-state physics---namely, heat-capacity measurements---to detect entanglement in macroscopic samples.
Heat capacity of a mixed-three-spin (1/2,1,1/2) antiferromagnetic XXX Heisenberg chain is precisely investigated by use of the partition function of the system for which, spins (1,1/2) have coupling constant [Formula: see text] and spins (1/2,1/2) have coupling constant [Formula: see text]. We verify tripartite entanglement for the model by means of the convex roof extended negativity (CREN) and concurrence as functions of temperature T, homogeneous magnetic field B and the coupling constants [Formula: see text] and [Formula: see text]. As shown in our previous work, [H. A. Zad, Chin. Phys. B 25 (2016) 030303.] the temperature, the magnetic field and the coupling constants dependences of the heat capacity for such spin system have different behaviors for the entangled and separable states, hence, we did some useful comparisons between this quantity and negativities of its organized bipartite (sub)systems at entangled and separable states. Here, we compare the heat capacity of the mixed-three-spin (1/2,1,1/2) system with the CREN and the tripartite concurrence (as measures of the tripartite entanglement) at low temperature. Ground state phase transitions, and also, transition from ground state to some excited states are explained in detail for this system at zero temperature. Finally, we investigate the heat capacity behavior around those critical points in which these quantum phase transitions occur.
This paper introduces the concept of Quantum Correlation Heat Capacity (QCHC), denoted as C_corr, as an independent thermodynamic response function characterizing the temperature-dependent evolution of quantum correlations within multipartite systems. While traditional thermodynamics defines heat capacity solely through the lens of internal energy variations with respect to temperature, namely C = (partial E) / (partial T), the framework presented here posits that information-theoretic measures—specifically quantum mutual information I(A:B)—exhibit their own distinct thermal storage and transfer dynamics. We define the quantum correlation heat capacity as C_corr = T * (partial I(A:B)) / (partial T), capturing the rate at which quantum correlation energy or informational configuration changes per unit temperature shift. By bridging quantum information theory and statistical mechanics, we demonstrate that temperature variations can induce an independent correlation heat storage capacity that operates orthogonally to ordinary energetic degrees of freedom. This formulation expands the conventional set of thermodynamic state variables, offering profound implications for quantum thermodynamics, information erasure, and the foundations of statistical mechanics.
Quantum Mechanics was established as the theory of the microscopic world, which allowed to understand processes in atoms and molecules. Its emergence led to a new scientific paradigm that quickly spread to different research fields. Two relevant examples are Quantum Thermodynamics and Quantum Many-Body Theory, where the former aims to characterize thermodynamic processes in quantum systems and the latter intends to understand the properties of quantum many-body systems. In this thesis, we tackle some of the questions in the overlap between these disciplines, focusing on the concepts of temperature and correlations. Specifically, it contains results on the following topics: locality of temperature, correlations in long-range interacting systems and thermometry at low temperature. The problem of locality of temperature is considered for a system at thermal equilibrium and consists in studying whether it is possible to assign a temperature to any of the subsystems of the global system such that both local and global temperatures are equal. We tackle this problem in two different settings, for generic one-dimensional spin chains and for a bosonic system with a phase transition at non-zero temperature. In the first case, we consider generic one-dimensional translation-invariant spin systems with short-range interactions and prove that it is always possible to assign a local temperature equal to the global one for any temperature, including at criticality. For the second case, we consider a three-dimensional discretized version of the Bose-Einstein model at the grand canonical ensemble for some temperature and particle density, and characterize its non-zero-temperature phase transition. Then, we show that temperature is locally well-defined at any temperature and at any particle density, including at the phase transition. Additionally, we observe a qualitative relation between correlations and locality of temperature in the system. Moving to correlations, we consider fermionic two-site long-range interacting systems at thermal equilibrium. We show that correlations between anti-commutative operators at non-zero temperature are upper bounded by a function that decays polynomially with the distance and with an exponent that is equal to the interaction exponent, which characterizes the interactions in the Hamiltonian. Moreover, we show that our bound is asymptotically tight and that the results extend to density-density correlations as well as other types of correlations for quadratic and fermionic Hamiltonians with long-range interactions. Regarding the results on thermometry, we consider a bosonic model and prove that strong coupling between the probe and the system can boost the thermal sensitivity for low temperature. Furthermore, we provide a feasible measurement scheme capable of producing optimal estimates at the considered regime.
The notion of capacity of entanglement is the quantum information theoretic counterpart of the heat capacity which is defined as the second cumulant of the entanglement spectrum. Given any bipartite pure state, we can define the capacity of entanglement as the variance of the modular Hamiltonian in the reduced state of any of the subsystems. Here, we study the dynamics of this quantity under a nonlocal Hamiltonian. Specifically, we address the following question: Given an arbitrary nonlocal Hamiltonian, what is the capacity of entanglement that the system can possess? As a useful application, we show that the quantum speed limit for creating the entanglement is not only governed by the fluctuation in the nonlocal Hamiltonian, but also depends inversely on the time average of the square root of the capacity of entanglement. Furthermore, we discuss this quantity for a general self-inverse Hamiltonian and provide a bound on the rate of capacity of entanglement. Towards the end, we generalize the capacity of entanglement for bipartite mixed states based on the relative entropy of entanglement and show that the above definition reduces to the capacity of entanglement for pure bipartite states. Our results can have several applications in diverse areas of physics.