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arXiv:2508.02614

Work extraction from long-lived quantum coherence of a three-level system

Wenjing Chen, Han, Si-Wei, X. N. Feng, Jun Min Feng

Published Aug 4, 2025• 0 citations
arXivHTMLPDF

Abstract

We analyze work extraction protocols using the long-lived quantum coherence of a three-level quantum system, which is coupled to a thermal bath through dipole-monopole interactions. We identify situations where persistent quantum coherence arises, i.e., for systems with degenerate excited states with aligned transition dipoles or nearly degenerate systems with small energy splittings. By designing two innovative thermodynamic protocols involving energy-preserving unitary operations, we show that quantum coherence can be transformed into population asymmetry, serving as a quantum resource for work extraction. As the system approaches final thermal equilibrium, the initial quantum coherence effectively acts as fuel, being progressively consumed. Specifically, we propose an optimized protocol capable of extracting the maximal extractable work (MEW), measured by the free energy difference (FED), from quantum coherence in a single-shot thermodynamic cycle. Our results highlight the thermodynamic advantages of long-lived coherence in a three-level quantum system and could influence future designs of coherence-driven quantum thermal machines.

DOI
10.48550/arxiv.2508.02614

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•Aug 6, 2025•33 citations
We analyze work extraction protocols using the long-lived quantum coherence of a three-level quantum system, which is coupled to a thermal bath through dipole-monopole interactions. We identify situations where persistent quantum coherence arises, i.e., for systems with degenerate excited states with aligned transition dipoles or nearly degenerate systems with small energy splittings. By designing two innovative thermodynamic protocols involving energy-preserving unitary operations, we show that quantum coherence can be transformed into population asymmetry, serving as a quantum resource for work extraction. As the system approaches final thermal equilibrium, the initial quantum coherence effectively acts as fuel, being progressively consumed. Specifically, we propose an optimized protocol capable of extracting the maximal extractable work (MEW), measured by the free energy difference (FED), from quantum coherence in a single-shot thermodynamic cycle. Our results highlight the thermodynamic advantages of long-lived coherence in a three-level quantum system and could influence future designs of coherence-driven quantum thermal machines.
Constraints on work extraction are fundamental to our operational understanding of the thermodynamics of both classical and quantum systems. In the quantum setting, finite-time control operations typically generate coherence in the instantaneous energy eigenbasis of the dynamical system. Thermodynamic cycles can, in principle, be designed to extract work from this nonequilibrium resource. Here, we isolate and study the quantum coherent component to the work yield in such protocols. Specifically, we identify a coherent contribution to the ergotropy (the maximum amount of unitarily extractable work via cyclical variation of Hamiltonian parameters). We show this by dividing the optimal transformation into an incoherent operation and a coherence extraction cycle. We obtain bounds for both the coherent and incoherent parts of the extractable work and discuss their saturation in specific settings. Our results are illustrated with several examples, including finite-dimensional systems and bosonic Gaussian states that describe recent experiments on quantum heat engines with a quantized load.
We consider the task of extracting work from quantum systems in the resource theory perspective of thermodynamics, where free states are arbitrary thermal states, and allowed operations are energy conserving unitary transformations. Taking as our work storage system a 'weight' we prove the second law and then present simple protocols which extract average work equal to the free energy change of the system - the same amount as in classical thermodynamics. Crucially, for systems in 'classical' states (mixtures of energy eigenstates) our protocol works on a single copy of the system. This is in sharp contrast to previous results, which showed that in case of almost-deterministic work extraction, collective actions on multiple copies are necessary to extract the free energy. This establishes the fact that free energy is a meaningful notion even for individual systems in classical states. However, for non-classical states, where coherences between energy levels exist, we prove that collective actions are necessary, so long as no external sources of coherence are used.
Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was introduced aiming at extending the thermodynamic formalism to genuine quantum settings, also referred to as autonomous quantum systems: free from external controls, only quantum systems interacting with each other. In this paper, we apply such a thermodynamic framework to common experimental situations of interacting quantum systems. In situations where traditional frameworks detect only heat exchanges, the recent autonomous thermodynamic framework points at work exchanges based on two mechanisms: population inversion and coherence generation / consumption. Such mechanisms are well known in the literature for being related to work expenditure and extraction, in particular in relation with ergotropy, which emphasizes the relevance of the autonomous framework and the limitations of traditional ones. Furthermore, the autonomous framework also identifies a genuine non-unitary mechanism of work exchange related to athermality. %, also pointed out as a resource for work extraction. Finally, in the semi-classical limit, the autonomous framework identifies all energy exchanges as pure work, but distinguishes between local work and interaction energy. Our results show that the autonomous framework provides a refined analysis of work exchange mechanisms in the quantum realm and serves as a consistent approach to analyze thermodynamic processes in realistic quantum devices.
This paper considers work extraction from a quantum system to a work storage system (or weight) following Horodecki and Oppenheim (2013 Nat. Commun. 4 2059 ). An alternative approach is here developed that relies on the comparison of subspace dimensions without a need to introduce thermo-majorization used previously. Optimal single shot work for processes where a weight transfers from (a) a single energy level to another single energy level is then re-derived. In addition we discuss the final state of the system after work extraction and show that the system typically ends in its thermal state, while there are cases where the system is only close to it. The work of formation in the single level transfer setting is also re-derived. The approach presented now allows the extension of the single shot work concept to work extraction (b) involving multiple final levels of the weight. A key conclusion here is that the single shot work for case (a) is appropriate only when a resonance of a particular energy is required. When wishing to identify 'work extraction' with finding the weight in a specific available energy or any higher energy a broadening of the single shot work concept is required. As a final contribution we consider transformations of the system that (c) result in general weight state transfers. Introducing a transfer-quantity allows us to formulate minimum requirements for transformations to be at all possible in a thermodynamic framework. We show that choosing the free energy difference of the weight as the transfer-quantity one recovers various single shot results including single level transitions (a), multiple final level transitions (b), and recent results on restricted sets of multi-level to multi-level weight transfers.
The amount of extractable work from a physical system is fundamentally connected to the information available about its state, as illustrated by Maxwell's demon and the Gibbs paradox. In standard thermodynamic protocols involving system--bath interactions, the maximum work is given by the free-energy difference between the initial state and the corresponding Gibbs state at the bath temperature. This motivates a natural question: does information also limit work extraction in closed quantum systems that do not involve a heat bath and where work is obtained through unitary operations generated by a time-dependent Hamiltonian? While ergotropy quantifies the maximum work extractable via unitary operations, it assumes complete knowledge of the quantum state, typically requiring full state tomography. In realistic scenarios, however, only partial information is accessible. In this case, the relevant figure of merit is observational ergotropy, which depends explicitly on the measurement used to probe the system. We show that observational ergotropy decreases under classical post-processing of measurement outcomes, implying that fine-grained measurements allow greater work extraction than coarse-grained ones. Moreover, maximizing observational ergotropy over all possible measurements recovers standard ergotropy, which decomposes into incoherent (classical) and coherent (quantum) contributions. Our results demonstrate that coherence in the measurement projectors constitutes the key resource, enabling work extraction beyond the incoherent limit and establishing coherence as the origin of quantum advantage in observational ergotropy extraction.
This paper considers work extraction from a quantum system to a work storage system (or weight) following Horodecki and Oppenheim (2013 Nat. Commun. 4 2059). An alternative approach is here developed that relies on the comparison of subspace dimensions without a need to introduce thermo-majorization used previously. Optimal single shot work for processes where a weight transfers from (a) a single energy level to another single energy level is then re-derived. In addition we discuss the final state of the system after work extraction and show that the system typically ends in its thermal state, while there are cases where the system is only close to it. The work of formation in the single level transfer setting is also re-derived. The approach presented now allows the extension of the single shot work concept to work extraction (b) involving multiple final levels of the weight. A key conclusion here is that the single shot work for case (a) is appropriate only when a resonance of a particular energy is required. When wishing to identify 'work extraction' with finding the weight in a specific available energy or any higher energy a broadening of the single shot work concept is required. As a final contribution we consider transformations of the system that (c) result in general weight state transfers. Introducing a transfer-quantity allows us to formulate minimum requirements for transformations to be at all possible in a thermodynamic framework. We show that choosing the free energy difference of the weight as the transfer-quantity one recovers various single shot results including single level transitions (a), multiple final level transitions (b), and recent results on restricted sets of multi-level to multi-level weight transfers.