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arXiv:2507.01916 · Zeitschrift für Naturforschung A

Quantum-mechanical treatment of two particles in a potential box

G. Mann

Published Jan 22, 2024• 0 citations
arXivHTMLPDF

Abstract

Abstract In classical physics, there is a basic principle, namely “A particle cannot be located at the position of another one on the same time.” Which consequences can be derived if this principle is transferred into quantum physics? For doing that, two distinguishable particles are considered to be trapped in a potential box by means of the Schrödinger equation. In result, the particles can necessarily be located only at discrete positions.

DOI
10.1515/zna-2023-0157

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Abstract In classical physics, there is a basic principle, namely “A particle cannot be located at the position of another one on the same time.” Which consequences can be derived if this principle is transferred into quantum physics? For doing that, two distinguishable particles are considered to be trapped in a potential box by means of the Schrödinger equation. In result, the particles can necessarily be located only at discrete positions.
Classical mechanics traces a particle’s movement through space and time through x(t). For example, one may consider the case of a particle moving at constant speed (momentum p) in one direction or a particle bouncing back and forth at constant speed in a box. These problems are described in time and have direction and position associated with time etc. It is possible to define a probability P(x,t) in the classical picture based on delta time, the amount of time a particle spends in a little region of space dx. P(x,t), by itself, loses much relevant information present in the x(t) scenario because a particle moving to the right, or to the left, or bouncing back and forth all have the same probability, 1/L, where L is length. Furthermore, this probability is the same for all p (momentum) values. Thus a probability description, without extra information, is a subset of the relevant information in the problem. As a result, to describe the classical picture fully, one might say that a particle has a probability of 1/L, but also a mass mo and velocity +v (i.e. momentum mov nonrelativistically). For the particle bouncing back and forth in a box with constant p, one needs to give the initial position at time=0 and then a subsequent time (as well as the initial velocity and mo) in order to fully describe the problem, even though probability = 1/L. In the literature (see (1)), there have been many attempts to derive the quantum Schrodinger equation from a classical Fockker-Planck equation or a continuity equation (which follows from the Fokker-Planck equation as shown in (1)). The continuity equation contains a probability P(x,t) and a velocity(x,t) and is generally argued to represent classical physics. It does, if one retains appropriate classical conditions such as the discontinuity of density for a particle in a box (i.e. density=0 outside the box, but 1/L inside) and the notion of differing directions within the box. In fact, one may write density=W*(x,t)W(x,t) where W(x,t) is an ad hoc complex function and still retain compatibility with classical physics. If one does not, however, retain the classical conditions completely, nonclassical physics is introduced, even if density(x,t)=1/L. For example, in quantum mechanics density(x) is considered to be continuous in all x. Thus for a particle moving in a box, density outside the box is 0 so at the box wall it must also be 0. In the classical case, the density is 1 inside the box and 0 outside. There is a discontinuity classically and this cannot be changed and this contradicts the quantum mechanical picture. Thus quantum mechanics does not follow form classical Fokker-Planck or continuity equations which retain classical conditions.. Furthermore, because time is completely removed in the FP-continuity approach as applied to quantum mechanics, one cannot distinguish between forwards and backwards motion. As seen by the velocity field given in (1), v is zero for a bound particle which completely removes the sense of time and violates the classical physics conditions. It is, however, not zero for a particle moving in one direction. Thus there seems to be no issue in describing a Fokker-Planck-continuity equation as describing classical physics. One may even introduce density(x,t)= W*(x,t)W(x,t) provided one retains classical conditions allowing for discontinuity in density and different W(x,t) values at different times i.e. a discontinuity in W(x,t) at a box wall. If these conditions, however, are not met, then one no longer describes classical physics, but a new kind of physics (quantum physics). Thus one cannot argue that quantum mechanics follows from classical statistical Fokker-Planck-continuity equations. It may follow from these if one adds a set of extra conditions. Given these extra conditions, however, one could derive quantum mechanics without starting with classical density.
One of the classic first problems in quantum theory textbooks is that of the particle trapped in a box. Despite the apparent artificiality of the situation, it has quite a few interesting features that we can quickly apply to some more physically plausible situations. The particle in a box is literally an object, such as an electron, trapped inside a ‘box.’ In a realistic physical example, this ‘box’ would be a volume of space bound by some constraining force acting on the particle. For example, an atom is a ‘box’ as far as the orbiting electrons are concerned, with the electrostatic force between the positive protons in the nucleus and the negative electrons providing the constraint. The first move is to assume that the wave function for any particle in the box will have separate spatial and temporal dependencies. One of the key steps in obtaining our wave function was the quantization of the momentum.
Abstract In stark contrast to classical Newtonian mechanics, the standard interpretation of quantum mechanics associates the Schrödinger wavefunction, not in a determ- inistic way with definite predictions about a specific, individual experimental result, but only in a probabilistic manner, with |ψ(x, t )|2 acting as a probability density, in this case, for position measurements. Before analyzing this approach in more detail, we will find it profitable to briefly review some of the basic concepts of discrete and
As an application of the postulates of quantum mechanics, this chapter discusses a simple problem that of a particle constrained to move in a one dimensional box. The structure of matter can be analyzed according to increasingly more fundamental levels of organization. Radioactive processes produce neutrinos, particles that have no detectable mass or charge. In the universe, energies at this level are available in the centers of stars and in star explosions. The wave mechanical treatment of an electron in a box gives rise to large number of discrete energy levels. Tunneling is the quantum-mechanical effect of transitioning through a classically-forbidden energy state. For a quantum particle moving against a potential energy “hill”, the wave function describing the particle can extend to the other side of the hill. This wave represents the probability of finding the particle in a certain location, meaning that the particle has the possibility of being detected on the other side of the hill.
A projection method is proposed to treat the one-dimensional Schr\"odinger equation for a single particle when the generalized uncertainty principle (GUP) generates an ultraviolet (UV) wave-vector cutoff. The existence of a unique coordinate representation called the naive one is derived from the one-parameter family of discrete coordinate representations. In this bandlimited quantum mechanics a continuous potential is reconstructed from discrete sampled values observed by means of a particle in maximally localized states. It is shown that bandlimitation modifies the speed of the center and the spreading time of a Gaussian wave packet moving in free space. Indication is found that GUP accompanied by bandlimitation may cause departures of the low-lying energy levels of a particle in a box from those in ordinary quantum mechanics to be much less suppressed than commonly thought when GUP without bandlimitation is at work.