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arXiv:2506.16570 · Physical Review A

Qubit thermodynamics: Entropy production from nonadiabatic driving

Pavel Zhelnin, Lucas Johns, Carlos A. Argüelles

Published Nov 13, 2025• 1 citation
arXivHTMLPDF

Abstract

Adiabaticity is a cornerstone of many promising approaches to quantum control, computing, and simulation. In practice, however, there is always a trade-off. Although the deleterious effects of noise can be diminished by running a control schedule more quickly, this benefit comes at the expense of nonadiabaticity. To put these two unwanted effects on the same theoretical footing, we analyze the nonadiabatic error in qubit control as a form of entropy production, examining the mechanism by which fine-grained information is effectively lost despite the dynamics being fundamentally unitary. A crucial issue here is the question of how to define equilibrium under a time-dependent Hamiltonian. Using the Landau-Zener protocol as a test case, we show that entropy increases nearly monotonically when equilibrium is defined with respect to the effective Hamiltonian in the optimal superadiabatic frame. We then consider single-passage Landau-Zener-St\"uckelberg-Majorana interferometry, in which the initial state of the qubit is arbitrary. Violations of the second law of thermodynamics are possible but require exquisite control to achieve deliberately.

DOI
10.1103/28ww-4bbd

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Adiabaticity is a cornerstone of many promising approaches to quantum control, computing, and simulation. In practice, however, there is always a trade-off. Although the deleterious effects of noise can be diminished by running a control schedule more quickly, this benefit comes at the expense of nonadiabaticity. To put these two unwanted effects on the same theoretical footing, we analyze the nonadiabatic error in qubit control as a form of entropy production, examining the mechanism by which fine-grained information is effectively lost despite the dynamics being fundamentally unitary. A crucial issue here is the question of how to define equilibrium under a time-dependent Hamiltonian. Using the Landau-Zener protocol as a test case, we show that entropy increases nearly monotonically when equilibrium is defined with respect to the effective Hamiltonian in the optimal superadiabatic frame. We then consider single-passage Landau-Zener-St"uckelberg-Majorana interferometry, in which the initial state of the qubit is arbitrary. Violations of the second law of thermodynamics are possible but require exquisite control to achieve deliberately.
A consistent theory of non-equilibrium thermodynamics for Markovian open quantum systems has been developed in the late seventies in analogy with Classical Irreversible Thermodynamics. The time-evolution of these open systems is usually described by means of effective master equations in Lindblad form, that turn out to be reliable when there is a separation of time-scales between system and environment, such that memory effects are negligible and the so-called Markovian approximation is justified. In this framework, the variations of energy and entropy in the system are consistently described, distinguishing between heat and work contributions and providing a statement of the second law of thermodynamics as positivity of the entropy production.\nHowever, there is empirical evidence that many physical systems like photosynthetic complexes,\nopto-mechanical resonators and superconducting qubits, just to mention a few, experience more general non-Markovian dynamics. The formulation of the laws of thermodynamics in a non-Markovian setting is matter of current research and represents the main topic of the present work. As a first step, we show that the entropy production defined as in the Markovian case can be negative for a class of non-Markovian dynamics. We argue that this outcome should not be interpreted as a violation of the second law of thermodynamics because the environment must be explicitly taken into account in the balance of entropy in the non-Markovian setting. In order to justify this claim we adopt a more general point of view, studying a closed bipartite quantum system, such that each of the two subsystems plays the role of a finite environment out of equilibrium for the other one. We concentrate on the balance of energy first and construct an effective Hamiltonian for each subsystem using physically reasonable requirements; then we define heat and work as in the standard Markovian treatment, with the effective Hamiltonian replacing the free Hamiltonian. It turns out that, in our framework, the work power is perfectly balanced between subsystems, while the correlations can store a part of energy locally inaccessible and exchange it with both subsystems in the form of heat.\nConcerning the balance of entropy, a quite general formulation of the second law of thermodynamics can be given as follows: under the assumption of a factorized initial state for the compound system, the sum of the total variations of the entropies in the two subsystems is always nonnegative. We show with an explicit example that this general formulation does not correspond to the statement presented in the framework of Markovian master equations, which should not be considered a priori the second law of thermodynamics.\nIn the last part of the thesis we concentrate of the so-called fluctuation relations, that are results extending the thermodynamic formalism beyond the behavior of average quantities. After reviewing the main theoretical outcomes, such as the Jarzynski equality and the Crooks fluctuation theorem, we describe a proposal to access experimentally the work performed on an ensemble of diatomic molecules by a time-dependent electric field coupled with their vibrational degree of freedom. This procedure could then be used to test the quantum Jarzynski equality. With respect to the results so far appeared in the literature, in which the left-hand side of the equality is inferred from an experiment and the right-hand side is computed according to a model, in our proposed setting we should be able to estimate from the experiment both the left-hand side and the right-hand side of the equality, independently.
Adiabatic evolution is considered to be the ideal situation for most thermodynamic cycles, as it allows for the achievement of maximum efficiency. However, no power output is produced in light of the infinite amount of time required to perform a transformation. Such issue can be overcome through Shortcuts-To-Adiabaticity (STA) protocols, which allows a dynamics to mimic its adiabatic counterpart, but in a finite time. Transitionless quantum driving (TQD) is one form of STA. We develop and study the effects of TQD on a single-qubit system subjected to a changing magnetic field and a general two-qubit Heisenberg model with a time-dependent interaction strength. We establish a quantitative relation between the work produced across the dynamics and the entropy production resulting from the evolution at hand, focusing on the role played by the initial states of the work medium. We identify the states that extremize performance under the TQD protocol. The thermodynamic implications of STA are discussed in the end.
We analyze the production of entropy along nonequilibrium processes in quantum systems coupled to generic environments.First, we show that the entropy production due to final measurements and the loss of correlations obeys a fluctuation theorem in detailed and integral forms.Second, we discuss the decomposition of the entropy production into two positive contributions, adiabatic and nonadiabatic, based on the existence of invariant states of the local dynamics.Fluctuation theorems for both contributions hold only for evolutions verifying a specific condition of quantum origin.We illustrate our results with three relevant examples of quantum thermodynamic processes far from equilibrium.
Protocols for nonadiabatic quantum control often require the use of classical time-varying fields. Assessing the thermodynamic cost of such protocols, however, is far from trivial. Here, we study the irreversible entropy produced by the classical apparatus generating the control fields, thus providing a direct link between the cost of a control protocol and dissipation. We focus, in particular, on the case of time-dependent magnetic fields and shortcuts to adiabaticity. Our results are showcased with two experimentally realizable case studies: the Landau-Zener model of a spin-12\frac{1}{2}21​ particle in a magnetic field and an ion confined in a Penning trap.
Abstract We report on the experimental quantification of the contribution to non-equilibrium entropy production stemming from the quantum coherence content in the initial state of a qubit exposed to both coherent driving and dissipation. Our experimental demonstration builds on the exquisite experimental control of the spin state of a nitrogen-vacancy defect in diamond and is underpinned, theoretically, by the formulation of a generalized fluctuation theorem designed to track the effects of quantum coherence. Our results provide significant evidence of the possibility to pinpoint the genuinely quantum mechanical contributions to the thermodynamics of non-equilibrium quantum processes in an open quantum systems scenario.
The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established that even pure quantum states can represent thermal equilibrium. However, pure quantum states do not satisfy the second law in that they are not passive, i.e., work can be extracted from them if arbitrary unitary operations are allowed. It therefore remains unresolved how quantum mechanics can be reconciled with thermodynamics. Here, based on our key quantum-mechanical notions of thermal equilibrium and adiabatic operations, we address the emergence of the second law for adiabatic operations in the thermodynamics limit. We first introduce infinite-observable macroscopic thermal equilibrium (iMATE); a quantum state, including pure states, is in iMATE if the expectation values of all additive observables agree with their equilibrium values. We also introduce a macroscopic operation as unitary evolution generated by a time-dependent additive Hamiltonian, which is regarded as corresponding to adiabatic operations. Employing these concepts, we show that no extensive work can be extracted from any quantum state in iMATE through any macroscopic operations. Furthermore, we introduce a quantum-mechanical form of entropy density such that it agrees with thermodynamic entropy density for any quantum state in iMATE. We then prove that for any initial state in iMATE, this entropy density cannot be decreased by any macroscopic operations, followed by a time-independent relaxation process. Our theory thus proves two different forms of the second law, by adopting macroscopically reasonable classes of observables, equilibrium states, and operations. We also discuss the time scales of macroscopic operations in these results.