Adiabatic evolution is considered to be the ideal situation for most thermodynamic cycles, as it allows for the achievement of maximum efficiency. However, no power output is produced in light of the infinite amount of time required to perform a transformation. Such issue can be overcome through Shortcuts-To-Adiabaticity (STA) protocols, which allows a dynamics to mimic its adiabatic counterpart, but in a finite time. Transitionless quantum driving (TQD) is one form of STA. We develop and study the effects of TQD on a single-qubit system subjected to a changing magnetic field and a general two-qubit Heisenberg model with a time-dependent interaction strength. We establish a quantitative relation between the work produced across the dynamics and the entropy production resulting from the evolution at hand, focusing on the role played by the initial states of the work medium. We identify the states that extremize performance under the TQD protocol. The thermodynamic implications of STA are discussed in the end.
Adiabatic evolution is considered to be the ideal situation for most thermodynamic cycles, as it allows for the achievement of maximum efficiency. However, no power output is produced in light of the infinite amount of time required to perform a transformation. Such issue can be overcome through Shortcuts-To-Adiabaticity (STA) protocols, which allows a dynamics to mimic its adiabatic counterpart, but in a finite time. Transitionless quantum driving (TQD) is one form of STA. We develop and study the effects of TQD on a single-qubit system subjected to a changing magnetic field and a general two-qubit Heisenberg model with a time-dependent interaction strength. We establish a quantitative relation between the work produced across the dynamics and the entropy production resulting from the evolution at hand, focusing on the role played by the initial states of the work medium. We identify the states that extremize performance under the TQD protocol. The thermodynamic implications of STA are discussed in the end.
In this thesis, it is presented a set of results in adiabatic dynamics (closed and open system) and transitionless quantum driving that promote some advances in our understanding on quantum control and Hamiltonian inverse engineering. In the context of adiabatic dynamics in closed systems, it is introduced a validation mechanism for the adiabaticity conditions by studing the system dynamics from a non-inertial reference frame. By considering a decohering scenario, validity conditions of the adiabatic approximation are also studied. As a fresh general result with potential applications, it is shown that under decoherence the adiabaticity may still occur in the infinite time limit, as it happens for closed systems, for a class of initial quantum states. To end, the original contributions of this thesis to the theory of shortcuts to adiabaticity refers to a generalized approach of transitionless quantum driving, where one explores the gauge freedom of the quantal phase factors accompanying adiabatic trajectories. A number of theoretical applications are studied, where some theoretical prediction presented in this thesis are experimentally verified through two different experimental setups, namely a qubit encoded in the energy hyperfine structure of a Ytterbium trapped ion, and in nuclear magnetic resonance with a nuclear spin qubit.
It is known that high intensity fields are usually required to implement shortcuts to adiabaticity via transitionless quantum driving (TQD). Here, we show that this requirement can be relaxed by exploiting the gauge freedom of generalized TQD, which is expressed in terms of an arbitrary phase when mimicking the adiabatic evolution. We experimentally investigate the performance of generalized TQD in comparison to both traditional TQD and adiabatic dynamics. By using a Yb+171 trapped ion hyperfine qubit, we implement a Landau–Zener adiabatic Hamiltonian and its (traditional and generalized) TQD counterparts. We show that the generalized theory provides energy-optimal Hamiltonians for TQD, with no additional fields required. In addition, the optimal TQD Hamiltonian for the Landau–Zener model is investigated under dephasing. Even using less intense fields, optimal TQD exhibits fidelities that are more robust against a decohering environment, with performance superior to that provided by the adiabatic dynamics.
Adiabaticity is a cornerstone of many promising approaches to quantum control, computing, and simulation. In practice, however, there is always a trade-off. Although the deleterious effects of noise can be diminished by running a control schedule more quickly, this benefit comes at the expense of nonadiabaticity. To put these two unwanted effects on the same theoretical footing, we analyze the nonadiabatic error in qubit control as a form of entropy production, examining the mechanism by which fine-grained information is effectively lost despite the dynamics being fundamentally unitary. A crucial issue here is the question of how to define equilibrium under a time-dependent Hamiltonian. Using the Landau-Zener protocol as a test case, we show that entropy increases nearly monotonically when equilibrium is defined with respect to the effective Hamiltonian in the optimal superadiabatic frame. We then consider single-passage Landau-Zener-St\"uckelberg-Majorana interferometry, in which the initial state of the qubit is arbitrary. Violations of the second law of thermodynamics are possible but require exquisite control to achieve deliberately.
Although the idea of combining thermodynamics with quantum mechanics is more than a century old, quantum thermodynamics has seen significant development over the past few decades. Understanding work, heat, and entropy in the quantum regime has become increasingly important, particularly in light of advances in quantum technologies. This thesis investigates work processes in quantum spin chains. Quantum work processes can involve genuinely quantum features such as entanglement, coherence, and measurement back-action, which are absent in classical thermodynamic descriptions, making their characterization an area of ongoing interest in quantum thermodynamics. Focusing first on a single work step, we show that the frictional work due to finite-time driving for a non-integrable quantum spin chain can be well quantified by the diagonal entropy production. We further demonstrate that integrability breaking enhances work extraction in the adiabatic limit, while suppressing it in the non-adiabatic regime. We then study a quantum Otto cycle using the transverse-field Ising model as the working substance. We determine how different types of operation (engine, refrigerator, accelerator, heater) can emerge for different parameter regimes. We show that with infinitesimal work strokes, a thermal machine behaves either as an engine or an accelerator, and that these regimes can be characterized by equilibrium transverse magnetization. At low temperatures, these regimes are governed by low-energy excitations, while at high temperatures they follow from a free-energy expansion in inverse temperature. Frictional effects can emerge and suppress the engine performance during non-adiabatic driving. We show that these effects can be mitigated using an optimised drive protocol based on a geometric formulation of the path of the system through parameter space. Overall, this thesis provides a comprehensive understanding of how integrability, coherence, finite-time driving, and non-adiabatic transitions govern work extraction and thermal machine operation in quantum spin chains, and paves the way for understanding these processes in other quantum many-body systems.
Thermodynamic uncertainty relations (TURs) are a set of inequalities expressing a fundamental trade-off between precision and dissipation in non-equilibrium classical and quantum thermodynamic processes. TURs show that achieving low fluctuations in a thermodynamic quantity (e.g., heat or work) requires a minimum entropy production, with profound implications for the efficiency of biological and artificial thermodynamic processes. The accurate evaluation of TURs is a necessary requirement to quantify the fluctuation and dissipation entailed by a thermodynamic process, and ultimately to optimize the performance of quantum devices, whose operation is fundamentally a quantum thermodynamic process. Here, we simulate TURs in a transverse-field Ising model subjected to a time-dependent driving protocol, using quantum and classical computers in concert. Varying the duration and strength of the drive as well as the system size, we verify the validity of TURs, identify quantum signatures in the work statistics within the linear response regime, and observe TUR saturation in the high-temperature limit.