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arXiv:2505.21227 · Physical Review Letters

Strong Molecule-Light Entanglement with Molecular Cavity Optomechanics

Hong-Yun Yu, Ya-Feng Jiao, Jie Wang, Feng Li, Bin Yin, Qi-Rui Liu, Tian Jiang, Hui Jing, Ke Wei

Published Dec 9, 2025• 5 citations
arXivHTMLPDF

Abstract

We propose a molecular optomechanical platform to generate robust entanglement among bosonic modes-photons, phonons, and plasmons-under ambient conditions. The system integrates a high-Q whispering-gallery-mode (WGM) optical resonator with a plasmonic nanocavity formed by a metallic nanoparticle and a single molecule. This hybrid architecture offers two critical advantages over stand-alone plasmonic systems: (i) efficient redirection of Stokes photons from the lossy plasmonic mode into the long-lived WGM resonator and (ii) suppression of molecular absorption and sustaining vibrational ground states via plasmon-WGM interactions. These features enable entanglement to redistribute from the fragile plasmon-phonon bipartition to a robust photon-phonon bipartition in the blue-detuned regime, yielding robust stationary entanglement resilient to environmental noise. Remarkably, the achieved entanglement surpasses the theoretical bound for conventional two-mode squeezing in certain parameter regimes. Our scheme establishes a universal approach to safeguard entanglement in open quantum systems and opens avenues for noise-resilient quantum information technologies.

DOI
10.1103/4z8v-f6s5

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