One of the fundamental problems of quantum statistical physics is how an ideally isolated quantum system can ever reach thermal equilibrium behavior despite the unitary time evolution of quantum-mechanical systems. Here, we study, via explicit time evolution for the generic model system of an interacting, trapped Bose gas with discrete single-particle levels, how the measurement of one or more observables subdivides the system into observed and non-observed Hilbert subspaces and the tracing over the non-measured quantum numbers defines an effective, thermodynamic bath, induces the entanglement of the observed Hilbert subspace with the bath, and leads to a bi-exponential approach of the entanglement entropy and of the measured observables to thermal equilibrium behavior as a function of time. We find this to be more generally fulfilled than in the scenario of the eigenstate thermalization hypothesis (ETH), namely for both local particle occupation numbers and non-local density correlation functions, and independent of the specific initial quantum state of the time evolution.
One of the fundamental problems of quantum statistical physics is how an ideally isolated quantum system can ever reach thermal equilibrium behavior despite the unitary time evolution of quantum-mechanical systems. Here, we study, via explicit time evolution for the generic model system of an interacting, trapped Bose gas with discrete single-particle levels, how the measurement of one or more observables subdivides the system into observed and non-observed Hilbert subspaces and the tracing over the non-measured quantum numbers defines an effective, thermodynamic bath, induces the entanglement of the observed Hilbert subspace with the bath, and leads to a bi-exponential approach of the entanglement entropy and of the measured observables to thermal equilibrium behavior as a function of time. We find this to be more generally fulfilled than in the scenario of the eigenstate thermalization hypothesis (ETH), namely for both local particle occupation numbers and non-local density correlation functions, and independent of the specific initial quantum state of the time evolution.
A very fundamental problem in quantum statistical mechanics involves whether—and how—an isolated quantum system will reach thermal equilibrium after waiting a long time. In quantum systems that do thermalize, the long-time expectation value of any “reasonable” operator will match its predicted value in the canonical ensemble. The Eigenstate Thermalization Hypothesis (ETH) posits that this thermalization occurs at the level of each individual energy eigenstate; in fact, any single eigenstate in a microcanonical energy window will predict the expectation values of such operators exactly. In the first part of this dissertation, we identify, for a generic model system, precisely which operators satisfy ETH, as well as limits to the information contained in a single eigenstate. Remarkably, our results strongly suggest that a single eigenstate can contain information about energy densities—and therefore temperatures—far away from the energy density of the eigenstate.Additionally, we study the possible breakdown of quantum thermalization in a model of itinerant electrons on a one-dimensional chain, with both spin and charge degrees of freedom. This model exhibits peculiar properties in the entanglement entropy, the apparent scaling of which is modified from a “volume law” to an “area law” after performing a partial, site-wise measurement on the system. These properties and others suggest that this model realizes a new, non-thermal phase of matter, known as a Quantum Disentangled Liquid (QDL). The putative existence of this phase has striking implications for the foundations of quantum statistical mechanics.
The question of how statistical physics can be seen to emerge from unitary quantum dynamics goes back to Schrödinger and von Neumann, however has been reaffirmed as a topic of importance due to recent advances in experimental capabilities, allowing the observation of the unitary evolution of many-particle systems over long periods of time. Understanding why such a system evolves to the specific thermal equilibrium state, effectively described by a relevant thermodynamic ensemble, has thus seen significantly more interest in recent years. Furthermore, observations of the dynamics of such systems open questions on the route to equilibrium, and subsequent fluctuations. In this thesis I will develop an approach to this problem, taking as a starting point the non-integrability of the system under study, which leads to a generic model in terms of random matrix theory (RMT), and more generally, chaotic wavefunctions. In the formulation of these methods, special attention is paid to the form of local observables of quantum systems, and an approach to their description is developed in terms of correlation functions of chaotic wavefunctions. From this approach a key conjecture in the understanding of thermalization, the eigenstate thermalization hypothesis (ETH), is derived in full, and the dynamical behaviour of such observables is obtained analytically. Further, I will show that emergent classical behaviour can be observed in the form of a fluctuation-dissipation theorem (FDT) of Brownian processes. This is exploited to develop an experimental proposal to measure the ‘complexity’ of a quantum device, by experimentally obtaining its effective Hilbert space dimension in terms of a fully connected system. Finally, quantum jump trajectories, describing stroboscopic projective measurements of local observables are studied, and shown to display classical Brownian dynamics in the form of a Markov process. Throughout this thesis, exact diagonalization calculations of realistic quantum spin systems are used to confirm analytical results.
Understanding the evolution towards thermal equilibrium of an isolated quantum system is at the foundation of statistical mechanics and a subject of interest in such diverse areas as cold atom physics or the quantum mechanics of black holes. Since a pure state can never evolve into a thermal density matrix, the Eigenstate Thermalization Hypothesis (ETH) has been put forward by Deutsch and Srednicki as a way to explain this apparent thermalization, similarly to what the ergodic theorem does in classical mechanics. In this paper this hypothesis is tested numerically. First, it is observed that thermalization happens in a subspace of states (the Krylov subspace) with dimension much smaller than that of the total Hilbert space. We check numerically the validity of ETH in such a subspace, for a system of hard core bosons on a two-dimensional lattice. We then discuss how well the eigenstates of the Hamiltonian projected on the Krylov subspace represent the true eigenstates. This discussion is aided by bringing the projected Hamiltonian to the tridiagonal form and interpreting it as an Anderson localization problem for a finite one-dimensional chain. We also consider thermalization of a subsystem and argue that generation of a large entanglement entropy can lead to a thermal density matrix for the subsystem well before the whole system thermalizes. Finally, we comment on possible implications of ETH in quantum gravity.
Statistical mechanics relies on the maximization of entropy in a system at thermal equilibrium. However, an isolated quantum many-body system initialized in a pure state remains pure during Schrödinger evolution, and in this sense it has static, zero entropy. We experimentally studied the emergence of statistical mechanics in a quantum state and observed the fundamental role of quantum entanglement in facilitating this emergence. Microscopy of an evolving quantum system indicates that the full quantum state remains pure, whereas thermalization occurs on a local scale. We directly measured entanglement entropy, which assumes the role of the thermal entropy in thermalization. The entanglement creates local entropy that validates the use of statistical physics for local observables. Our measurements are consistent with the eigenstate thermalization hypothesis.
Classical statistical mechanics relies on the ergodic hypothesis, which states that a system explores the entire allowed phase space during its time evolution. Pure quantum states are at odds with this concept as they remain in a single quantum state even if the system's parameters are suddenly altered. However, in a generic many-body system, coherent dynamics drive local thermalization of its subsystems. In this case, any local observable appears thermal and can be described by a statistical ensemble even though the full state remains pure. The key to understanding the phenomenon of quantum thermalization lies in the entanglement properties of the system: The presence of entanglement creates local entropy that validates the use of statistical physics.\nIn this thesis, we experimentally study the emergence of statistical mechanics in a quantum state and observe the fundamental role of quantum entanglement in facilitating this emergence. We perform microscopy on an evolving quantum system, and we see thermalization occur on a local scale while we measure that the full quantum state remains pure.\nThe only known robust exception from the paradigm of quantum thermalization is provided by disordered systems. In this case, the particle transport ceases through the system, preventing the formation of a sufficient amount of entanglement required for thermalization. However, if the many-body system is interacting, the state develops non-local quantum correlations that are inaccessible to any local observable. These correlations spread exponentially slowly in time throughout the entire system and are considered a hallmark feature of many-body-localized states.\nIn order to study the interplay between thermalization and localization in our system, we develop novel methods for high fidelity state preparation and readout. We achieved an exquisite isolation of our system from the environment, which allows us to monitor coherent many-body dynamics over multiple decades of time evolution.\nWe experimentally realize such a many-body localized system and observe the formation of non-local quantum correlations, while the particle transport is frozen in the system. Our work experimentally establishes many-body localization as a qualitatively distinct phenomenon from localization in non-interacting, disordered systems.
If we prepare an isolated, interacting quantum system in an eigenstate and perturb a local observable at an initial time, its expectation value will relax towards a thermal expectation value, even though the time evolution of the system is deterministic. The eigenstate thermalization hypothesis (ETH) of Deutsch and Srednicki suggests that this is possible because each eigenstate of the full quantum system acts as a thermal bath to its subsystems, such that the reduced density matrices of the subsystems resemble thermal density matrices. Here, we use the observation that the eigenvalue distribution of interacting quantum systems is a Gaussian under very general circumstances, and Dyson Brownian motion random matrix theory, to derive the ETH and thereby elevate it from hypothesis to theory. Our analysis provides a derivation of statistical mechanics which neither requires the concepts of ergodicity or typicality, nor that of entropy. Thermodynamic equilibrium follows solely from the applicability of quantum mechanics to large systems and the absence of integrability.